Recycling superabsorbent polymer fines
A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
1. A superabsorbent polymer composition comprising:
(i) caustic treated superabsorbent polymer fines treated with from about 1 to about 12 wt % of a caustic solution comprising sodium hydroxide, sodium carbonate or sodium bicarbonate wherein the superabsorbent polymer fines have a particle size of less than about 150 μm.
2. The superabsorbent polymer composition of claim 1 , further comprising
(ii) a monomer solution comprising acrylic acid wherein from about 0.1 to about 30 wt % of the caustic treated superabsorbent polymer fines of (i) based on the weight of the monomer solution are added to the monomer solution.
3. The superabsorbent polymer composition of claim 2 , further comprising
(iii) from about 0.001 to about 5.0 wt % based on the monomer of an internal crosslinking agent.
4. The superabsorbent polymer composition of claim 2 , wherein the acrylic acid of the monomer solution is neutralized to from about 50 mol % to about 80 mol %.
5. The superabsorbent polymer composition of claim 1 , wherein the superabsorbent polymer composition comprises less than 10% moisture thus forming a dry superabsorbent polymer composition.
6. The superabsorbent polymer composition of claim 5 , further comprising
(iv) from about 0.001 to about 5.0 wt % based on the weight of the dry superabsorbent polymer composition of a surface crosslinking agent.
7. The superabsorbent polymer composition of claim 1 , wherein the content of the superabsorbent polymer fines relative to the total amount of the superabsorbent polymer composition is from about 0.1 to about 10 wt %.
8. The superabsorbent polymer composition of claim 1 , further comprising (v) a multivalent metal salt selected from aluminum sulfate or aluminum lactate.
9. The superabsorbent polymer composition of claim 5 , further comprising (vi) from about 0.01 to about 0.5 wt % based on the weight of the dry superabsorbent polymer of a thermoplastic polymer coating wherein the thermoplastic polymer is selected from polyolefin, polyethylene, polyesters, polyurethanes, linear low density polyethylene, ethylene acrylic acid copolymer, styrene copolymers, ethylene alkyl methacrylate copolymer, polypropylene, maleated polypropylene, ethylene vinyl acetate copolymer, polyamide, polyester, or blends and copolymers thereof.
10. The superabsorbent polymer composition of claim 9 , wherein the thermoplastic polymer is maleated polypropylene.
11. The superabsorbent polymer composition of claim 5 , further comprising (vii) from about 0.01 to about 0.5 wt % based on the weight of the dry superabsorbent polymer of poly(vinyl amine).
12. The superabsorbent polymer composition of claim 5 , further comprising (viii) from about 0.01 to about 3 wt % based on the weight of the dry superabsorbent polymer of a silica.
13. The superabsorbent polymer composition of claim 12 , wherein the silica comprises precipitated silica.