IP Library › Granted Patent US 8,663,550
Granted Patent B2
US 8,663,550 · App. 13/257,417 · Granted Mar 4, 2014

Hot work tool steel with outstanding toughness and thermal conductivity

Inventor: Isaac Valls Anglés (Barcelona, ES)
Assignee: Rovalma, S.A.
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Quick Facts
Patent No.
US 8,663,550
App. No.
13/257,417
Granted
Mar 4, 2014
Kind
B2
Abstract

A hot work tool steel family with exceptional thermal diffusivity, toughness (both fracture toughness and notch sensitivity resilience CVN—charpy V-notch) and trough hardenability has been developed. Mechanical resistance and yield strength at room and high temperatures (above 600° C.) are also high, because the tool steels of the present invention present a high alloying level despite the high thermal conductivity. Given the exceptional resistance to thermal fatigue and thermal shock, wear resistance can be severely increased for many applications requiring simultaneously resistance to thermal cracking and wear like is the case for some forging and some parts of die casting dies.

Claims (205)

1. A steel, for a hot work tool steel, having the following composition, all percentages being in weight percent:

% Ceq = 0.26-0.55

% C = 0.20-0.55

% N = 0-0.6

% B = 0-0.45

% Cr < 1.5

% Ni = 1.0-9

% Si < 0.4

% Mn = 0-3

% Al = 0-2.5

% Mo = 0-10

% W = 0-15

% Ti = 0-3

% Ta = 0-3

% Zr = 0-3

% Hf = 0-3,

% V = 0-4

% Nb = 0-3

% Cu = 0-4

% Co = 0-6,

% S = 0-1

% Se = 0-1

% Te = 0-1

% Bi = 0-1

% As = 0-1

% Sb = 0-1

% Ca = 0-1,

the rest consisting of iron and unavoidable impurities, wherein

% C eq =% C+0.86*% N+1.2*% B,

% Ni+9*% Mn+5*% Si<8,

and

% Mo+½% W>1.2,

said steel having a low scattering structure permitting a thermal diffusivity higher than 8 mm 2 /s

and wherein:

x C eq *( x Mo+0.5* x W)/( x Cr+ x V+ x Nb)>8

where:

xCeq—weight percent Carbon;

xMo—weight percent Molybdenum:

xW—weight percent Tungsten;

xV—weight percent Vanadium;

xNb—weight percent Niobium;

where xCr, xV and xNb are the real weight percents even if present at concentrations lower than 0.05%.

2. A steel according to claim 1 , wherein at least 80% weight of the carbides are carbides of primarily Fe, Mo or W, alone or in combination.

3. A steel according to claim 2 , wherein no other single metallic element is present in solid solution within the Fe, Mo and/or W carbides in a concentration higher than 10% weight.

4. A steel according to claim 2 , wherein the % C in the carbides is at least partly replaced by % N and/or % B.

5. A steel according to claim 1 , wherein no single element is present in solid solution within the Fe metallic matrix embedding the carbides in a concentration higher than 0.5% except % Ni and/or % Mn.

6. A steel according to claim 1 , wherein no single element is present in solid solution within the Fe metallic matrix embedding the carbides in a concentration higher than 0.1% except % Ni.

7. A steel according to claim 1 , wherein:

0.03 <x C eq −A C[ x Mo/(3 A Mo)+ x W/(3 A W)+ x V/ A V]<0.165

where:

xCeq—weight percent Carbon;

xMo—weight percent Molybdenum;

xW—weight percent Tungsten;

xV—weight percent Vanadium;

AC—carbon atomic mass (12.0107 u);

AMo—molybdenum atomic mass (95.94 u);

AW—tungsten atomic mass (183.84 u);

AV—vanadium atomic mass (50.9415 u).

8. A steel according to claim 1 , wherein:

% Cr<0.2, % Si<0.2 and % Ni>2.99.

9. A steel according to claim 1 , wherein % Cr<0.1.

10. A steel according to claim 1 , wherein % Si<0.1.

11. A steel according to claim 1 , wherein % Cr<0.05 and % Si<0.05.

12. A steel according to claim 1 , wherein % Mo=2-10, and 3<% Mo+½·% W<11.

13. A steel according to claim 1 , wherein:

% C eq = 0.26-0.4

% C = 0.26-0.4

% N = 0-0.45

% B = 0-0.3

% Cr < 0.5

% Ni = 2.99-6

% Si < 0.3

% Mo = 2.5-8

% W = 0-5.

14. A steel according to claim 1 , wherein:

% C eq = 0.28-0.36

% C = 0.28-0.36

% N = 0-0.4

% B = 0-0.25

% Cr < 0.3

% Ni = 2.99-5

% Si < 0.25

% Mo = 3-6.5

% W = 1-4.

