Black matrix for colour filters

1. Actinically modifiable composition for producing a black matrix comprising, all based on the entire composition,

10-70% by weight of a colorant or a mixture of colorants;

90-30% by weight of actinically reactive binder material consisting of components selected from the group consisting of binders, binder precursors, dispersants, photoinitiators and stabilizers, although optionally from 0% to 30% by weight of the actinically reactive binder material can be non-reactive components; and

0-10% by weight of further, non-reactive constituents;

characterized in that

the composition has an optical density 1.0, in the entire wavelength range 430-650 nm per 1 μm layer thickness; and

the colorant or 50-100% by weight, the colorant mixture comprises a colorant obtainable by reaction of a compound of the formula

with a compound of the formula

in a molar ratio of 1:2, or by reaction of a compound of the formula

with 2 to 5 compounds of the formula

in a molar (i):(iii) overall ratio of 1:2, in the presence of a catalyst having a pK value≦4.5 in water at 25° C., or a mixture of such colorants, where

R 1 and R 2 independently of one another are H or are C 1 -C 24 alkyl, C 3 -C 24 cycloalkyl, C 2 -C 24 alkenyl, C 3 -C 24 cycloalkenyl or C 2 -C 24 alkynyl, each unsubstituted or substituted by halogen or C 1 -C 8 alkoxy; are C 7 -C 24 aralkyl which is unsubstituted or substituted one or more times by halogen, nitro, cyano, C 1 -C 8 alkyl and/or C 1 -C 8 alkoxy; or are C 6 -C 24 aryl which is unsubstituted or substituted one or more times by halogen, nitro, cyano, C 1 -C 8 alkyl and/or C 1 -C 8 alkoxy;

R 3 is H, F, Cl, R 8 or OR 8 ;

R 4 , R 5 and R 6 independently of one another are H, F, Br, Cl, COOH, COOR 8 , CONH 2 , CONHR 8 , CONR 8 R 8 , CN, COR 8 , SO 3 H, SO 2 NH 2 , SO 2 NHR 8 , SO 2 NR 8 R 8 , SO 2 R 8 , NO 2 , R 8 , OR 8 , SR 8 , NR 8 R 8 , NHCOR 8 or

or R 3 and R 4 , R 4 and R 5 or R 5 and R 6 in pairs together form a C 1 -C 6 alkylenedioxy, C 3 -C 6 alkylene, C 3 -C 6 alkenylene or 1,4-butadienylene radical, each unsubstituted or substituted one or more times by F, OR 8 , NO 2 , oxo, thioxo or SO 3 H;

R 7 is H or is C 1 -C 24 alkyl, C 3 -C 24 cycloalkyl, C 2 -C 24 alkenyl, C 3 -C 24 cycloalkenyl, C 2 -C 24 alkynyl or C 2 -C 12 heterocycloalkyl, each unsubstituted or substituted one or more times by F, oxo or thioxo and uninterrupted or interrupted one or more times by O, S or NR 8 ; or is C 7 -C 24 aralkyl, C 1 -C 12 heteroaryl-C 1 -C 8 alkyl, C 6 -C 24 aryl or C 1 -C 12 heteroaryl, each unsubstituted or substituted one or more times by oxo, thioxo, F, Br, Cl, COOH, COOR 8 , CONH 2 , CONHR 8 , CONR 8 R 8 , CN, COR 8 , SO 3 H, SO 2 NH 2 , SO 2 NHR 8 , SO 2 NR 8 R 8 , SO 2 R 8 , NO 2 , R 8 , OR 8 , SR 8 , NR 8 R 8 , NHCOR 8 or

each R 8 , independently of all other R 8 s, is C 1 -C 24 alkyl, C 3 -C 24 cycloalkyl, C 2 -C 24 alkenyl, C 3 -C 24 cycloalkenyl, C 2 -C 24 alkynyl or C 2 -C 12 heterocycloalkyl, each unsubstituted or substituted one or more times by F, oxo, thioxo, OR 9 , SR 9 or NR 9 R 9 ; or is C 7 -C 24 aralkyl, C 1 -C 12 heteroaryl-C 1 -C 8 alkyl, C 6 -C 24 aryl or C 1 -C 12 heteroaryl, each unsubstituted or substituted one or more times by oxo, F, Br, Cl, COOH, CONH 2 , CONHR 9 , CONR 9 R 9 , SO 3 H, SO 2 NH 2 , SO 2 NHR 9 , SO 2 NR 9 R 9 , CN, NO 2 , OR 9 , SR 9 , NR 9 R 9 , NHCOR 9 or

or two vicinal R 8 s together form —O—CO—O—, —O—CS—O—, —CO—N—CO—, —N—CO—N—, —N═S═N—, —N—C═C—, —O—C═C—, —S—C═C—, —O—C═N—, —S—C═N—, —N—N═N—, —N═C—C═C—, —C═N—C═C—, —N═C—C═N—, —C═N—N═C— or —C═N—C═N— or —C═C—C═C—, in which each —C═ and —N— independently of all other —C═ and —N— is substituted by H or R 9 ;

or two geminal or vicinal R 8 s together form a C 3 -C 8 alkylene or C 3 -C 8 alkenylene radical, each unsubstituted or substituted one or more times by F, oxo or thioxo, and in which 0, 1 or 2 non-vicinal methylene units may be replaced by O, S or NR 9 ;

