Cement compositions comprising sub-micron alumina and associated methods
Methods and compositions that comprise sub-micron alumina for accelerating setting of a cement composition. An embodiment includes a method of cementing in a subterranean formation. The method may comprise introducing a cement composition into the subterranean formation, wherein the cement composition comprises hydraulic cement, sub-micron alumina, and water. The method further may comprise allowing the cement composition to set in the subterranean formation. Another embodiment includes a cement composition that may comprise hydraulic cement, sub-micron alumina, and water.
1. A method of cementing in a subterranean formation:
providing a hydraulic cement,
providing sub-micron alumina particles,
preparing a cement composition comprising the hydraulic cement, the sub-micron alumina particles, and water, wherein the sub-micron alumina particles have a particle size in a range of from about 150 nm to about 950 nm, and wherein the sub-micron alumina particles are present in an amount in a range of from 0.1% to about 10% by weight of the hydraulic cement on a dry basis;
introducing the cement composition into a subterranean formation; and
allowing the cement composition to set in the subterranean formation.
2. The method of claim 1 wherein the hydraulic cement comprises at least one hydraulic cement selected from the group consisting of a Portland cement, a pozzolana cement, a gypsum cement, a high-alumina-content cement, a slag cement, a silica/lime cement, and any combination thereof.
3. The method of claim 1 wherein the cement composition comprises belite in an amount from 0.1% to about 50% by weight of calcium silicates in the cement composition.
4. The method of claim 1 wherein the cement composition comprises a colloidal alumina dispersion comprising sub-micron alumina particles suspended in a base fluid.
5. The method of claim 1 comprising providing the sub-micron alumina particles in a dry, free-flowing form.
6. The method of claim 1 wherein the sub-micron alumina particles have a particle size in the range of about 400 nm to about 500 nm.
7. The method of claim 1 wherein the sub-micron alumina particles are present in the cement composition in an amount in the range of about 0.5% to about 5% by weight of the hydraulic cement on a dry basis.
8. The method of claim 1 wherein the cement composition further comprises a latex.
9. The method of claim 8 wherein the latex comprises at least one rubber material selected from the group an ethylene-propylene rubber, a styrene-butadiene rubber, a nitrile rubber, a nitrile butadiene rubber, a butyl rubber, a neoprene rubber, a polybutadiene rubber, an acrylonitrile-styrene-butadiene rubber, a polyisoprene rubber, and any combination thereof.
10. The method of claim 1 wherein the cement composition further comprises at least one additive selected from the group consisting of a latex stabilizer, a strength-retrogression additive, a set accelerator, a set retarder, a weighting agent, a lightweight additive, a gas-generating additive, a mechanical property enhancing additive, a lost-circulation material, a filtration-control additive, a fluid loss control additive, a dispersant, a defoaming agent, a foaming agent, a thixotropic additive, and any combination thereof.
11. The method of claim 1 wherein the cement composition further comprises at least one additive selected from the group consisting of a gas, crystalline silica, amorphous silica, fumed silica, a salt, a fiber, a hydratable clay, calcined shale, vitrified shale, a microsphere, fly ash, slag, diatomaceous earth, metakaolin, rice husk ash, a natural pozzolan, zeolite, cement kiln dust, lime, an elastomer, a resin, and any combination thereof.
12. The method of claim 1 wherein introducing the cement composition into the subterranean formation comprises introducing the cement composition into a well bore in a space between the subterranean formation and a conduit disposed in the well bore.
13. The method of claim 1 wherein introducing the cement composition into the subterranean formation comprises introducing the cement composition into a well bore having a bottomhole circulating temperature of about 40° F. to about 180° F.
14. A method of cementing in a subterranean formation:
providing a hydraulic cement,
providing sub-micron alumina particles,
preparing a cement composition comprising the hydraulic cement, the sub-micron alumina particles for accelerating setting of the cement composition, latex, and water, wherein the sub-micron alumina particles have a particle size of about 150 nm to about 950 nm, wherein preparing the cement composition comprises providing a colloidal alumina dispersion comprising the sub-micron alumina particles in an aqueous base fluid;
introducing the cement composition into a well bore in a space between the subterranean formation and a conduit disposed in the well bore; and
allowing the cement composition to set.
