IP Library › Granted Patent US 8,568,524
Granted Patent B2
US 8,568,524 · App. 13/072,267 · Granted Oct 29, 2013

Method for coating mineral granules to improve bonding to hydrocarbon-based substrate and coloring of same

Inventors: Bowen Li (Chassell, MI); Ralph Hodek (Chassell, MI); Domenic Popko (Lake Linden, MI); Jiann-Yang Hwang (Chassell, MI)
Assignee: Michigan Technology University
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Quick Facts
Patent No.
US 8,568,524
App. No.
13/072,267
Granted
Oct 29, 2013
Kind
B2
Abstract

Provided are compositions comprising stamp sand granules embedded in asphalt, where the stamp sand granules comprise a silane coating. Additionally provided are methods of making a silane-coated stamp sand, the methods comprising combining stamp sand granules and a silane solution to form a mixture and drying the mixture. Additionally provided are methods of covering a surface, the methods comprising combining silane-coated particles and asphalt to provide a mixture and distributing the mixture on the surface.

Claims (24)

1. A composition comprising:

stamp sand granules embedded in asphalt, wherein the stamp sand granules comprise a silane coating, wherein the silane coating comprises methyltrimethoxysilane.

2. The composition of claim 1 , wherein the stamp sand comprises a silica, a kaolinite, a talc, a limestone, a slate, a basalt, a nephelite, a bentonite, or a combination thereof.

3. The composition of claim 1 , wherein the stamp sand granules comprise about 9% 8-12 mesh granules, about 38% 12-16 mesh granules, about 30% 16-20 mesh granules, and about 15% 20-30 mesh granules.

4. The composition of claim 1 , wherein the stamp sand granules further comprise a pigment.

5. The composition of claim 4 , wherein the pigment comprises titanium oxide, kaolin, bentonite, red iron oxide, chrome oxide, chrome green, carbon black, metal ferrite, and mixtures thereof.

6. The composition of claim 1 , wherein the asphalt comprises a modified asphalt.

7. The composition of claim 1 , wherein the composition comprises an average adhesion, and the average adhesion is at least about 60% after the composition has soaked in water for about 3 days to about 10 days.

8. The composition of claim 1 , further comprising a paper, a fiberglass, or a combination thereof.

9. A method of making a silane-coated stamp sand, the method comprising:

combining stamp sand granules and a silane solution to form a mixture; and

drying the mixture,

wherein the silane solution comprises methyltrimethoxysilane.

10. The method of claim 9 , wherein the silane solution comprises at least about 0.10 wt. % of the mixture.

11. The method of claim 9 , wherein the stamp sand granules comprise a pigment.

12. The method of claim 11 , wherein the pigment comprises titanium oxide, kaolin, bentonite, red iron oxide, chrome oxide, chrome green, carbon black, metal ferrite, and mixtures thereof.

13. The method of claim 9 , wherein the stamp sand granules comprise a ceramic coating.

14. The method of claim 13 , wherein the ceramic coating comprises sodium silicate, a metal oxide, and bentonite clay.

15. The method of claim 13 , wherein the metal oxide comprises titanium oxide, red iron oxide, chrome oxide, metal ferrite, and mixtures thereof.

16. The method of claim 9 , wherein drying comprises heating the mixture from about 50° C. to about 110° C.

17. The method of claim 9 , wherein the stamp sand granules are not dry.

18. A method of covering a surface, the method comprising:

combining silane-coated particles and asphalt to provide a mixture; and

distributing the mixture on the surface, wherein the silane-coated particles comprise methyltrimethoxysilane.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 6, 2011
From: LI, BOWEN; HODEK, RALPH; POPKO, DOMENIC; HWANG, JIANN-YANG
To: MICHIGAN TECHNOLOGICAL UNIVERSITY
Reel/Frame 026550/0345 →
Continuity (2)
Provisional Application 61341010 · Mar 25, 2010
Related Publication 20110257295A1 · Oct 20, 2011