Tanning process and tanning composition
Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning with a tanning agent (A) of a formula (I), Wherein Hal signifies fluorine or chlorine, R1 signifies hydrogen, C 1-8 -alkyl or an alkyleneoxy radical of a formula (Ia), —(—C 2-3 alkylene-O—) q —H (Ia), R2 signifies C- 1-4 -alkyl or C- 1-4 -alkoxy, m, signifies 1 or 2, n signifies 0 or 1, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step, the invention relates to the defined tanning process, particular tanning agent compositions, the use of the tanned leather, skins or pelts for further processing and the produced tanned and optionally further processed leather, skins or pets.
1. A process for the production of tanned leather, skins or pelts by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of formula (I),
wherein
Hal is fluorine or chlorine,
R1 is hydrogen, C 1-8 -alkyl or an alkyleneoxy radical of formula (Ia),
—(—C 2-3 alkylene-O—) q —H (Ia)
R2 is C 1-4 -alkyl or C 1-4 -alkoxy,
m is 1 or 2,
n is 0 or 1,
q is from 1 to 10,
M is hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation,
in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
2. A tanning process according to claim 1 , wherein the bated hide or skin or pelt is subjected to tanning step without previous pickling.
3. A process according to claim 1 , wherein a bated and pickled hide, skin or pelt is depickled to a pH in the range of 6 to 10 before the tanning step.
4. A process according to claim 1 , wherein the tanning agent (A) is employed in the form of an aqueous composition (T) free of metal compounds of tanning activity.
5. A process according to claim 1 , wherein the tanning agent (A) is employed in the presence of a solvent (S) selected from the group consisting of protic solvents (S1) and aprotic solvents (S2).
6. A process according to claim 5 , wherein the tanning agent (A) is employed in the form of an aqueous/organic composition (T′) comprising (S1).
7. A process according to claim 5 , wherein (S1) is (S1″) selected from group consisting of mono-, di- and tri-(C 2-3 -alkylene)glycol mono (C 1-4 -alkyl) ethers with 3-12 carbon atoms.
8. A process according to claim 4 , wherein the aqueous composition (T) is a composition (T1), the composition (T1) further comprising a surfactant (B), a buffer (C 1 ) or both to keep an acidic to neutral pH.
9. A process according to claim 8 , wherein the composition (T1) further comprises an agent (D) to protect against the damaging action of microorganisms, a polysaccharide-based thickener (E) or both.
10. A process according to claim 9 , wherein aqueous composition (T1) comprises a polysaccharide-based thickener (E).
11. A process according to claim 1 , wherein the tanning bath comprises a buffer (C2) to achieve a nearly neutral to basic pH at the beginning of the tanning step.
12. A process according to claim 1 for the production of non-metal tanned leather, skin or pelt, wherein the tanning step with the tanning agent (A) is a pre-tanning, a main tanning or a full tanning or a pretanning and a main tanning.
13. A process according to claim 12 , wherein tanning step with the tanning agent (A) is carried out as a two-stage tanning process, wherein a pre-tanning is carried out with the tanning agent (A) being a tanning agent (A2),
the tanning agent (A2) comprising at least one monosulpho compound of formula (V),
wherein Hal, R1, R2, n and M are as defined above,
which is begun at a pH in the range of 7.5 to 9,
and then a main tanning is carried out with the tanning agent (A) being a tanning agent (A3), the tanning agent (A3) comprising at least one disulpho compound of formula (VII),
wherein Hal, R1, R2, n and M are as defined in claim 1 , which is begun at a pH in the range of 6 to 8;
or a pre-tanning is carried out with the tanning agent (A3), which is begun at a pH in the range of 6 to 8, and then a main tanning is carried out with a tanning agent (A2), which is begun at a pH in the range of 7.5 to 9.
14. A process according to claim 12 , wherein a non-mineral tanning agent (F), which is different from the tanning agent (A), is used before, after or together with tanning agent (A) in pre-tanning, in main tanning or in full tanning, or in combination with tanning agent (A) in full tanning.
15. A process according to claim 14 wherein the non-mineral tanning agent (F) is selected from the group consisting of
(F1) a vegetable tanning agent,
(F2) a syntan,
(F3) a synthetic, semisynthetic or natural resin or polymer,
(F4) a tanning natural oil or modified oil, and mixtures thereof.
16. A process according to claim 12 , wherein the substrates are tanned with tanning agent (A) in a main or full tanning and then are subjected to a complementary tanning with a non-mineral tanning agent (F).
17. A process according to claim 14 , wherein the non-mineral tanning agent (F) is employed in a smaller amount compared with the amount of the tanning agent (A).
18. An aqueous tanning composition (T1), comprising the at least one tanning agent (A) of formula (I) according to claim 1 , and at least one further component selected from the group consisting of a surfactant (B), a buffer (C1), an agent (D) to protect against the damaging action of microorganisms, and a polysaccharide-based thickener (E), for use as tanning agent in a tanning process.
19. An aqueous/organic tanning composition (T′), comprising the at least one tanning agent (A) of formula (I) according to claim 1 , and at least one protic solvent (S1), for use as tanning agent in a tanning process.
20. A composition (T′) according to claim 19 , wherein (S1) is (S1″), wherein (S1″) is selected from mono-, di- and tri-(C2-3-alkylene)glycol mono (C1-4-alkyl) ethers with 3-12, carbon atoms.
21. The tanned leather, skin or pelt produced according to a process as defined in claim 1 for further processing by at least one further treatment selected from the group consisting of
(a) retanning with a non-mineral tanning agent (F), which is different from the tanning agent (A) as defined in claim 1 ,
(b) fat-liquoring,
(c) dyeing, and
(d) finishing.
22. A tanned leather, skin or pelt produced according to a process as defined in claim 1 for further processing by a further treatment comprising retanning with a non-mineral tanning agent (F) which is different from the tanning agent (A) as defined in claim 1 .
23. A tanned leather, skin or pelt produced according to a process as defined in claim 1 for further processing by a further treatment comprising retanning with non-mineral tanning agent (F) which is different from the tanning agent (A) as defined in claim 1 , fat-liquoring and optionally dyeing, finishing or both.
24. The tanned leather, skin or pelt according to claim 21 , wherein the non-mineral tanning agent (F) is selected from the group consisting of
(F1) a vegetable tanning agent,
(F2) a syntan,
(F3) a synthetic, semisynthetic or natural resin or polymer,
(F4) a tanning natural oil or modified oil, and mixtures thereof.
25. A tanned leather, skin or pelt made in accordance with the process according to claim 1 .