Ink jet ink, ink cartridge, and ink jet recording method
An ink jet ink including a pigment and an ABC triblock polymer, wherein the above-described ABC triblock polymer is formed from an A block having an aryl group, a B block having a unit represented by the following general formula (1), and a C block having a unit represented by the following general formula (2).
1. An ink jet ink comprising:
a pigment and an ABC triblock polymer,
wherein the ABC triblock polymer is formed from an A block having an aryl group, a B block having a unit represented by the following general formula (1), and a C block having a unit represented by the following general formula (2),
in the general formula (1), R B1 represents a hydrogen atom or a methyl group and R B2 represents an alkyl group having the carbon number of 1 to 8, a cycloalkyl group having the carbon number of 4 to 8, or a hydroxy alkyl group having the carbon number of 2 to 8, and
in the general formula (2), at least one of R C1 to R C4 is a —COOH group, an —R C5 —COOH group, or a salt thereof, the remainder is a hydrogen atom, an alkyl group having the carbon number of 1 to 8, or a cycloalkyl group having the carbon number of 4 to 8, and R C5 is an alkylene group having the carbon number of 1 to 5
2. The ink jet ink according to claim 1 , wherein an acid value of the ABC triblock polymer is 20 mgKOH/g or more and 150 mgKOH/g or less.
3. The ink jet ink according to claim 1 , wherein the proportion (percent by mass) of the A block in the ABC triblock polymer is 20.0 percent by mass or more and 80.0 percent by mass or less relative to a total mass of the ABC triblock polymer.
4. The ink jet ink according to claim 1 , wherein a number average molecular weight of the ABC triblock polymer is 1,000 or more and 30,000 or less.
5. The ink jet ink according to claim 1 , wherein the ABC triblock polymer has a molecular weight distribution satisfying 1.0≦(weight average molecular weight)/(number average molecular weight)≦2.0.
6. The ink jet ink according to claim 1 , wherein the proportion (percent by mass) of the A block in the ABC triblock polymer is 5.0 times or more and 15.0 times or less the proportion (percent by mass) of units derived from all acidic monomers contained in the ABC triblock polymer.
7. The ink jet ink according to claim 1 , wherein the ratio of the number average molecular weight of the ABC triblock polymer to the acid value of the ABC triblock polymer is 50 or more and 200 or less.
8. The ink jet ink according to claim 1 , wherein the content (percent by mass) of the ABC triblock polymer in the ink jet ink is 0.2 times or more and 0.5 times or less the content (percent by mass) of the pigment on a mass ratio basis.
9. The ink jet ink according to claim 1 , wherein the ink further comprises a polyurethane polymer emulsion having a unit derived from a polyether polyol.
10. The ink jet ink according to claim 9 , wherein the content (percent by mass) of the polyurethane polymer emulsion relative to a total mass of the ink is 0.10 times or more and 0.70 times or less the content (percent by mass) of the pigment on a mass ratio basis.
11. The ink jet ink according to claim 9 , wherein the content (percent by mass) of the polyurethane polymer emulsion relative to a total mass of the ink is 0.30 times or more and less than 1.00 time of the content (percent by mass) of the ABC triblock polymer on a mass ratio basis.
12. The ink jet ink according to claim 9 , wherein the polyether polyol is a polypropylene glycol.
13. An ink cartridge comprising an ink storage portion to store an ink, wherein the ink stored in the ink storage portion is the ink jet ink according to claim 1 .
14. An ink jet recording method comprising the step of ejecting an ink by an ink jet method from an ink jet recording head to perform recording on a recording medium, wherein the ink is the ink jet ink according to claim 1 .