Plasma etching method capable of detecting end point and plasma etching device therefor

1. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed, wherein

at least two steps of a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate are repeatedly implemented,

at least an emission intensity of Si or fluorinated silicon in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of Si or fluorinated silicon becomes equal to or less than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

2. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed, wherein

at least two steps of a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate are repeatedly implemented,

at least an emission intensity of F in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of F becomes equal to or more than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

3. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed, wherein

after a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate is implemented for a previously determined time, at least two steps of the large-amount supply step and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate are repeatedly implemented,

at least an emission intensity of Si or fluorinated silicon in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of Si or fluorinated silicon becomes equal to or less than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

4. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed, wherein

after a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate is implemented for a previously determined time, at least two steps of the large-amount supply step and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate are repeatedly implemented,

at least an emission intensity of F in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of F becomes equal to or more than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

5. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by repeatedly implementing: an etching step of etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed; and a passivation-layer forming step of forming a passivation-layer on a structural surface formed at the etching step by supplying passivation-layer forming gas containing fluorocarbon gas or O 2 gas so that plasma is formed, wherein

the etching step is configured by at least two steps of: a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate; and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate,

at least an emission intensity of Si or fluorinated silicon in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of Si or SiFx becomes equal to or less than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

6. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by repeatedly implementing: an etching step of etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed; and a passivation-layer forming step of forming a passivation-layer on a structural surface formed at the etching step by supplying passivation-layer forming gas containing fluorocarbon gas or O 2 gas so that plasma is formed, wherein

the etching step is configured by at least two steps of: a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate; and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate,

at least an emission intensity of F in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of F becomes equal to or more than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

7. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by repeatedly implementing: an etching step of etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed and a passivation-layer forming step of forming a passivation-layer on a structural surface formed at the etching step by supplying passivation-layer forming gas containing fluorocarbon gas or O 2 gas so that plasma is formed, wherein

the etching step and the passivation-layer forming step are repeatedly implemented for a previously determined number of times, and thereafter, the etching step is implemented by dividing into at least two steps of: a large-amount supply step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate; and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate,

at least an emission intensity of Si or fluorinated silicon in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of Si or fluorinated silicon becomes equal to or less than a previously set reference value, a determination is made that the etching end point is reached, a process is ended.

8. A plasma etching method capable of detecting an end point in which a Si film of a silicon substrate including the Si film formed on a surface side and a lower layer film formed below the Si film is etched, the plasma etching method for etching the Si film by repeatedly implementing: an etching step of etching the Si film by supplying etching gas containing SF 6 gas so that plasma is formed; and a passivation-layer forming step of forming a passivation-layer on a structural surface formed at the etching step by supplying passivation-layer forming gas containing fluorocarbon gas or O 2 gas so that plasma is formed, wherein

the etching step and the passivation-layer forming step are repeatedly implemented for a previously determined number of times, and thereafter, the etching step is implemented by dividing into at least two steps of: a large-supply amount step of supplying a large amount of SF 6 gas for performing high-speed etching on the silicon substrate; and a small-amount supply step at which a supply amount is reduced to supply a small amount of SF 6 gas for performing low-speed etching on the silicon substrate,

at least an emission intensity of F in the plasma at the small-amount supply step is measured,

only the emission intensity measured at the small-amount supply step is used to determine whether an etching end point where the lower layer film is exposed is reached, and

when the emission intensity of F becomes equal to or more than a previously set reference value, a determination is made that the etching end point is reached, and a process is ended.

9. The plasma etching method capable of detecting an end point according to any one of claims 1 to 8 , wherein at the large-amount supply step, SF 6 gas of 200 sccm or more is supplied, and at the small-amount supply step, SF 6 gas of 180 sccm or less is supplied.