Coating compositions for cans and methods of coating
A coating composition for a food or beverage can that includes an emulsion polymerized latex polymer formed by combining an ethylenically unsaturated monomer component with an aqueous dispersion of a water-dispersible polymer.
1. A method, comprising the steps of:
(a) providing a latex-based coating composition that includes one or more polymers, wherein the one or more polymers are formed by polymerizing one or more ethylenically unsaturated monomers, wherein the ethylenically unsaturated monomers include (i) one or more oxirane functional group-containing monomers, (ii) one or more acid-functional monomers and (iii) one or more additional ethylenically unsaturated monomers selected from butyl (meth)acrylate or styrene, wherein the one or more oxirane functional-group containing monomers are polymerized into the one or more polymers using an emulsion polymerization, and wherein the coating composition is not made using PVC compounds and is substantially free of bound BPA and aromatic glycidyl ether compounds; and
(b) spray applying the coating composition to an interior surface of a food or beverage can or a portion thereof.
2. The method of claim 1 , wherein the one or more oxirane functional group-containing monomers comprises a glycidyl ester of an alpha, beta-unsaturated acid or anhydride thereof.
3. The method of claim 1 , wherein the one or more oxirane functional group-containing monomers comprises glycidyl (meth)acrylate.
4. The method of claim 1 , wherein the ethylenically unsaturated monomers include glycidyl (meth)acrylate, butyl acrylate, and styrene.
5. The method of claim 1 , wherein the ethylenically unsaturated monomers including methacrylic acid.
6. The method of claim 1 , wherein the ethylenically unsaturated monomers include one or more hydroxyl alkyl (meth)acrylate.
7. The method of claim 1 , wherein the coating composition is spray applied onto at least a portion of an interior surface of an aluminum beverage can or a portion thereof.
8. The method of claim 1 , wherein the coating composition includes a tertiary amine.
9. The method of claim 1 , wherein the coating composition comprises a quaternary salt linkage.
10. The method of claim 1 , wherein one or more of the one or more polymers has an acid number of at least 40 milligrams KOH per gram resin.
11. The method of claim 1 , wherein one or more of the one or more polymers is an acid- or anhydride-functional acrylic polymer having an acid number of at least 40 milligrams KOH per gram resin.
12. The method of claim 1 , wherein the coating composition includes a surfactant.
13. The method of claim 1 , wherein the coating composition includes a strong acid.
14. The method of claim 13 , wherein the strong acid comprises dodecylbenzene sulphonic acid.
15. The method of claim 13 , wherein the strong acid is present in an amount of from at least 0.01% by weight to no greater than 3% by weight, based on the weight of nonvolatile material.
16. A method, comprising the steps of:
(a) providing an aqueous coating composition that includes a latex polymer that is substantially free of bound BPA and aromatic glycidyl ether compounds and is made without using PVC compounds, wherein the latex polymer is formed by emulsion polymerizing a mixture of ethylenically unsaturated monomers comprising 0.1 to 30 weight percent oxirane functional group-containing monomer, based on the weight of the mixture, in the presence of an acid- or anhydride-functional polymer; and
(b) spray applying the coating composition to an interior surface of a food or beverage can or a portion thereof.
17. The method of claim 16 , wherein the oxirane functional group-containing monomer comprises a glycidyl ester of an alpha, beta-unsaturated acid or anhydride thereof.
18. The method of claim 16 , wherein oxirane functional group-containing monomer comprises glycidyl (meth)acrylate.
19. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomer includes at least one additional ethylenically unsaturated monomer selected from butyl (meth)acrylate or styrene.
20. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomers includes glycidyl (meth)acrylate, butyl acrylate, and styrene.
21. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomers comprises at least 20 weight percent of vinyl aromatic compounds.
22. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomers comprises at least 40 weight percent of alkyl (meth)acrylates.
23. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomers comprises at least 40 weight percent of alkyl (meth)acrylates and at least 20 weight percent of vinyl aromatic compounds.
24. The method of claim 16 , wherein the coating composition includes a strong acid.
25. The method of claim 16 , wherein the coating composition includes dodecylbenzene sulphonic acid.
26. The method of claim 16 , wherein the coating composition includes a surfactant.
27. The method of claim 16 , wherein the coating composition includes a tertiary amine.
28. The method of claim 16 , wherein the coating composition comprises a quaternary salt linkage.
29. The method of claim 16 , wherein the coating composition is substantially free of mobile and bound BPA and aromatic glycidyl ether compounds.
30. The method of claim 16 , wherein the mixture of ethylenically unsaturated monomers includes glycidyl (meth)acrylate and styrene.
31. The method of claim 30 , wherein the mixture of ethylenically unsaturated monomers includes at least 20 weight percent of styrene.
32. The method of claim 16 , wherein the acid- or anhydride-functional polymer comprises an acrylic polymer.
33. The method of claim 32 , wherein the acrylic polymer is formed from ethylenically unsaturated monomers including methacrylic acid.
34. The method of claim 32 , wherein the acrylic polymer has an acid number of at least 40 milligrams KOH per gram resin.
35. A method, comprising the steps of:
(a) providing an aqueous coating composition that includes a latex polymer that is substantially free of bound BPA and aromatic glycidyl ether compounds, wherein the latex polymer is formed by emulsion polymerizing a mixture of ethylenically unsaturated monomers comprising butyl acrylate, styrene, and 0.1 to 30 weight percent of oxirane functional group-containing monomer, based on the weight of the mixture, in the presence of an acid- or anhydride-functional acrylic polymer having an acid number of at least 40 milligrams KOH per gram resin; and
(b) spray applying the coating composition to an interior surface of a food or beverage can or a portion thereof.