Methods for co-processing biorenewable feedstock and petroleum distillate feedstock
Methods for co-processing a biorenewable feedstock and a petroleum distillate feedstock are provided. The petroleum distillate feedstock containing sulfur is reacted with hydrogen gas in the presence of a hydrotreating catalyst thereby forming an effluent mixture comprising hydrogen sulfide. A combined feed comprising the effluent mixture, optionally a recycle liquid, and the biorenewable feedstock is contacted with hydrogen gas in a reaction zone with a deoxygenation catalyst under reaction conditions to provide a reaction product comprising a hydrocarbon fraction. The combined feed comprises greater than 50 weight percent biorenewable feedstock.
1. A method for co-processing a biorenewable feedstock and a petroleum distillate feedstock, the method comprising the steps of:
reacting a petroleum distillate feedstock containing sulfur with hydrogen gas in the presence of a hydrotreating catalyst and forming an effluent mixture comprising hydrogen sulfide; and
contacting a combined feed comprising the effluent mixture the biorenewable feedstock, and a recycle liquid in a ratio of about 0.1:1 to about 4:1 recycle liquid to biorenewable feedstock with hydrogen gas in a reaction zone with a deoxygenation catalyst under reaction conditions to provide a reaction product comprising a hydrocarbon fraction, the combined feed comprising greater than 50 weight percent biorenewable feedstock.
2. The method of claim 1 , wherein the step of reacting a petroleum distillate feedstock containing sulfur with hydrogen gas comprises reacting the petroleum distillate feedstock containing sulfur with recycle hydrogen gas.
3. The method of claim 1 , wherein the step of reacting a petroleum distillate feedstock containing sulfur with hydrogen gas comprises reacting the petroleum distillate feedstock containing sulfur with fresh hydrogen gas.
4. The method of claim 1 , wherein the step of reacting a petroleum distillate feedstock comprises controlling a ratio of the petroleum distillate feedstock to the biorenewable feedstock in the combined feed.
5. The method of claim 1 , wherein the step of reacting the petroleum distillate feedstock containing sulfur comprises reacting the petroleum distillate feedstock with the hydrogen gas under hydrotreating conditions comprising a temperature of about 260° C. to about 454° C., a hydrogen partial pressure of about 2000 kPa to about 14000 kPa, and a liquid hourly space velocity of about 0.5 hr −1 to about 10 hr −1 .
6. The method of claim 1 , wherein the step of contacting combined feed comprises contacting the combined feed with hydrogen recycle gas.
7. The method of claim 1 , wherein the step of contacting a combined feed comprises contacting the combined feed in the reaction zone of a treating reactor.
8. The method of claim 1 , further comprising the steps of:
providing the petroleum distillate feedstock containing sulfur;
contacting the petroleum distillate feedstock with the hydrotreating catalyst under hydrotreating conditions using hydrogen recycle gas or fresh hydrogen gas to convert at least a portion of the sulfur to hydrogen sulfide in the effluent mixture; and
contacting the combined feed comprising the effluent mixture, a recycle liquid, and the biorenewable feedstock with a deoxygenation catalyst under reaction conditions using hydrogen gas to provide the reaction product comprising the hydrocarbon fraction and to maintain the deoxygenation catalyst in sulfided form with the hydrogen sulfide.
9. The method of claim 8 , wherein the step of contacting a combined feed comprises adjusting a ratio of petroleum distillate feedstock to the biorenewable feedstock to at least meet sulfur requirements.
10. The method of claim 8 , wherein the step of contacting the combined feed comprises contacting the combined feed with hydrogen recycle gas.
11. The method of claim 8 , wherein the step of contacting the combined feed comprises contacting the combined feed in the reaction zone of a treating reactor.
12. The method of claim 8 , further comprising the step of pretreating the petroleum distillate feedstock prior to the step of contacting the petroleum distillate feedstock step.
13. The method of claim 1 , further comprising the steps of:
introducing the petroleum distillate feedstock with hydrogen gas into a hydrotreating reactor in the presence of the hydrotreating catalyst under hydrotreating conditions comprising a temperature of about 260° C. to about 454° C., a hydrogen partial pressure of about 2000 kPa to about 14000 kPa, and a liquid hourly space velocity of about 0.5 hr −1 to about 10 hr −1 to form the effluent mixture comprising hydrogen sulfide; and
co-feeding the combined feed comprising the effluent mixture, a recycle liquid, and the biorenewable feedstock to a reaction zone at reaction conditions in the presence of the deoxygenation catalyst to provide the reaction product and to maintain a minimum of at least about 150 ppm sulfur in the combined feed.
14. The method of claim 13 , wherein the step of introducing a petroleum distillate feedstock with hydrogen gas comprises introducing the petroleum distillate feedstock with hydrogen recycle gas.
15. The method of claim 13 , wherein the step of introducing a petroleum distillate feedstock with hydrogen gas comprises introducing the petroleum distillate feedstock with fresh hydrogen gas.
16. The method of claim 13 , wherein the step of co-feeding effluent mixture, recycle liquid, and biorenewable feedstock comprises adjusting the amount of effluent mixture to biorenewable feedstock in the combined feed.