Metal fine particles and manufacturing method therefor
There is provided a method for efficiently manufacturing metal nano particles without condensing laser beams by using a lens etc. In this method, first, metallic foil pieces, which are a starting material, are dispersed in a dispersion liquid. Next, laser beams are irradiated directly to the metallic foil pieces without providing a condensing means, by which many metal fine particles are yielded. The particle diameters of the metal fine particles obtained can be controlled to sizes from nano particles to submicron particles by utilizing the relationship between the shape (especially thickness) of the metallic foil piece which is a starting material and the absorbed energy of the laser beam.
1. A manufacturing method for metal fine particles each having a particle diameter of several tens nanometers, characterized in that laser beams having at least an energy density not lower than an energy density E th2 [J/cm 2 ] necessary for allowing metallic particles to reach the vicinity of the boiling point are irradiated to the metallic particles, each having a particle diameter of several hundred nanometers, the metallic particles being dispersed in a dispersion liquid during the irradiating with the laser beams, wherein the dispersion liquid does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles.
2. The manufacturing method for metal fine particles according to claim 1 , wherein the metal fine particles formed have a substantially spherical shape.
3. The manufacturing method for metal fine particles according to claim 1 , wherein the method further comprises manufacturing the metal fine particles, using, as a starting material, metallic foil pieces, the metallic foil pieces having a thickness not larger than 1 μm, and wherein the manufacturing of the metal fine particles includes irradiating laser beams directly to the metallic foil pieces, dispersed in the dispersion liquid to form the metal fine particles.
4. The manufacturing method for metal fine particles according to claim 3 , wherein the metallic foil pieces are foil piece-shaped metal flakes.
5. The manufacturing method for metal fine particles according to claim 3 , wherein an energy density of the laser beams irradiated directly to the metallic foil pieces, in forming the metal fine particles, is E th1 [J/cm 2 ] necessary for allowing the metallic foil pieces to reach the vicinity of the melting point.
6. A manufacturing method for metal fine particles by using metallic foil pieces as a starting material, comprising a step of dispersing the metallic foil pieces in a dispersion liquid; and a step of subsequently irradiating laser beams directly to the metallic foil pieces, characterized in that the dispersion liquid is a solvent consisting of chain or cyclic ketone.
7. A manufacturing method for metal fine particles by using metallic thin films as a starting material, comprising a step of immersing a substrate the top surface of which is formed with a metallic thin film in a solvent, wherein the metallic thin film has a thickness not larger than 1 μm, and wherein the solvent is a dispersion liquid that does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles; and a step of subsequently irradiating laser beams directly to the metallic thin film from the top surface or the back surface of the substrate.
8. The manufacturing method for metal fine particles according to claim 7 , wherein the metal fine particles formed have a substantially spherical shape.
9. A manufacturing method for metal fine particles each having a particle diameter of several tens nanometers, characterized in that laser beams, having at least an energy density not lower than an energy density E th2 [J/cm 2 ] necessary for allowing metallic foil pieces, having a thickness not larger than 1 μm, to reach the vicinity of the boiling point, are irradiated to the metallic foil pieces, the metallic foil pieces being dispersed in a dispersion liquid during the irradiating, wherein the dispersing liquid does not additionally contain a surface active agent or other protecting agent that restrains aggregation of the metal fine particles.
10. The manufacturing method for metal fine particles according to claim 9 , wherein said metallic foil pieces are foil piece-shaped metal flakes having the thickness not larger than 1 μm.
11. A manufacturing method for metal fine particles by using metallic thin films as a starting material, comprising a step of immersing a substrate, the top surface of which is formed with a metallic thin film, in a solvent, wherein the metallic thin film has a thickness not larger than 1 μm, and wherein the solvent is a dispersion liquid that does not contain sodium dodecyl sulfate; and a step of subsequently irradiating laser beams directly to the metallic thin film from the top surface or the back surface of the substrate.