Process to produce sodium sulfate and magnesium hydroxide
This invention refers to a novel process to obtain magnesium hydroxide and sodium sulfate from a solid raw material, which contains sodium and magnesium soluble salts, preferably in the form of sulfates, coming from a natural source or as a byproduct of an industrial process. The process consisting in the conditioning of the raw material to guarantee the correct concentrations of sodium and magnesium sulfates that is subjected to a salting-out crystallization when mixed with sodium sulfate obtaining sodium sulfate; the resulting solution is subjected to an alkali treatment to precipitate the magnesium hydroxide and the mother liquor is fed to a regeneration stage of the alkali used in the precipitation of the magnesium hydroxide as well in the sodium sulfate solution for the crystallization. The crystallization can be performed as a multistage process countercurrent to increase the purity of sodium sulfate.
1. A process to obtain sodium sulfate and magnesium hydroxide from a mixture or compound containing salts sodium and magnesium soluble salts consisting in the following stages:
a. Conditioning the raw material by means of a prior treatment,
b. Mixing the raw material treated with a solution abundant in sodium sulfate to crystallize the sodium sulfate in the mixture, as final product,
c. Reacting the crystallization remaining solution of the sodium sulfate in the mixture mentioned in the step b) with an alkali, and precipitate the magnesium hydroxide formed, as final product,
d. Regenerating the alkali by treating the mother liquor of the above stage, and
e. Recirculating the alkali regenerated in the stage before stage c) and recirculating the solution abundant in sodium sulfate to stage b).
2. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein the mixture or compound used as raw material is found in its solid state.
3. A process to obtain sodium sulfate and magnesium hydroxide according to claim 2 , wherein the raw material is a natural mineral selected from the group that includes Bloedite, Loewite, Vanthoffite, Dansite, Neighborite, Humberstonite and Konyaite.
4. A process to obtain sodium sulfate and magnesium hydroxide according to claim 2 , wherein the raw material is a salt or a mixture of salts that are a product or byproduct of an industrial process, such as astrakanite.
5. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein the pretreatment adjusts the sodium and magnesium sulfate content in the raw material and the impurities and insolubles content are decreased.
6. A process to obtain sodium sulfate and magnesium hydroxide according to claim 5 , wherein the adjustment f sodium and magnesium sulfate is done by means of the substitution of other anions of sulfates.
7. A process to obtain sodium sulfate and magnesium hydroxide according to claim 6 , wherein the anions substitution is done by washing with sulfuric acid.
8. A process to obtain sodium sulfate and magnesium hydroxide according to claim 5 , wherein the impurities and insolubles reduction is done by washing optionally with a solution saturated of the raw material.
9. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein the crystallization process is done by salting-out mixing a sodium sulfate solution with the raw material conditioned to produce a sodium sulfate current as final product, a residual current of insoluble material and a current with a sodium and magnesium sulfate solution.
10. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein crystallization takes place in multiple countercurrent stages.
11. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein the sodium and magnesium sulfate solution resulting from the salting-out is mixed with an alkali to produce a magnesium hydroxide precipitate as final product and an aqueous solution of sodium soluble salts and the salt formed by the substitution of OH − in the alkali (mother liquor).
12. A process to obtain sodium sulfate and magnesium hydroxide according to claim 1 , wherein the mother liquor in the magnesium hydroxide precipitate is subjected to a process to regenerate the alkali that recirculates to precipitate the magnesium hydroxide and the sodium sulfate to be used in the salting-out.
13. A process to obtain sodium sulfate and magnesium hydroxide according to claim 12 , wherein when the alkali used in the magnesium hydroxide precipitation is ammonium hydroxide or ammonia the regeneration is performed by adding a stronger alkali such as soda, calcium oxide or hydroxide that releases ammonia gas.
14. A process to obtain sodium sulfate and magnesium hydroxide according to claim 13 , wherein the ammonia gas is absorbed in water to form ammonium hydroxide.
15. A process to obtain sodium sulfate and magnesium hydroxide according to claim 12 , wherein when the alkali used is an alkali metal hydroxide, the alkali regeneration is performed by electrochemical processes.