Catalyst for catalytic cracking of hydrocarbon, which is used in production of light olefin and production method thereof
Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO 2 and 1˜15 wt % of P 2 O 5 are simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.
1. A method for preparing a catalyst for light olefins comprising the steps of:
(a) mixing ZSM-5 zeolite, clay and inorganic oxide precursor with phosphorus precursor and manganese precursor under stirring to prepare a mixing slurry; and
(b) spray drying the mixing slurry, followed by calcinations, to obtain a final catalyst wherein the step (a) comprises the steps of:
(i) mixing the ZSM-5 zeolite with manganese precursor, followed by adding the clay and stirring the mixture to prepare a ZSM-5 zeolite/clay slurry;
(ii) mixing the inorganic precursor with phosphorus precursor and manganese precursor under stirring to prepare an inorganic oxide slurry; and
(iii) mixing the ZSM-5 zeolite/clay slurry and the inorganic oxide slurry uniformly;
wherein both 0.01-5.0 wt % MnO 2 and 1-15 wt % of P 2 O 5 are embedded in each of 1-50 wt % of ZSM-5 zeolite, 21-70 wt % of clay, and 1-40 wt % of an inorganic oxide in the final catalyst.
2. A method for preparing a catalyst for light olefins comprising the steps of:
(a) mixing ZSM-5 zeolite, clay and inorganic oxide precursor with phosphorus precursor and manganese precursor under stirring to prepare a mixing slurry; and
(b) spray drying the mixing slurry, followed by calcinations, wherein the step (a) comprises the steps of:
(i) mixing the ZSM-5 zeolite with manganese precursor to prepare a zeolite slurry;
(ii) mixing the inorganic precursor with phosphorus precursor and manganese precursor under stirring to prepare an inorganic oxide slurry; and
(iii) mixing the ZSM-5 zeolite slurry, the inorganic oxide slurry, and clay uniformly;
wherein both 0.01-5.0 wt % MnO 2 and 1-15 wt % of P 2 O 5 are embedded in each of 1-50 wt % of ZSM-5 zeolite, 21-70 wt % of clay, and 1-40 wt % of an inorganic oxide in the final catalyst.
3. A method for preparing a catalyst for light olefins comprising the steps of:
(a) mixing ZSM-5 zeolite, clay and inorganic oxide precursor with phosphorus precursor and manganese precursor under stirring to prepare a mixing slurry; and
(b) spray drying the mixing slurry, followed by calcinations to obtain a final catalyst,
wherein the step (a) is carried out by mixing the ZSM-5 zeolite, clay and inorganic oxide precursor, phosphorus precursor and manganese precursor at the same time under stirring
wherein both 0.01-5.0 wt % MnO 2 and 1-15 wt % of P 2 O 5 are embedded in each of 1-50 wt % of ZSM-5 zeolite, 21-70 wt % of clay, and 1-40 wt % of an inorganic oxide in the final catalyst.
4. The method of claim 1 , wherein the inorganic oxide precursor comprises Al 2 O 3 , SiO 2 or Al 2 O 3 —SiO 2 , and forms a sol, gel, or solution.
5. The method of claim 1 , wherein the manganese precursor is a sulfate, nitrate, chloride or acetate compound of manganese.
6. The method of claim 1 , wherein the phosphorus precursor is an aqueous phosphorus compound selected from the group of H 3 PO 4 , (NH 4 ) 3 PO 4 , H(NH 4 ) 2 (PO 4 ) and H 2 (NH 4 )PO 4 .
7. The method of claim 2 , wherein the inorganic oxide precursor comprises Al 2 O 3 , SiO 2 or Al 2 O 3 —SiO 2 , and forms a sol, gel, or solution.
8. The method of claim 3 , wherein the inorganic oxide precursor comprises Al 2 O 3 , SiO 2 or Al 2 O 3 —SiO 2 , and forms a sol, gel, or solution.
9. The method of claim 2 , wherein the manganese precursor is a sulfate, nitrate, chloride or acetate compound of manganese.
10. The method of claim 3 , wherein the manganese precursor is a sulfate, nitrate, chloride or acetate compound of manganese.
11. The method of claim 2 , wherein the phosphorus precursor is an aqueous phosphorus compound selected from the group of H 3 PO 4 , (NH 4 ) 3 PO 4 , H(NH 4 ) 2 (PO 4 ) and H 2 (NH 4 )PO 4 .
12. The method of claim 3 , wherein the phosphorus precursor is an aqueous phosphorus compound selected from the group of H 3 PO 4 , (NH 4 ) 3 PO 4 , H(NH 4 ) 2 (PO 4 ) and H 2 (NH 4 )PO 4 .