15. The method of claim 14 wherein the latex comprises a styrene-butadiene latex.
16. The method of claim 14 wherein the sub-micron alumina particles are present in the cement composition in an amount in the range of about 0.1% to about 10% by weight of the hydraulic cement on a dry basis, and wherein the sub-micron alumina particles have a particle size of about 400 nm to about 500 nm.
17. The method of claim 14 wherein the cement composition further comprises at least one additive selected from the group consisting of a latex stabilizer, a strength-retrogression additive, a set accelerator, a set retarder, a weighting agent, a lightweight additive, a gas-generating additive, a mechanical property enhancing additive, a lost-circulation material, a filtration-control additive, a fluid loss control additive, a dispersant, a defoaming agent, a foaming agent, a thixotropic additive, and any combination thereof.
18. The method of claim 14 wherein the cement composition further comprises at least one additive selected from the group consisting of crystalline silica, amorphous silica, fumed silica, a salt, a fiber, a hydratable clay, calcined shale, vitrified shale, a microsphere, fly ash, slag, diatomaceous earth, metakaolin, rice husk ash, natural pozzolan, zeolite, cement kiln dust, lime, an elastomer, a resin, and any combination thereof.
19. The method of claim 14 wherein the well bore has a bottom hole circulating temperature of about 40° F. to about 180° F.
20. A method of cementing in a subterranean formation:
providing a hydraulic cement,
providing sub-micron alumina particles,
preparing a cement composition, wherein the cement composition comprises:
hydraulic cement;
sub-micron alumina particles having a particle size in a range of about 150 nm to about 950 nm, wherein the sub-micron alumina particles are present in the cement composition in an amount in a range of about 0.1% to about 10% by weight of the hydraulic cement on a dry basis; and
water;
introducing the cement composition into a subterranean formation; and
allowing the cement composition to set in the subterranean formation.
21. The method of claim 20 wherein the hydraulic cement comprises at least one hydraulic cement selected from the group consisting of a Portland cement, a pozzolana cement, a gypsum cement, a high-alumina-content cement, a slag cement, a silica/lime cement, and any combination thereof.
22. The method of claim 20 wherein the cement composition comprises belite in an amount from 0.1% to about 50% by weight of calcium silicates in the cement composition.
23. The method of claim 20 wherein the cement composition comprises a colloidal alumina dispersion comprising the sub-micron alumina particles suspended in a base fluid.
24. The method of claim 20 wherein the cement composition further comprises a latex.
25. The method of claim 24 wherein the latex comprises at least one rubber material selected from the group an ethylene-propylene rubber, a styrene-butadiene rubber, a nitrile rubber, a nitrile butadiene rubber, a butyl rubber, a neoprene rubber, a polybutadiene rubber, an acrylonitrile-styrene-butadiene rubber, a polyisoprene rubber, and any combination thereof.
26. The method of claim 20 wherein the cement composition further comprises at least one additive selected from the group consisting of a latex stabilizer, a strength-retrogression additive, a set accelerator, a set retarder, a weighting agent, a lightweight additive, a gas-generating additive, a mechanical property enhancing additive, a lost-circulation material, a filtration-control additive, a fluid loss control additive, a dispersant, a defoaming agent, a foaming agent, a thixotropic additive, and any combination thereof.
27. The method of claim 20 wherein the cement composition further comprises at least one additive selected from the group consisting of a gas, crystalline silica, amorphous silica, fumed silica, a salt, a fiber, a hydratable clay, calcined shale, vitrified shale, a microsphere, fly ash, slag, diatomaceous earth, metakaolin, rice husk ash, a natural pozzolan, zeolite, cement kiln dust, lime, an elastomer, a resin, and any combination thereof.
28. The method of claim 20 wherein introducing the cement composition into the subterranean formation comprising introducing the cement composition into a well bore in a space between the subterranean formation and a conduit disposed in the well bore.
29. The method of claim 28 wherein the well bore has a bottom hole circulating temperature of about 40° F. to about 180° F.