High-strength transparent zirconia sintered body, process for producing the same, and uses thereof
Translucent zirconia sintered bodies have had a problem that incorporation of titania improves translucency but lowers mechanical strength. The invention provides: a zirconia sintered body containing titanium oxide, the sintered body containing 6-15 mol % yttria and 3-20 mol % titania and having an in-line transmission of 50% or higher when examined at a sample thickness of 1 mm and a measuring wavelength of 600 nm; and a zirconia sintered body having especially high translucency which is a high-quality transparent zirconia sintered body that contains 3-20 mol % titania and 6-15 mol % yttria and has an in-line transmission, as measured at a wavelength of 600 nm, of 73% or higher and a haze value of 2.0% or less and that is highly translucent and is undimmed (cloudless). The invention further relates to a production process in which a powder having the composition is molded and thereafter subjected to ordinary-pressure primary sintering and hot isostatic pressing (HIP) under specific conditions.
1. A zirconia sintered body comprising yttria in an amount of 6-15 mol % and titania in an amount of 3-20 mol %, the zirconia sintered body having an average grain size of less than 30 μm and an in-line transmission of 73% or higher when examined at a sample thickness of 1 mm and a measuring wavelength of 600 nm, and further has a haze value of 2.0% or less.
2. A zirconia sintered body comprising yttria in an amount of 6-15 mol % and titania in an amount of 3-20 mol %, the zirconia sintered body having an average grain size of 30-60 μm and an in-line transmission of 60% or higher when examined at a sample thickness of 1 mm and a measuring wavelength of 600 nm.
3. The zirconia sintered body as claimed in claim 2 having a brightness L* of 84-90.
4. The zirconia sintered body as claimed in claim 2 having a color hue in which a* is −1.5 to 0.2 and b* is 0.0 to 4.0.
5. A process for producing a zirconia sintered body containing 3-20 mol % titania and 6-15 mol % yttria, characterized by molding a zirconia powder which contains 3-20 mol % titania and 6-15 mol % yttria, subjecting the resultant compact to primary sintering at ordinary pressure and then to hot isostatic pressing (HIP) to obtain a sintered body having a ratio of reduced Ti of 20% or higher, and annealing the sintered body to obtain a zirconia sintered body as claimed in claim 1 .
6. The process for producing a zirconia sintered body as claimed in claim 5 characterized in that the sintered body obtained by the primary sintering has a relative density of 94% or higher and an average grain size of 3 μm or less and this sintered body is subjected to HIP.
7. The process for producing a zirconia sintered body as claimed in claim 5 characterized in that the sintered body obtained through sintering at 1,200-1,400° C. is subjected to HIP.
8. The process for producing a zirconia sintered body as claimed in claim 5 characterized in that the HIP is conducted at 1,400-1,800° C.
9. An optical part which comprises the zirconia sintered body as claimed in claim 1 .
10. The optical part as claimed in claim 9 which comprises an optical lens.
11. An exterior part for electronic appliances which comprises the zirconia sintered body as claimed in claim 1 .
12. The zirconia sintered body as claimed in claim 2 which has an in-line transmission of 73% or higher when examined at a sample thickness of 1 mm and a measuring wavelength of 600 nm.