Method for purifying flue gases from combustion plants and then producing urea
A method and apparatus is provided for cleaning flue gases from combustion plants. The method includes removing dust and removing nitrogen from flue gases, bringing flue gases into contact with an aqueous ammonia solution in the presence of an oxidizing agent whereby a reaction solution forms which contains at least ammonium carbonate, heating the reaction solution such that ammonium carbonate decomposes and carbon dioxide and ammonia transfer into the gas atmosphere, and reacting the gaseous carbon dioxide and the gaseous ammonia to form urea. The apparatus includes a device for removing nitrogen and removing dust from the flue gases, a washing device downstream of the device for removing nitrogen and removing dust, a stripper downstream of the washing device, and a urea installation downstream of the stripper.
1. An apparatus for cleaning flue gases from a combustion plant, including:
a device for removing nitrogen and removing dust from the flue gases,
a washing device downstream of the devices for removing nitrogen and removing dust, in which at least a portion of the flue gases is brought into contact with an aqueous ammonia solution in the presence of an oxidizing agent, whereby a reaction solution forms, which contains at least ammonium carbonate,
a stripper downstream of the washing device, in which the reaction solution is so treated that the ammonium carbonate contained in the reaction solution decomposes to form ammonia and carbon dioxide, and
a urea installation downstream of the stripper, in which ammonia and carbon dioxide are reacted to form urea.
2. The apparatus as claimed in claim 1 , wherein the apparatus further includes a device for desulfurization of the flue gases which is located upstream of the washing device.
3. The apparatus as claimed in claim 1 , wherein the apparatus further includes a device for synthesizing ammonia.
4. The apparatus as claimed in claim 1 , wherein the apparatus further includes a device downstream of the stripper for separating ammonium sulfate from the aqueous solution.
5. The apparatus as claimed in claim 4 , wherein the device for separating ammonium sulfate from the aqueous solution is a spray drying device.