High pressure reduction-oxidation desulfurization process
An improved process for reduction-oxidation desulphurization uses an oxidizer operating at a pressure greater than the absorber where a liquid reduction-oxidation catalyst solution contacts a sulfur-containing gas feed stream.
1. A desulfurization process comprising the following steps in combination:
a. continuously feeding a stream of sour hydrocarbon gas containing hydrogen sulfide to an absorber operating at a pressure P1, where P1 is >100 psig;
b. contacting the sour gas with an aqueous catalyst solution within the absorber to convert the hydrogen sulfide to elemental solid sulfur and generating a spent catalyst solution containing the solid sulfur;
c. removing a gas stream from the absorber;
d. pumping the spent catalyst solution containing the solid sulfur into an oxidizer operating a pressure P2, where P2>P1+5 psi;
e. controlling the pressure of the oxidizer by monitoring the absorber pressure and controlling a valve on the oxidizer vent line;
f. oxidizing the spent catalyst solution using pressurized air within the oxidizer to form a regenerated catalyst solution;
g. separating and removing the solid sulfur from the regenerated catalyst solution from the oxidizer; and
h. removing the regenerated catalyst solution from the oxidizer.
2. The process of claim 1 where the pressurized air is fed to the oxidizer at a pressure P3, where P3>P2.
3. The process of claim 1 where the pressurized air is used to maintain the pressure differential between the oxidizer and the absorber.
4. The process of claim 1 further comprising the absence of a flash drum in fluid communication with the absorber and the oxidizer.
5. The process of claim 1 where the aqueous catalyst solution in the absorber comprises the regenerated catalyst solution removed from the oxidizer.
6. The process of claim 1 where the aqueous catalyst solution comprises a chelated iron catalyst.