Iron complex, manufacturing method thereof and supported iron oxide catalyst constructed thereby
A manufacturing method of an iron complex is mixing ferric chloride and at least one chelating agent with a solvent, wherein Fe 3+ ions of ferric chloride is reacted with the at least one chelating agent to form an iron complex Fe[R 1 ] a [R 2 ] b [H 2 O] c 3+ or Fe[R 1 ] a [H 2 O] c 3+ , wherein the at least one chelating agent is selected from a group including ethylenediamine, 1,10-phenanthroline, 2,2′-Bipyridine, diethylenetriamine, triethylenetetraamine, phenanthroline, or bipyridine. Moreover, a method for producing an iron oxide catalyst is mixing ferric chloride, at least one chelating agent and the support with a solvent to form an iron complex, which is incorporated with the support. Following, a drying step and a heat treatment step are processed to get the iron oxide catalyst.
1. A manufacturing method of making an iron oxide through an iron complex, comprising:
a chelating step mixing a ferric chloride, first chelating agent and second chelating agent with a solvent to form an iron complex solution, wherein the first and second chelating agents are selected from a group consisting of ethylenediamine, 1,10-phenanthroline, 2,2′-Bipyridine, diethylenetriamine, triethylenetetraamine, phenanthroline, and bipyridine, and Fe 3 +ions of ferric chloride being reacted with the first and second chelating agent to form the iron complex;
a drying step removing the solvent from the iron complex solution to obtain a dried iron complex; and
a heat treatment step executing heat treatment for the dried iron complex to form iron oxide with molecular formula Fe 3 O 4 , wherein the heat treatment step is processed under a nitrogen atmosphere;
wherein the iron complex is in the form of Fe[R 1 ] a [R 2 ] b [H 2 O] c 3+ , with the R 1 representing the first chelating agent and the R 2 representing the second chelating agent and being different from the first chelating agent, wherein an equation of (a ×the coordination number of R 1 )+(b×the coordination number of R 2 )+c=6 is held and a, b and c are not zero.
2. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein the ferric chloride and the first and second chelating agents are mixed with the solvent by continuously stirring.
3. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein the solvent is sonicated after ferric chloride and the first and second chelating agent are added into the solvent.
4. The manufacturing method of making the iron oxide through the iron complex as defined in claim 3 , wherein the solvent containing the iron complex is sonicated for 24 hours.
5. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein the drying step is processed under vacuum condition.
6. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein the temperature for processing the heat treatment step is limited between 800 and 900° C.
7. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein a time period for processing the heat treatment step is 1 to 4 hours.
8. The manufacturing method of making the iron oxide through the iron complex as defined in claim 1 , wherein after completing the heat treatment step, iron oxide is allowed to cool to room temperature in a nitrogen atmosphere.