Membrane-electrode assembly, fuel cell, and fuel cell system
A membrane electrode assembly includes solid polymer electrolyte membrane, an anode, and cathode. The cathode has a stacked body formed of a catalyst layer and a gas diffusion layer. The catalyst layer, which contains catalyst metal-supporting carbon particles and an ion conductor, further contains a mesoporous humidity control agent whose amount of water adsorption rises steeply as a relative humidity increases in a specific relative humidity region.
1. A membrane electrode assembly, comprising:
an electrolyte membrane;
an anode disposed on one face of said electrolyte membrane; and
a cathode disposed on the other face of said electrolyte membrane,
wherein:
at least either one of the anode and the cathode has a catalyst layer containing a mesoporous humidity control agent whose amount of water adsorption rises steeply as a relative humidity increases in a predetermined relative humidity region,
the mesoporous humidity control agent is mesoporous silica,
a humidified reaction gas is supplied to the catalyst layer, and
the average pore diameter of the mesoporous silica added to an upstream side of the flow of the reaction gas is smaller than the average pore diameter of the mesoporous silica added to a downstream side thereof.
2. A membrane electrode assembly according to claim 1 , wherein an average pore diameter of the mesoporous silica is 1 to 15 nm.
3. A membrane electrode assembly according to claim 2 , wherein
the amount of the mesoporous silica, added to an upstream side of the flow of the reaction gas, relative to the catalyst layer on an upstream side is larger than the amount of the mesoporous silica, added to a downstream side of the flow of the reaction gas, relative to the catalyst layer on a downstream side.
4. A fuel cell having a membrane electrode assembly according to claim 2 .
5. A fuel cell having a membrane electrode assembly according to claim 1 .