Flexible, molded or extruded articles and semiconductive compounds for their manufacture
View Patent ↗A molded or extruded article, e.g., an electrical part or shielded cable, comprises at least one insulation layer and at least one semiconductive layer, the semiconductive layer thick and comprising in weight percent: A. 1 to 30 wt % of conductive filler; B. 10 to 90 wt % of a non-olefin elastomer; C. 10 to 90 wt % of an olefin elastomer; and D. Optionally, 0.5 to 2.5 wt % of peroxide. Carbon black and/or metal particulates or powder typically comprise the filler, silicone or urethane rubber the non-olefin elastomer, and EPR or EPDM the olefin elastomer.
1. A molded or extruded article comprising at least one insulation layer and at least one semiconductive layer, the semiconductive layer comprising in weight percent:
A. 20 to 30 wt % of conductive filler comprising conductive carbon black;
B. polymers consisting of
(i) 20 to 80 wt % of a non-olefin elastomer selected from the group consisting of silicone rubber, urethane rubber, and combinations thereof; and
(ii) 20 to 80 wt % of an olefin elastomer selected from the group consisting of polyolefin homopolymers, ethylene/α-olefin interpolymers propylene/α-olefin interpolymers, and combinations thereof; and
C. optionally, 0.5 to 2.5 wt % of peroxide.
2. The article of claim 1 in which the article is an electrical part of shielded cable.
3. The article of claim 2 in which the article further comprises a second semiconductive layer and the insulation layer is between the first and second semiconductive layers.
4. The article of claim 2 in which the conductive filler comprise a metal particulate or powder.
5. The article of claim 2 in which the conductive filler comprise a blend of carbon black and metal particulate or powder.
6. The article of claim 2 in which the olefin elastomer is at least one of an ethylene-propylene rubber and an ethylene-propylene-diene monomer rubber.
7. The article of claim 6 in which the olefin elastomer is a linear, homogeneously branched polyethylene resin.
8. The article of claim 2 in which the non-olefin and olefin elastomers are present at a non-olefin:olefin elastomer weight ratio between 10:90 and 90:10.
9. The article of claim 2 in which the semiconductive layer further comprises at least one additive.
10. The article of claim 9 in which at least one additive is a plasticizer oil.
11. The article of claim 1 in which the insulation layer comprises a silane-grafted polyolefin or silane-olefin copolymer crosslinked with hydroxyl-terminated silicone.
12. The article of claim 3 in which the insulation layer comprises one or more of an olefin elastomer, olefin block copolymer, EPDM, EPR or silicone.
13. A semi-conductive composition comprising, based on the weight of the composition:
A. 20 to 30 wt % of conductive filler comprising conductive carbon black;
B. polymers consisting of
(i) 20 to 80 wt % of a non-olefin elastomer selected from the group consisting of silicone rubber, urethane rubber, and combinations thereof; and
(ii) 20 to 80 wt % of an olefin elastomer selected from the group consisting of polyolefin homopolymers, ethylene/α-olefin interpolymers propylene/α-olefin interpolymers, and combinations thereof; and
C. optionally, 0.5 to 2.5 wt % of peroxide.