Ink, ink cartridge, and ink jet recording method
Provided are an ink with which an image excellent in both black density and glossiness can be recorded, and an ink cartridge and an ink jet recording method each using the ink. The ink includes: a carbon black; a resin for dispersing the carbon black; a resin fine particle; and a water-soluble organic solvent, in which: the resin fine particle contains at least a unit derived from an ethylenically unsaturated hydrophobic monomer, and a unit derived from a monomer selected from an ethylenically unsaturated acid monomer and a salt thereof, and a ratio of a unit derived from a saturated alkyl group-containing monomer to the unit derived from the ethylenically unsaturated hydrophobic monomer is 95.0 mass % or more; and the water-soluble organic solvent contains a water-soluble organic solvent having a dielectric constant at 20° C. of 18.0 or more and less than 30.0.
1. An ink, comprising:
a carbon black;
a resin for dispersing the carbon black;
a resin fine particle; and
a water-soluble organic solvent,
wherein:
the resin fine particle comprises at least a unit derived from an ethylenically unsaturated hydrophobic monomer, and a unit derived from a monomer selected from an ethylenically unsaturated acid monomer and a salt thereof, and a ratio of a unit derived from a saturated alkyl group-containing monomer to the unit derived from the ethylenically unsaturated hydrophobic monomer is 95.0 mass % or more; and
the water-soluble organic solvent comprises a water-soluble organic solvent having a dielectric constant at 20° C. of 18.0 or more and less than 30.0.
2. An ink according to claim 1 , wherein a mass ratio of a content (mass %) of the resin fine particle to a content (mass %) of the water-soluble organic solvent having a dielectric constant at 20° C. of 18.0 or more and less than 30.0 based on a total mass of the ink is 0.10 times or more and 1.0 times or less.
3. An ink according to claim 1 , wherein a content (mass %) of the resin fine particle based on a total mass of the ink is 0.30 mass % or more and 5.0 mass % or less.
4. An ink according to claim 1 , wherein a mass ratio of a content (mass %) of the resin for dispersing the carbon black to a content (mass %) of the carbon black based on a total mass of the ink is 0.15 times or more and 0.30 times or less.
5. An ink according to claim 1 , further comprising a water-soluble urethane resin, wherein a mass ratio of a content (mass %) of the water-soluble urethane resin to a content (mass %) of the carbon black based on a total mass of the ink is 0.15 times or more and 0.30 times or less.
6. An ink according to claim 5 , wherein the water-soluble urethane resin has a poly(oxytetramethylene) structure.
7. An ink according to claim 1 , wherein the resin fine particle is polymerized by employing a soap-free polymerization method.
8. An ink according to claim 1 , wherein the saturated alkyl group-containing monomer comprises a (meth)acrylic ester of a saturated aliphatic primary alcohol having a chain structure.
9. An ink cartridge, comprising an ink and an ink storage portion for storing the ink, wherein the ink comprises the ink according to claim 1 .
10. An ink jet recording method, comprising ejecting ink from a recording head according to an ink jet system to record an image on a recording medium, wherein the ink comprises the ink according to claim 1 .
11. An ink jet recording method according to claim 10 , wherein the recording medium is a glossy paper.
12. An ink according to claim 1 , wherein the water-soluble organic solvent having a dielectric constant at 20° C. of 18.0 or more and less than 30.0 is at least one selected from the group consisting of 1,2,6-hexanetriol, 2-pyrrolidone, 1,5-pentanediol, 3-methyl-1,5-pentanediol, and polyethylene glycol having an average molecular weight of 200.
13. An ink according to claim 1 , wherein a content (mass %) of the water-soluble organic solvent having a dielectric constant at 20° C. of 18.0 or more and less than 30.0 is 0.5 mass % or more and 10.0 mass % or less based on the total mass of the ink, and a content (mass %) of the water-soluble organic solvent is 3.0 mass % or more and 50.0 mass % or less based on the total mass of the ink.
14. An ink according to claim 1 , wherein the resin for dispersing the carbon black is a water-soluble resin that is a copolymer having at least a hydrophilic unit derived from (meth)acrylic acid and a hydrophobic unit derived from an aromatic ring-containing monomer.
15. An ink according to claim 5 , wherein the water-soluble urethane resin is a polyether-based urethane resin.