Alternative paths to alcohols and hydrocarbons from biomass
A method of producing hydrocarbons from biomass that includes converting at least a portion of the biomass into a first product having at least one of a carboxylic acid, a ketone, an ammonium carboxylate salt, and combinations thereof; converting at least a portion of the first product into an alcohol; reacting at least some of the alcohol in an oligomerization reactor as part of a process that produces an oligomerization product.
1. A method of producing hydrocarbons from biomass, the method comprising:
converting at least a portion of the biomass into a first product comprising at least one of a carboxylic acid, a ketone, an ammonium carboxylate salt, and combinations thereof;
converting at least a portion of the first product into an alcohol;
reacting at least some of the alcohol in an oligomerization reactor as part of a process that produces an oligomerization product; and
separating hydrocarbons from the oligomerization product.
2. The method of claim 1 , wherein converting at least a portion of the first product into an alcohol comprises reacting the carboxylic acid to form an ester and hydrogenolyzing the ester to make an alcohol.
3. The method of claim 1 , wherein the first product comprises ketones, and wherein converting at least a portion of the first product into an alcohol further comprises hydrogenating ketones to make an alcohol.
4. The method of claim 1 , wherein the first product comprises ammonium carboxylate salts, and wherein converting at least a portion of the first product into an alcohol further comprises reacting ammonium carboxylate salts to form an ester and hydrogenolyzing the ester to make an alcohol.
5. The method of claim 1 , wherein the first product comprises carboxylic acids, and wherein converting at least a portion of the first product further comprises reacting carboxylic acids with an olefin to produce an ester; and hydrogenolyzing the ester to produce the alcohol.
6. The method of claim 1 , wherein converting at least a portion of the first product is carried out in the oligomerization reactor.
7. The method of claim 1 , the method further comprising:
separating a recycle stream from the oligomerization product;
processing the recycle stream in a reformer to produce hydrogen; and
using a least a portion of the produced hydrogen for the conversion reaction of the biomass to the first product.
8. A method of producing hydrocarbons from biomass, the method comprising:
converting at least a portion of the biomass into a first product comprising one of a carboxylic acid, a ketone, an ammonium carboxylate salt, and combinations thereof;
converting at least a portion of the first product into an alcohol;
reacting at least some of the alcohol in an oligomerization reactor under suitable reaction conditions to produce a second product comprising hydrocarbons; and
separating hydrocarbons from the second product.
9. The method of claim 8 , wherein converting at least a portion of the first product into an alcohol comprises: reacting carboxylic acid with an olefin to produce an ester; and
hydrogenolyzing the ester to produce the alcohol.
10. The method of claim 9 , wherein converting at least a portion of the first product is carried out in the oligomerization reactor.
11. The method of claim 10 , wherein reactions in the oligomerization reactor are carried out with at least one catalyst.
12. The method of claim 8 , the method further comprising:
separating a recycle stream from the second product;
processing the recycle stream in a reformer to produce hydrogen; and
using a least a portion of the produced hydrogen for the conversion reaction of the biomass to the first product.
13. The method of claim 12 , the method further comprising:
separating olefins from the recycle stream prior to processing the recycle stream in a reformer to produce hydrogen; and
providing the olefins to the oligomerization reactor for the reaction that produces the second product.
14. The method of claim 8 , the method further comprising:
separating a recycle stream from the second product;
separating olefins from the recycle stream; and
providing the olefins to the oligomerization reactor for the process that produces the second product.
15. A method of producing hydrocarbons from biomass, the method comprising:
converting biomass into a product stream comprising at least one of a carboxylic acid component, a carboxylate salt component, and combinations thereof;
reacting the product stream to produce an alcohol product; and
reacting at least some of the alcohol product in an oligomerization reactor as part of a process that produces an hydrocarbon oligomerization product.
16. The method of claim 15 , wherein reacting the product stream is carried out in the oligomerization reactor.
17. The method of claim 15 , the method further comprising:
separating a recycle stream from the hydrocarbon oligomerization product;
processing the recycle stream in a reformer to produce hydrogen; and
using a least a portion of the produced hydrogen for the conversion reaction of the biomass to the product stream.
18. The method of claim 16 , the method further comprising:
separating olefins from the recycle stream prior to processing the recycle stream in a reformer to produce hydrogen; and
providing the olefins to the oligomerization reactor for the reaction that produces the oligomerization product.
19. The method of claim 15 , the method further comprising:
separating a recycle stream from the hydrocarbon oligomerization product;
separating olefins from the recycle stream; and
providing the olefins to the oligomerization reactor for the process that produces the hydrocarbon oligomerization product.