Metal oxygen battery containing oxygen storage materials
In one aspect of the present invention, a battery system is disclosed. In one embodiment, the battery system includes a metal oxygen battery (MOB) having a first electrode and second electrode. The second electrode includes a metal material. The battery system also includes an oxygen storage material disposed within the metal oxygen battery. In another embodiment, the oxygen storage material is on oxygen communication with the first electrode.
1. A battery system comprising:
a metal oxygen battery housing a non-aqueous electrolyte, an anode including a metal material (M) and oxygen in a first operating state and a cathode including an oxide or a peroxide of M in a second operating state and including an intermixture of catalyst particles and ionic conductive material particles; and
an oxygen storage material (OSM) disposed within the cathode intermixture as one or more segments of OSM.
2. The battery system of claim 1 , wherein the metal oxygen battery is a closed system with regard to air transfer to and from atmospheric air.
3. The battery system of claim 1 , wherein the OSM has a first operating state of oxygen adsorption into the OSM.
4. The battery system of claim 1 , wherein the OSM has a second operating state of oxygen desorption from the OSM.
5. The battery system of claim 1 , wherein the OSM includes a metal organic framework having an entactic metal center, a secondary building unit having at least two entactic metal centers, an aerogel-like substance, or any combination thereof.
6. The battery system of claim 5 , wherein the OSM includes a solvated metal-organic framework (MOF) compound, a covalent organic framework (COF) compound, a zeolite imidazolate framework (ZIF) compound, or any combination thereof.
7. The battery system of claim 1 , wherein the metal oxygen battery is substantially free of water molecules.
8. The battery system of claim 1 , further comprising a separator defining a cathode compartment including the cathode and an anode compartment including the anode, the OSM being disposed within the cathode compartment.
9. A battery system comprising:
a metal oxygen battery housing a non-aqueous electrolyte, a cathode and an anode, the anode including a metal material (M) and oxygen in a first operating state and the cathode including an oxide or a peroxide of the metal material (M) in a second operating state and including an intermixture of catalyst particles and ionic conductive material particles; and
an oxygen storage material (OSM) selected from the group consisting of a catalytically-active metal organic framework (MOF), an organically-solvated MOF, an ionically-solvated MOF, and a partially-ionically-solvated MOF, the OSM disposed within the cathode intermixture as one or more segments of OSM.
10. A method of operating a battery system, comprising:
adsorbing oxygen into one or more segments of an oxygen storage material (OSM) internal to a metal oxygen battery (MOB) housing a non-aqueous electrolyte, an anode inducing a metal material (M) and oxygen in a first operating state and a cathode including an oxide or a peroxide of M in a second operating state and including an intermixture of catalyst particles and ionic conductive material particles, the OSM disposed within the cathode intermixture as one or more segments of OSM; and
releasing oxygen from the cathode intermixture in the second operating state to the one or more segments of OSM.
11. The method of claim 10 , further comprising operating the (MOB) under an operating pressure of from 1 bar to 5 bar.
12. The method of claim 10 , further comprising operating the (MOB) under an operating temperature of from 230 to 310 degrees Kelvin.
13. The battery system of claim 9 , wherein the OSM includes a clathrate site or an intercalation site.
14. The battery system of claim 1 , wherein a cross-section of the one or more segments is enclosed by a cross-section of the cathode intermixture.
15. The battery system of claim 9 , wherein a cross-section of the one or more segments is enclosed by a cross-section of the cathode intermixture.
16. The battery method of claim 10 , wherein a cross-section of the one or more segments is enclosed by a cross-section of the cathode intermixture.
17. The battery system of claim 1 , wherein the cathode intermixture further includes an electrolyte.
18. The battery system of claim 9 , wherein the cathode intermixture further includes an electrolyte.
19. The battery method of claim 10 , wherein the cathode intermixture further includes an electrolyte.
20. The battery system of claim 1 , wherein the one or more segments of OSM are disposed in a patterned or unpatterned configuration.