Lubricating compositions for transmissions
The present disclosure relates to lubricating compositions for transmissions, in particular for gear boxes, and to the use thereof for limiting the fuel consumption of motor vehicles. The compositions according to the disclosure are suitable for all types of vehicles, especially light vehicles, and are particularly suitable for hybrid engine vehicles.
1. A lubricating composition for gearboxes, with a kinematic viscosity at 100° C. measured according to the ASTM D445 standard of between 5.5 and 7 mm 2 /s, comprising:
(a) one or more phosphorus-containing, sulfur-containing, or phosphorus-sulphur-containing antiwear and/or extreme pressure additives;
(b) at least 30% by weight of at least one fatty acid methyl ester of formula RCOOCH 3 , wherein R is a paraffinic or olefinic group containing from 11 to 23 carbon atoms; and
(c) at least one compound selected from the group of light polyalphaolefins with kinematic viscosity at 100° C., measured according to the ASTM D445 standard, comprised between 1.5 and 6 mm 2 /s, with a kinematic viscosity at 40° C., measured according to the ASTM D445 standard, comprised between 4 and 30 mm 2 /s and with a molecular mass by weight of less than 500 daltons in combination with one or more compounds of polymethacrylate type, with a molecular mass by weight of less than 30,000 daltons, and wherein the mass percentage of light polyalphaolefin(s) is at least 10%, and wherein the mass percentage of the polymethacrylate(s) and the fatty acid methyl ester(s) is collectively at least 60%.
2. The lubricating composition according to claim 1 , comprising at least 20% by weight of at least one fatty acid methyl ester of formula R 1 COOCH 3 , wherein R 1 is a mono-, di- or tri-unsaturated olefinic group containing from 11 to 23 carbon atoms.
3. The lubricating composition according to claim 1 , comprising at least 20% by weight of at least one fatty acid methyl ester of formula R 2 COOCH 3 , wherein R 2 is a mono-unsaturated group containing from 11 to 23 carbon atoms.
4. The lubricating composition according to claim 2 , wherein the unsaturations of the olefinic group R 1 is in the cis configuration.
5. The lubricating composition according to claim 1 , wherein the ratio between the mass percentage of polymethacrylate(s) and the mass percentage of fatty acid ester(s) is comprised between 0.8 and 1.2.
6. The lubricating composition according to claim 1 , comprising at least 85% by weight of one or more fatty acid methyl esters of formula RCOOCH 3 , wherein R is a paraffinic or olefinic group containing from 11 to 23 carbon atoms, based on the total weight of fatty acid esters present in said lubricant composition.
7. The lubricating composition according to claim 6 , comprising at least 75% by weight of at least one fatty acid methyl ester of formula R 1 COOCH 3 , wherein R 1 is a mono-, di- or tri-unsaturated olefinic group containing from 11 to 23 carbon atoms, based on the total weight of fatty acid esters present in said lubricant composition.
8. The lubricating composition according to claim 6 , comprising at least 65% by weight of at least one fatty acid methyl ester of formula R 2 COOCH 3 , wherein R 2 is a mono-unsaturated group containing from 11 to 23 carbon atoms, based on the total weight of fatty acid esters present in said lubricant composition.
9. The lubricating composition according to claim 7 , wherein the unsaturations of the olefinic group R 1 is in the cis configuration.
10. The lubricating composition according to claim 6 , comprising at most 15% by weight of saturated fatty acid esters, based on the total weight of fatty acid esters present in said lubricant composition.
11. The lubricating composition according to claim 1 , wherein the ratio S/P between the mass content of the sulfur element measured according to the ASTM D2622 standard and the content of the phosphorus element measured according to the ASTM D5185 standard in the lubricating compositions is comprised between 3 and 60.
12. The lubricating composition according to claim 1 , wherein its VI, measured according to the ASTM D2270 standard, is greater than 250.
13. A method for lubricating gearboxes comprising contacting the gearboxes with a lubricating composition for gearboxes, with a kinematic viscosity at 100° C. measured according to the ASTM D445 standard, comprised between 5.5 and 7 mm 2 /s, wherein the method generates fuel savings of more than 1%, measured under standard conditions of the NDEC test according to the Directive EEC 90/C81/01 on motor vehicles, and wherein the lubricating composition comprises:
(a) one or more phosphorus-containing, sulfur-containing, or phosphorus-sulphur-containing antiwear and/or extreme pressure additives,
(b) at least 30% by weight of at least one fatty acid methyl ester of formula RCOOCH 3 , wherein R is a paraffinic or olefinic group containing from 11 to 23 carbon atoms; and
(c) at least one compound selected from the group of light polyalphaolefins with a kinematic viscosity at 100° C., measured according to the ASTM D445 standard, comprised between 1.5 and 6 mm 2 /s, with a kinematic viscosity at 40° C., measured according to the ASTM D445 standard, comprised between 4 and 30 mm 2 /s, and with a molecular mass by weight of less than 500 daltons in combination with one or more compounds of the polymethacrylate type, with a molecular mass by weight of less than 30,000 daltons, and wherein the mass percentage of light polyalphaolefin(s) is at least 10%, and wherein the mass percentage of polymethacrylate(s) and the fatty acid methyl ester(s) is collectively at least 60%.
14. The method according to claim 13 , wherein the fuel savings are generated on engines of light duty vehicles.
15. The method according to claim 13 , wherein the vehicles are equipped with manual or automatic or automated manual gearboxes.
16. The lubricating composition according to claim 3 , wherein the unsaturation of the olefinic group R 2 is in the cis configuration.
17. The lubricating composition according to claim 8 , wherein the unsaturation of the olefinic group R 2 is in the cis configuration.