15. A die, tool or part comprising at least one steel according to claim 1 .

16. A steel, for a hot work tool steel, having the following composition, all percentages being in weight percent:

% Ceq = 0.20 − 1.2

% C = 0.20 − 1.2

% N = 0 − 0 − 1

% B = 0 − 1

% Cr < 0.05

% Ni = 1.0 − 9

% Si < 0.05

% Mn = 0 − 3

% Al = 0 − 2.5

% Mo = 0 − 10

% W = 0 − 15

% Ti = 0 − 3

% Ta = 0 − 3

% Zr = 0 − 3

% Hf = 0 − 3,

% V = 0 − 4

% Nb = 0 − 3

% Cu = 0 − 4

% Co = 0 − 6,

% S = 0 − 1

% Se = 0 − 1

% Te = 0 − 1

% Bi = 0 − 1

% As = 0 − 1

% Sb = 0 − 1

% Ca = 0 − 1,

the rest consisting of iron and unavoidable impurities, wherein

% C eq % C+0.86*% N+1.2*% B,

and

% Mo+½% W>1.2

and wherein:

x C eq *( x Mo+0.5* x W)/( x Cr+ x V+ x Nb)>8

where:

xCeq—weight percent Carbon;

xMo—weight percent Molybdenum:

xW—weight percent Tungsten;

xV—weight percent Vanadium;

xNb—weight percent Niobium;

where xCr, xV and xNb are the real weight percents even if present at concentrations lower than 0.05%.

17. A steel, for a hot work tool steel, having the following composition, all percentages being in weight percent:

% C eq = 0.26 − 0.4

% C = 0.26 − 0.4

% N = 0 − 0.45

% B = 0 − 0.3

% Cr < 0.5

% Ni = 2.99 − 6

% Si < 0.3

% Mn = 0 − 3

% Al = 0 − 2.5

% Mo = 2.5 − 8

% W = 0 − 5

% Ti = 0 − 3

% Ta = 0 − 3

% Zr = 0 − 3

% Hf = 0 − 3,

% V = 0 − 4

% Nb = 0 − 3

% Cu = 0 − 4

% Co = 0 − 6,

% S = 0 − 1

% Se = 0 − 1

% Te = 0 − 1

% Bi = 0 − 1

% As = 0 − 1

% Sb = 0 − 1

% Ca = 0 −1,

the rest consisting of iron and unavoidable impurities, wherein

% C eq =% C+0.86*% N+1.2*% B,

and

% Mo+½·% W>1.2

and wherein:

x C eq *( x Mo+0.5* x W)/( x Cr+ x V+ x Nb)>8

where:

xCeq—weight percent Carbon;

xMo—weight percent Molybdenum:

xW—weight percent Tungsten;

xV—weight percent Vanadium;

xNb—weight percent Niobium;

where xCr, xV and xNb are the real weight percents even if present at concentrations lower than 0.05%.

18. A steel, for a hot work tool steel, having the following composition, all percentages being in weight percent:

% C eq = 0.28 − 0.36

% C = 0.28 − 0.36

% N = 0 − 0.4

% B = 0 − 0.25

% Cr < 0.3

% Ni = 2.99 − 5

% Si < 0.25

% Mn = 0 − 3

% Al = 0 − 2.5

% Mo = 3 − 6.5

% W = 0 − 4

% Ti = 0 − 3

% Ta = 0 − 3

% Zr = 0 − 3

% Hf = 0 − 3,

% V = 0 − 4

% Nb = 0 − 3

% Cu = 0 − 4

% Co = 0 − 6,

% S = 0 − 1

% Se = 0 − 1

% Te = 0 − 1

% Bi = 0 − 1

% As = 0 − 1

% Sb = 0 − 1

% Ca = 0 − 1,

the rest consisting of iron and unavoidable impurities, wherein

% C eq =% C+0.86*% N+1.2*% B,

and

% Mo+½·% W>1.2

and wherein:

x C eq *( x Mo+0.5* x W)/( x Cr+ x V+ x Nb)>8

where:

xCeq—weight percent Carbon;

xMo—weight percent Molybdenum:

xW—weight percent Tungsten;

xV—weight percent Vanadium;

xNb—weight percent Niobium;

where xCr, xV and xNb are the real weight percents even if present at concentrations lower than 0.05%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 5, 2011
From: VALLS ANGLES, ISAAC
To: ROVALMA, S.A.
Reel/Frame 027324/0514 →
Priority Claims (1)
EP 09382044 · Apr 1, 2009 · regional
Continuity (1)
Related Publication 20120063946A1 · Mar 15, 2012