Directly fabricated nanoparticles for raman scattering
A Raman-active nanoparticle is provided that includes a dish-shape plasmonically active metal base, and a plasmonically active metal pillar disposed on the plasmonically active metal base, where the plasmonically active metal pillar is disposed within the dish-shape plasmonically active metal base and normal to a bottom of the dish-shape plasmonically active metal base, where a circular gap is disposed between the dish-shape plasmonically active metal pillar and inner walls of the dish-shape plasmonically active metal base. In one embodiment a Raman-active nanoparticle is provided that includes a dish-shape base having a dielectric material, an electrically conductive layer disposed on the inner surface of the dish-shape base, and an electrically conductive pillar disposed on the conductive layer, and within the dish-shape and perpendicular to a bottom of the dish-shape base, where a circular gap is disposed between the conductive pillar and inner walls of the dish-shape base.
1. A Raman-active nanoparticle comprising:
a. a circular base and a parallel-surface wall surrounding said circular base, wherein said circular base is a plasmonically active metal circular base; and
b. a plasmonically active metal circular pillar disposed on said plasmonically active metal circular base, wherein said plasmonically active metal circular pillar is disposed within said parallel-surface wall of said plasmonically active metal circular base and normal to a bottom of said plasmonically active metal circular base, wherein a circular gap is disposed between a side of said active metal circular pillar and an inner surface of said parallel-surface wall of said plasmonically active metal circular base.
2. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular base comprises a material selected from the group consisting of Ag, Au, Pt, Cu, and Al.
3. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular base comprises layered laminates and alloys.
4. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular pillar comprises material selected from the group consisting of Ag, Au, Pt, Cu, and Al.
5. The Raman-active nanoparticle of claim 4 , wherein said plasmonically active metal circular pillar comprises layered laminates and alloys.
6. The Raman-active nanoparticle of claim 1 , wherein said circular gap has a dimension in a range of 1 nm to 100 nm.
7. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular base is disposed on a dielectric material, wherein said dielectric material comprises a circular dielectric base and a parallel-surface dielectric wall surrounding said circular dielectric base.
8. The Raman-active nanoparticle of claim 7 , wherein said dielectric material comprises a material selected from the group consisting of SiO 2 , Al 2 O 3 , MgO, silicon nitride, titanium nitride, and indium tin oxide.
9. The Raman-active nanoparticle of claim 7 , wherein said dielectric parallel-surface wall has an outer diameter in a range of 10 nm to 1000 nm.
10. The Raman-active nanoparticle of claim 7 , wherein said dielectric parallel-surface wall has a wall thickness in a range of 1 nm to 100 nm.
11. The Raman-active nanoparticle of claim 7 , wherein said dielectric circular base dielectric material has a bottom thickness in a range of 1 nm to 100 nm.
12. The Raman-active nanoparticle of claim 7 , wherein said dielectric parallel-surface wall dielectric material has a height in a range of 2 nm to 100 nm.
13. The Raman-active nanoparticle of claim 7 , wherein said dielectric material comprises a material having a complex index of refraction (n+ik), wherein k has a value in a range between 0.0 and 0.5.
14. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular base has a thickness in a range of 1 nm to 100 nm.
15. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular pillar has a diameter in a range of 1 nm to 999 nm.
16. The Raman-active nanoparticle of claim 1 , wherein said plasmonically active metal circular pillar has a height in a range of 1 nm to 200 nm.
17. The Raman-active nanoparticle of claim 1 , wherein said nanoparticle comprises of at least one magnetic layer.
18. The Raman-active nanoparticle of claim 1 , wherein said nanoparticle comprises at least one magnetic coating.
19. The Raman-active nanoparticle of claim 1 , wherein said Raman-active nanoparticle comprises an array of said Raman-active nanoparticles on a substrate.