IP Library Granted Patent US 8,492,061
Granted Patent B2
US 8,492,061 · App. 12/612,406 · Granted Jul 23, 2013

Electrophotographic toner and method of preparing the same

Inventors: Jae-Hyeuk Jeong (Suwon-Si, KR); Kyeong Pang (Suwon-Si, KR); Jung-Ik Choi (Suwon-Si, KR); Soon-Cheol Jeong (Seoul, KR); Hong-Chul Shin (Suwon-Si, KR)
Assignee: Samsung Electronics Co., Ltd.
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,492,061
App. No.
12/612,406
Granted
Jul 23, 2013
Kind
B2
Abstract

The disclosure provides electrophotographic toner and a method of preparing the same. The toner includes a latex, a colorant, and a releasing agent, wherein the toner has a weight-average molecular weight of about 50,000 to about 80,000; a complex viscosity of about 1×10 3 to about 5×10 4 (Pa·s) at a temperature ranging from about 100° C. to about 140° C.; and a storage modulus Pa (dG′) to a loss modulus Pa (dG″) (dG′/dG″) ratio of about 1.10 to about 1.25.

Claims (19)

1. An electrophotographic toner comprising a latex, a colorant, and a releasing agent, wherein the electrophotographic toner has a weight-average molecular weight of about 50,000 to about 80,000; a complex viscosity of about 1×10 3 to about 5×10 4 (Pa·s) at a temperature ranging from about 100° C. to about 140° C.; and a dG′/dG″ ratio of about 1.10 to about 1.25 at temperatures from about 100° C. to less than 140° C., the dG′/dG″ ratio being defined as ΔG′/ΔG″, where ΔG′ is a first change in G′ and ΔG″ is a second change in G″ over a frequency region of about 0.1 rad/s to about 100 rad/s.

2. The electrophotographic toner of claim 1 , further comprising silicon (Si) and iron (Fe), each independently in a range of about 3 ppm to about 1,000 ppm.

3. The electrophotographic toner of claim 1 , wherein the releasing agent comprises a mixture of a paraffin-based wax and an ester-based wax; or an ester group containing paraffin-based wax.

4. The electrophotographic toner of claim 3 , wherein the releasing agent has a content of an ester group from about 2% by weight to about 10% by weight based on the total weight of the releasing agent.

5. The electrophotographic toner of claim 1 , wherein the toner has a volume average particle diameter of about 3 μm to about 8 μm.

6. The electrophotographic toner of claim 1 , wherein the toner has an average value of circularity of about 0.940 to about 0.980.

7. The electrophotographic toner of claim 1 , wherein the toner has a value of a volume average particle size distribution index (GSDv) and a number average particle size distribution index (GSDp) less than about 1.25, respectively.

8. A method of preparing an electrophotographic toner, the method comprising the steps of:

a) mixing a primary latex particle, a colorant dispersion, and a releasing agent dispersion to prepare a mixture;

b) adding an agglomerating agent to the mixture to prepare a primary agglomerated toner; and

c) coating a secondary latex, prepared by polymerizing one or more polymerizable monomers, on the primary agglomerated toner to provide a secondary agglomerated toner, thus preparing the electrophotographic toner,

wherein the electrophotographic toner has a weight-average molecular weight of about 50,000 to about 80,000; a complex viscosity of about 1×10 3 to about 5×10 4 (Pa·s) at a temperature ranging from about 100° C. to about 140° C.; and a dG′/dG″ ratio of about 1.10 to about 1.25 at temperatures from about 100° C. to less than 140° C., the dG′/dG″ ratio being defined as ΔG′/ΔG″, where ΔG′ is a first change in G′ and AG″ is a second change in G″ over a frequency region of about 0.1 rad/s to about 100 rad/s.

9. The method of claim 8 , wherein the primary latex particle comprises polyester alone; a polymer obtained by polymerizing one or more polymerizable monomers; or a mixture thereof.

10. The method of claim 8 , the method further comprising the step of:

d) coating a tertiary latex, prepared by polymerizing one or more polymerizable monomers, on the secondary agglomerated toner, to provide a tertiary agglomerated toner, thus preparing the electro graphic toner.

11. The method of claim 8 , wherein the polymerizable monomer comprises at least one monomer selected from styrene-based monomers; acrylic acid or methacrylic acid; derivatives of (metha)acrylates; ethylenically unsaturated mono-oletins; halogenized vinyls; vinyl esters; vinyl ethers; vinyl ketones; and nitrogen containing vinyl compounds.

12. The method of claim 8 , wherein the releasing agent dispersion comprises a mixture of a paraffin-based wax and an ester-based wax; or an ester group containing paraffin-based wax.

13. The method of claim 8 , wherein the agglomerating agent comprises Si and Fe containing metallic salts.

14. The method of claim 8 , wherein the agglomerating agent comprises polysilica iron.

Assignments (6)
CONFIRMATORY ASSIGNMENT EFFECTIVE NOVEMBER 1, 2018 Recorded Oct 17, 2019
From: HP PRINTING KOREA CO., LTD.
To: HEWLETT-PACKARD DEVELOPMENT COMPANY, L.P.
Reel/Frame 050747/0080 →
CHANGE OF LEGAL ENTITY EFFECTIVE AUG. 31, 2018 Recorded Oct 16, 2019
From: HP PRINTING KOREA CO., LTD.
To: HP PRINTING KOREA CO., LTD.
Reel/Frame 050938/0139 →
CORRECTIVE ASSIGNMENT TO CORRECT THE DOCUMENTATION EVIDENCING THE CHANGE OF NAME PREVIOUSLY RECORDED ON REEL 047370 FRAME 0405. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Nov 21, 2018
From: S-PRINTING SOLUTION CO., LTD.
To: HP PRINTING KOREA CO., LTD.
Reel/Frame 047769/0001 →
CHANGE OF NAME Recorded Aug 17, 2018
From: S-PRINTING SOLUTION CO., LTD.
To: HP PRINTING KOREA CO., LTD.
Reel/Frame 047370/0405 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2017
From: SAMSUNG ELECTRONICS CO., LTD
To: S-PRINTING SOLUTION CO., LTD.
Reel/Frame 041852/0125 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2009
From: JEONG, JAE-HYEUK; PANG, KYEONG; CHOI, JUNG-IK; JEONG, SOON-CHEOL; SHIN, HONG-CHUL
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 023470/0295 →
Priority Claims (1)
KR 10-2008-0134949 · Dec 26, 2008 · national
Continuity (1)
Related Publication 20100167194A1 · Jul 1, 2010