IP Library Granted Patent US 8,592,325
Granted Patent B2
US 8,592,325 · App. 12/685,332 · Granted Nov 26, 2013

Insulating layers on different semiconductor materials

Inventors: Joseph F. Shepard, Jr. (Hopewell Junction, NY); Siddarth A. Krishnan (Hopewell Junction, NY); Rishikesh Krishnan (Hopewell Junction, NY); Michael P. Chudzik (Hopewell Junction, NY)
Assignee: International Business Machines Corporation
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Quick Facts
Patent No.
US 8,592,325
App. No.
12/685,332
Granted
Nov 26, 2013
Kind
B2
Abstract

A method of creating insulating layers on different semiconductor materials includes providing a substrate having disposed thereon a first material and a second material, the second material having a chemical composition different from the first material; non-epitaxially depositing a continuous sacrificial layer of approximately constant thickness onto the first material and the second material, and then converting the sacrificial layer into a layer consisting essentially of SiO 2 without oxidizing more than 10 angstroms into the second material. A structure includes a silicon nitride film disposed conformally on a silicon layer and a silicon germanium layer; a SiO 2 layer is disposed on the silicon nitride film.

Claims (33)

1. A method of creating insulating layers on different semiconductor materials, comprising:

providing a substrate having a first semiconductor region and a second semiconductor region, wherein said first semiconductor region comprises a first semiconductor material of a first crystal orientation having a first uppermost surface, and said second region comprises said first semiconductor material having a second uppermost surface which is located adjacent to and beneath said first uppermost surface;

epitaxially growing a second semiconductor material on said second uppermost surface, wherein said second semiconductor material has said first crystal orientation and a chemical composition different from said first semiconductor material;

forming a trench isolation region between sidewall edges of the first semiconductor material and the second semiconductor material, said trench isolation region having a depth extending into a portion of the substrate;

non-epitaxially depositing a continuous sacrificial layer of approximately constant thickness onto the first semiconductor material, the second semiconductor material and an upper surface of the trench isolation region; and

converting the sacrificial layer into a layer consisting essentially of SiO 2 without oxidizing more than 10 angstroms into the second semiconductor material, wherein said converting the sacrificial layer into a layer consisting essentially of SiO 2 comprises radical oxidation at a temperature of about 900° C.

2. The method as claimed in claim 1 , wherein the first semiconductor material is silicon and the second semiconductor material is silicon germanium.

3. The method as claimed in claim 1 , wherein the non-epitaxially depositing comprises depositing the continuous sacrificial layer using molecular layer deposition.

4. The method as claimed in claim 1 , wherein the continuous sacrificial layer has an approximately constant thickness in a range from approximately 10 angstroms to approximately 50 angstroms.

5. The method as claimed in claim 1 , wherein the continuous sacrificial layer comprises silicon nitride.

6. The method as claimed in claim 1 , wherein the continuous sacrificial layer comprises amorphous silicon.

7. The method as claimed in claim 1 , wherein the continuous sacrificial layer comprises polycrystalline silicon.

8. The method as claimed in claim 1 , wherein the continuous sacrificial layer comprises silicon carbide.

9. The method as claimed in claim 1 , wherein the converting includes converting the sacrificial layer entirely into an SiO 2 layer.

10. A method of creating insulating layers on different semiconductor materials, comprising:

providing a substrate comprising a first semiconductor material and having a first crystal orientation, said first semiconductor material consisting essentially of Si;

recessing a portion of said substrate providing a structure comprising a first semiconductor region of said first semiconductor material having an uppermost surface and a second semiconductor region of said first semiconductor material comprising a second uppermost surface, said second uppermost surface is located adjacent to and beneath said first uppermost surface;

epitaxially growing a second semiconductor material having a different chemical composition than said first semiconductor material from said second uppermost surface, said second semiconductor material having said first crystal orientation;

forming a trench isolation region between sidewall edges of the first semiconductor material and the second semiconductor material, said trench isolation region having a depth extending into a portion of the substrate;

molecular layer depositing a continuous silicon nitride layer of approximately constant thickness conformally onto the first semiconductor material, the second semiconductor material and an upper surface of the trench isolation region; and

converting the silicon nitride layer into a layer consisting essentially of SiO 2 without oxidizing more than 10 angstroms into the second semiconductor material, wherein said converting the silicon nitride layer into a layer consisting essentially of SiO 2 comprises radical oxidation at a temperature of about 900° C.

11. The method as claimed in claim 10 , wherein the approximately constant thickness is in a range from approximately 10 angstroms to approximately 50 angstroms.

12. The method as claimed in claim 10 , wherein the second semiconductor material consists essentially of SiGe.

13. The method as claimed in claim 10 , wherein the silicon nitride layer is entirely converted into SiO 2 without oxidizing any of the second semiconductor material.

14. The method as claimed in claim 13 , wherein the second material layer consists essentially of SiGe.

15. The method as claimed in claim 1 , wherein said converting the silicon nitride layer into a layer consisting essentially of SiO 2 comprises a pressure of 7 T and with a hydrogen concentration of 5%.

16. The method as claimed in claim 10 , wherein said converting the silicon nitride layer into a layer consisting essentially of SiO 2 comprises a pressure of 7 T and with a hydrogen concentration of 5%.

17. A method of creating insulating layers on different semiconductor materials, comprising:

providing a substrate having a first semiconductor region and a second semiconductor region, wherein said first semiconductor region comprises a first semiconductor material of a first crystal orientation having a first uppermost surface, and said second region comprises said first semiconductor material having a second uppermost surface which is located adjacent to and beneath said first uppermost surface;

epitaxially growing a second semiconductor material on said second uppermost surface, wherein said second semiconductor material has said first crystal orientation and a chemical composition different from said first semiconductor material;

forming a trench isolation region between sidewall edges of the first semiconductor material and the second semiconductor material, said trench isolation region having a depth extending into a portion of the substrate;

non-epitaxially depositing a continuous sacrificial layer of approximately constant thickness onto the first semiconductor material, the second semiconductor material and an upper surface of the trench isolation region; and

converting the sacrificial layer into a layer consisting essentially of SiO 2 without oxidizing more than 10 angstroms into the second semiconductor material, wherein said converting the sacrificial layer into a layer consisting essentially of SiO 2 comprises wet oxidation.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 1, 2010
From: SHEPARD, JR., JOSEPH P.; KRISHNAN, SIDDARTH A.; KRISHNAN, RISHIKESH; CHUDZIK, MICHAEL P.
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 023876/0354 →
Continuity (1)
Related Publication 20110169141A1 · Jul 14, 2011