each R 9 , independently of all other R 9 s, is C 1 -C 8 alkyl, C 3 -C 6 cycloalkyl or benzyl, each unsubstituted or substituted one or more times by oxo, thioxo, F and/or O—C 1 -C 8 alkyl; or is phenyl or C 1 -C 5 heteroaryl, each unsubstituted or substituted one or more times by F, Br, Cl, CO—C 1 -C 8 alkyl, COOH, CONH 2 , CONHC 1 -C 8 alkyl, CON(C 1 -C 8 alkyl) 2 , SO 3 H, SO 2 NH 2 , SO 2 NHC 1 -C 8 alkyl, SO 2 N(C 1 -C 8 alkyl) 2 , CN, NO 2 , C 1 -C 8 alkyl, OC 1 -C 8 alkyl, SC 1 -C 8 alkyl or N(C 1 -C 8 alkyl) 2 ;

or two vicinal R 9 s together form —O—CO—O—, —O—CS—O—, —CO—N—CO—, —N—CO—N—, —N═S═N—, —N—C═C—, —O—C═C—, —S—C═C—, —O—C═N—, —S—C═N—, —N—N═N—, —N═C—C═C—, —C═N—C═C—, —N═C—C═N—, —C═N—N═C— or —C═N—C═N— or —C═C—C═C—, in which each —C═ and —N— independently of all other —C═ and —N— is substituted by H, F, oxo, thioxo, C 1 -C 8 alkyl or OC 1 -C 8 alkyl;

or two geminal or vicinal R 9 s together form a C 3 -C 8 alkylene or C 3 -C 8 alkenylene radical, each unsubstituted or substituted one or more times by oxo or thioxo, and in which 0, 1 or 2 non-vicinal methylene units may be replaced by O, S or N(C 1 -C 8 alkyl); and

R 10 is H, CH 3 , C 2 H 5 , OCH 3 , OC 2 H 5 , F, Cl, Br, NO 2 , CN, COOH or SO 3 H,

R 11 is H, NO 2 , CN, COOH or SO 3 H, and

R 12 is H, CH 3 , C 2 H 5 , OCH 3 , OC 2 H 5 , F, or Cl.

2. Composition according to claim 1 , wherein:

R 3 =R 4 =R 5 =R 6 =R 7 =H;

R 3 =R 5 =R 6 =R 7 =H, R 4 =NO 2 ;

R 3 =R 5 =R 6 =R 7 =H, R 4 =OCH 3 ;

R 3 =R 5 =R 6 =R 7 =H, R 4 =Cl;

R 3 =R 5 =R 6 =R 7 =H, R 4 =F;

R 3 =R 5 =R 6 =R 7 =H, R 4 =Br;

R 3 =R 5 =R 6 =R 7 =H, R 4 =SO 3 H;

R 3 =R 5 =R 6 =R 7 =H, R 4 =COOH;

R 3 =R 5 =R 6 =R 7 =H, R 4 =N(CH 3 ) 2 ;

R 3 =R 5 =R 6 =R 7 =H, R 4 =NHCOC 1 -C 18 alkyl;

R 3 =R 5 =R 6 =R 7 =H, R 4 =C 1 -C 20 alkyl;

R 3 =R 5 =R 6 =R 7 =H, R 4 =C 2 -C 20 alkoxy;

R 3 =R 5 =R 7 =H, R 4 =R 6 =CH 3 ;

R 3 =R 5 =R 7 =H, R 4 =R 6 =Cl;

R 3 =R 5 =R 7 =H, R 4 =C 1 , R 6 =CH 3 ;

R 3 =R 4 =R 5 =R 6 =H, R 7 =CH 3 ;

R 3 =R 4 =R 5 =R 6 =H, R 7 =C 6 H 5 ; or

R 3 =R 4 =R 7 =H, R 5 and R 6 together=1,4-butadienylene.

3. Composition according to claim 1 , wherein the reaction products of compounds of the formula (i) with compounds of the formula (ii) or (iii) consist of particles having an average particle size L of 50-200 nm, with 60-95% by weight of the particles having a particle size of L±½L, 1-15% by weight of the particles having a particle size <½L and 4-25% by weight of the particles having a particle size >1½L.

4. Composition according to claim 1 , comprising 0.01-10% by weight, based on the entire composition, of a photoinitiator.

5. Colour filter comprising pixels composed of at least three colours, characterized in that the black matrix which separates the pixels comprises a composition according to claim 1 or a product obtainable by actinic curing thereof.

6. Colour filter according to claim 5 , wherein the black matrix is in direct contact with liquid crystals, optionally also in contact with pixel electrodes.

7. Process for producing colour filters, wherein the black matrix which separates the pixels comprises a composition according to claim 5 or a product obtainable by actinic curing thereof, characterized in that a composition according to claim 5 is applied to a substrate, exposed through a mask, developed and cured, so that depressions are formed between crosslinked elevations (matrix), and thereafter coloured inks are applied patternwise in these depressions by inkjet printing or photolithography, with each ink ending up in only some of the depressions in accordance with a regular pattern.

8. A method of using a composition according to claim 1 comprising manufacturing a black matrix for colour filters.