IP Library Granted Patent US 8,584,760
Granted Patent B2
US 8,584,760 · App. 13/144,002 · Granted Nov 19, 2013

Cleaning agents for wellbore cleaning and methods of use thereof

Inventors: Morris Arvie, Jr. (Houston, TX); Shaohua Lu (Houston, TX); Eugene Dakin (Langdon, CA)
Assignee: M-I L.L.C.
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Quick Facts
Patent No.
US 8,584,760
App. No.
13/144,002
Granted
Nov 19, 2013
Kind
B2
Abstract

A method of cleaning walls of a wellbore that includes contacting the walls with a cleaning fluid, the cleaning fluid comprising: a base fluid comprising a blend of a base oil and at least one of a mutual solvent or a terpene; and an alkyl glycoside is disclosed herein.

Claims (32)

1. A method of cleaning walls of a wellbore, comprising:

contacting the walls with a cleaning fluid, the cleaning fluid comprising:

a base fluid comprising a blend of a base oil and at least one of a mutual solvent or a terpene; and

an alkyl glycoside,

wherein the cleaning fluid is blended with a diluting fluid comprising an aqueous fluid or an oleaginous fluid.

2. The method of claim 1 , wherein the alkyl glycoside has an HLB of about 9 to about 15.

3. The method of claim 1 , wherein the alkyl glycoside has the formula RO—(R′O) x Z y where the letter O represents an oxygen atom; R represents a monovalent alkyl radical containing from 8 to 16 carbon atoms; R′ represents a divalent alkyl radical containing 2 to 4 carbon atoms; x represents the number of oxy-alkylene units in the alkyl glycoside varying from 0 to about 12; Z represents a saccharide moiety containing 5 or 6 carbon atoms, and y represents the number of saccharide units in the glycoside.

4. The method of claim 3 , wherein y ranges from 1.3 to 1.8.

5. The method of claim 1 , wherein the base oil comprises mineral oil or diesel.

6. The method of claim 1 , wherein the mutual solvent comprises at least one compound selected from the group consisting of ethylene glycol, ethylene glycol monobutyl ether, and butyl carbitol.

7. The method of claim 1 , wherein the cleaning fluid comprises from about 5% to about 40% of alkyl glycoside and about 60% to about 95% of the base fluid.

8. The method of claim 7 , wherein cleaning fluid comprises from 10 to 50% by volume of a base oil, about 10 to 45% by volume of a mutual solvent, about 10 to 40% by volume of a terpene, and about 5 to 40% by volume of an alkyl glycoside.

9. The method of claim 1 , wherein the cleaning fluid and diluting fluid are mixed about to 50 percent by volume cleaning fluid and about 50 to 95 percent by volume diluting fluid.

10. A method of cleaning a casing in a wellbore having an oil-based fluid contained therein, comprising:

injecting diesel to displace the oil-based fluid;

injecting a weighted spacer fluid to displace the diesel;

injecting a cleaning fluid to displace the weighted spacer fluid, the cleaning fluid comprising:

a base fluid comprising a blend of a base oil and at least one of a mutual solvent or a terpene; and

a surfactant at least one alkyl glycoside; and

injecting a brine to displace the cleaning fluid.

11. The method of claim 10 , wherein the brine has at least one viscosifier contained therein.

12. The method of claim 10 , wherein the injecting the cleaning fluid comprises injecting the cleaning fluid at a rate sufficient to cause turbulent flow.

13. The method of claim 10 , wherein at least one injecting step comprises injecting at a rate sufficient to cause turbulent flow.

14. The method of claim 10 , wherein the surfactant has an HLB of about 9 to about 15.

15. The method of claim 10 , wherein the alkyl glycoside has the formula RO—(R′O) x Z y where the letter O represents an oxygen atom; R represents a monovalent alkyl radical containing from 8 to 16 carbon atoms; R′ represents a divalent alkyl radical containing 2 to 4 carbon atoms; x represents the number of oxy-alkylene units in the alkyl glycoside varying from 0 to about 12; Z represents a saccharide moiety containing 5 or 6 carbon atoms, and y represents the number of saccharide units in the glycoside.

16. The method of claim 15 , wherein y ranges from 1.3 to 1.8.

17. The method of claim 10 , wherein the base oil comprises mineral oil or diesel.

18. The method of claim 10 , wherein the mutual solvent comprises at least one compound selected from the group consisting of ethylene glycol, ethylene glycol monobutyl ether, and butyl carbitol.

19. The method of claim 10 , wherein the cleaning fluid comprises from about 5% to about 40% of alkyl glycoside and about 60% to about 95% of the base fluid.

20. The method of claim 19 , wherein cleaning fluid comprises from 10 to 50% by volume of a base oil, about 10 to 45% by volume of a mutual solvent, about 10 to 40% by volume of a terpene, and about 5 to 40% by volume of an alkyl glycoside.

21. The method of claim 10 , wherein the cleaning fluid is blended with a diluting fluid comprising an aqueous fluid or an oleaginous fluid.

22. The method of claim 21 , wherein the cleaning fluid and diluting fluid are mixed about 5 to 50 percent by volume cleaning fluid and about 50 to 95 percent by volume diluting fluid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2011
From: ARVIE, MORRIS, JR.; LU, SHAOHUA; DAKIN, EUGENE
To: M-I L.L.C.
Reel/Frame 026583/0390 →
Continuity (2)
Provisional Application 61148878 · Jan 15, 2009
Related Publication 20110272160A1 · Nov 10, 2011