Acrylic pressure-sensitive adhesive resin composition, and pressure-sensitive adhesive sheet or pressure-sensitive adhesive tape using the same
The present invention relates to an acrylic pressure-sensitive adhesive resin composition including an organic-inorganic hybrid polymer synthesized from the following (a) to (d): (a) fine silica particles having silanol groups on a surface thereof; (b) a siloxane having at least one selected from a group consisting of an alkoxysilyl group and a silanol group at a molecular end thereof; (c) a trialkoxysilane represented by the following general formula (I) in which R 1 represents a C 1-6 alkyl group, and R 1′ represents a hydrogen atom or a methyl group; and (d) a (meth)acrylic monomer:
1. An acrylic pressure-sensitive adhesive resin composition comprising an organic-inorganic hybrid polymer synthesized from the following (a) to (d):
(a) fine silica particles having silanol groups on a surface thereof;
(b) a siloxane having at least one selected from a group consisting of an alkoxysilyl group and a silanol group at a molecular end thereof;
(c) a trialkoxysilane represented by the following general formula (I); and
(d) a (meth)acrylic monomer,
wherein R 1 represents a C 1-6 alkyl group, and R 1′ represents a hydrogen atom or a methyl group, wherein the organic-inorganic hybrid polymer is a copolymer constituted of a polysiloxane formed from 5 to 40% by weight (a) fine silica particles and 40 to 95% by weight (b) siloxane and an acrylic copolymer formed from at least 0.001 to 0.1% by weight (c) trialkoxysilane and 60 to 99.95% by weight (d) (meth)acrylic monomer, the polysiloxane and the acrylic copolymer being bonded with each other through siloxane bonds.
2. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein the (a) fine silica particles are colloidal silica which has an average primary-particle diameter of 1 to 100 nm and a pH of 2 to 4 or of 8 to 10.
3. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein the (b) siloxane comprises at least one selected from the group consisting of a siloxane having, at a molecular end thereof, an alkoxysilyl group in an amount of 10% by weight or more based on the whole molecule and a siloxane having, at a molecular end thereof, a silanol group in an amount of 10% by weight or less based on the whole molecule.
4. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein the siloxane having an alkoxysilyl group at a molecular end thereof has a weight-average molecular weight of 100 to 6,000.
5. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein the siloxane having a silanol group at a molecular end thereof has a weight-average molecular weight of 300 to 3,000.
6. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein the (d) (meth)acrylic monomer is represented by the following general formula (II):
CH 2 ═C(R 2 )COOR 3 (II)
wherein R 2 represents a hydrogen atom or a methyl group, and R 3 represents a hydrocarbon group having 2 to 14 carbon atoms.
7. The acrylic pressure-sensitive adhesive resin composition according to claim 1 , wherein (e) a carboxyl-containing monomer is further included as a comonomer ingredient of an acrylic copolymer, and the (e) carboxyl-containing monomer, the (c) trialkoxysilane, and the (d) (meth)acrylic monomer form an acrylic copolymer.
8. A pressure-sensitive adhesive sheet or pressure-sensitive adhesive tape which comprises a substrate or a separator and, formed thereon, a layer comprising the acrylic pressure-sensitive adhesive resin composition according to claim 1 .