Self-repairing cyclic oxide-substituted chitosan polyurethane networks
Thermosetting polymeric compositions, such as polyurethane compositions, and related methods are provided. The invention relates to coating and polymer compositions and related methods derived from a biodegradable natural polysaccharide compound such as chitosan, pectin, heparin, and combinations thereof reacted to a cyclic oxide compound, such as an oxetane, oxolane or oxepane compound. The compositions and methods of the present invention exhibit self-repairing properties upon exposure to ultraviolet (UV) light. The compositions and methods of the present invention can be used in many coating applications, such as the transportation, packaging, fashion, and biomedical industries.
1. A cyclic oxide-substituted biodegradable natural polysaccharide composition comprising:
[BNP-OXE 1-2 ] n
wherein BNP is a disaccharide of a biodegradable natural polysaccharide selected from the group consisting of chitosan, pectin, heparin, and combinations thereof, OXE is an oxetane, oxolane, or oxepane compound, and n ranges from 5 to about 1475.
2. A cyclic oxide-substituted chitosan composition comprising:
[CHI-OXE 1-2 ] n
wherein CHI is a disaccharide of chitosan, OXE is an oxetane, oxolane or oxepane compound, and n ranges from 5 to about 1475.
3. The composition of claim 2 , wherein the chitosan has a degree of deacetylation ranging from about 4% to about 2%.
4. The composition of claim 2 , further comprising an alkaline solvent.
5. The composition of claim 2 , wherein OXE is an oxetane compound.
6. The composition of claim 2 wherein the composition comprises
wherein n ranges from 5-650.