IP Library Granted Patent US 8,647,550
Granted Patent B2
US 8,647,550 · App. 13/164,372 · Granted Feb 11, 2014

Process for introducing an additive into a polymer melt

Inventors: Kevin Philip Nelson (Appleton, WI); Dan G Siegel (Belleville, IL)
Assignee: Curwood, Inc.
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Quick Facts
Patent No.
US 8,647,550
App. No.
13/164,372
Granted
Feb 11, 2014
Kind
B2
Abstract

A process includes introducing a base polymer into an extruder, heating to a temperature sufficient to form a polymer melt, introducing a liquid comprising water and at least one additive consisting of an NO donating compound with mixing and subsequent vaporization and venting of the liquid to produce an extrudate having a uniform distribution of preferably uniformly small additive particles.

Claims (27)

1. A process comprising: a) introducing at least one base: polymer into an extruder; b) heating the base polymer to a temperature sufficient to form a polymer melt; c) introducing into the extruder a liquid comprising water and at least one additive; wherein the additive is an NO donating compound; d) mixing the liquid with the polymer melt in the extruder to form a blend; e) vaporizing at least a portion offline liquid and removing it: from the polymer melt; and f) extruding the additive containing polymer through an extruder die; wherein the base polymer is selected from the group consisting of polyolefin, polyethylene polypropylene, ethylene vinyl acetate, EMA, EEA, EMAA, polybutene-1 and mixtures thereof.

2. The process of claim 1 , wherein the additive is a salt.

3. The process of claim 1 , wherein the additive is an inorganic salt.

4. The process of claim 1 ,wherein the additive in an undissolved state is a solid at 23° C.

5. The process of claim 2 , wherein the salt is selected from the group consisting of nitrite salts, nitrate salts, and mixtures thereof.

6. The process of claim 2 , wherein the salt is selected from the group consisting of sodium nitrite, sodium nitrate, and mixtures thereof.

7. The process of claim 1 , wherein the polymer is a polyester, ionomer, or nylon.

8. The process of claim 1 , wherein the polymer is heated to a temperature above a melting point of the polymer.

9. The process of claim 1 , wherein the polymer is an amorphous polymer and is heated to a temperature above a glass transition point of the polymer.

10. The process of claim 1 , wherein the polymer is heated to a temperature above about 275° F.

11. The process of claim 1 , wherein the polymer is heated to a temperature less than 100° F. above a melting point of the polymer.

12. The process of claim 1 , wherein the liquid comprises between about 20 wt % and about 60 wt % additive.

13. The process of claim 2 , wherein the introduced liquid comprises between about 20 wt % and about 42 wt % salt.

14. The process of claim 2 , wherein the introduced liquid comprises between about 30 wt % and about 40 wt % salt.

15. The process of claim 2 , wherein a sufficient amount of the liquid is introduced into the polymer melt to obtain a blend comprising between about 2 wt % and about 10 wt % salt.

16. The process of claim 2 , wherein a sufficient amount of the liquid is introduced into the polymer melt to obtain a blend comprising between about 4 wt % and about 6 wt % salt.

17. The process of claim 1 , wherein at least 10 wt. % of the liquid is removed.

18. The process of claim 1 , wherein at least 50 wt. % of the liquid is removed.

19. The process of claim 1 , wherein at least 90 wt. % of the liquid is removed.

20. The process of claim 1 , wherein at least 98 wt. % of the liquid is removed.

21. The process of claim 1 , wherein the liquid is removed by venting.

22. The process of claim 1 , wherein the liquid is removed by venting with a vacuum assist.

23. The process of claim 1 wherein the extruder includes a base polymer feed port and an injection port located at a position downstream of the base polymer feed port, wherein the solution is injected through the injection port.

24. The process of claim 22 , located wherein the extruder includes a vent located at a position downstream from the injection port, further comprising venting vapor through the vent.

25. The process of claim 23 , further comprising at least restriction device downstream of the base polymer feed port and upstream of the solution feed port.

26. The process of claim 1 , further comprising dissolving the additive in water to form the liquid solution.

27. The process of claim 1 , further comprising dispersing the additive in water to form a solid in liquid dispersion or emulsion.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2017
From: NELSON, KEVIN PHILIP; SIEGEL, DAN G.
To: CURWOOD, INC.
Reel/Frame 043426/0820 →
MERGER Recorded Aug 28, 2017
From: CURWOOD, INC.
To: BEMIS COMPANY, INC.
Reel/Frame 043426/0855 →
Continuity (2)
Continuation 11408221 · Apr 20, 2006
Related Publication 20120259052A1 · Oct 11, 2012