Flash photolysis system
View Patent ↗A pump-probe LFP system is adapted to a substantially lower energy requirement of a pump light source and a probe light source. The LFP system includes a photonic crystal fiber based probe light source, a pump light source adapted to produce light pulses with nanojoule or higher energy, a main laser source to generate a first beam portion to the probe light source and a second beam portion to the pump light source, a delay generator, computer, an optical modulator, and a detector. One or more lenses can be used to focus the light beams to areas less than about 1 micron on a sample, where the sample can be rastered to provide domain specific flash photolysis data of the sample.
1. A system for flash photolysis comprising:
a light source for generating a beam of light;
a beam splitter for generating a first beam portion and a second beam portion from the beam of light;
a probe light source responsive to the first beam portion for generating a pulsed probe beam of light to travel through a sample in a flash photolysis application;
a pump light source responsive to the second beam portion for generating a pulsed pump beam of light to travel through the sample and initiate a chemical reaction in the sample;
a delay generator to regulate a time delay between generation of the pulsed probe beam and generation of the pulsed pump beam throughout the flash photolysis application;
a detector to receive the pulsed probe beam exiting the sample to detect a change in absorption of the pulsed probe beam in the sample caused by the pulsed pump beam; and
a lens for focusing one of the pulsed probe beam and the pulsed pump beam.
2. The system for flash photolysis according to claim 1 , wherein the light source is a laser and the probe light source is a laser energized photonic crystal fiber.
3. The system for flash photolysis according to claim 1 , further comprising another lens for focusing the other of the pulsed probe beam and the pulsed pump beam.
4. The system for flash photolysis according to claim 1 , wherein the lens comprises a microscope objective.
5. The system for flash photolysis according to claim 1 , wherein the lens is configured to focus one of the pulsed probe beam and the pulsed pump beam to an area of less than about 1 square micron.
6. The system for flash photolysis according to claim 1 , further including an optical modulator between the beam splitter and the delay generator for modulating the pulsed pump beam.
7. The system for flash photolysis according to claim 6 , wherein the optical modulator is operated to block some of the pump pulses to obtain a spectrum of the probe beam pulse traveling through the sample when unpumped.
8. The system for flash photolysis according to claim 7 , wherein the optical modulator is operated to block the pump pulses at a rate of every other one of the probe beam pulses to obtain a spectrum of the probe beam pulse traveling through the sample when unpumped.
9. The system for flash photolysis according to claim 6 , wherein the optical modulator is operated to pass through some of the pump pulses to obtain a spectrum of the probe beam pulse traveling through the sample when pumped.
10. The system for flash photolysis according to claim 9 , wherein the optical modulator is operated to pass the pump pulses at a rate of every other one of the probe beam pulses to obtain a spectrum of the probe beam pulse traveling through the sample when pumped.
11. The system for flash photolysis according to claim 6 , wherein the optical modulator is operated to modulate the pump beam according to a lock-in amplification algorithm.
12. The system for flash photolysis according to claim 1 , wherein the delay generator is one of an optical delay line and an optical delay generator.
13. A system for flash photolysis comprising:
a light source for generating a beam of light;
a beam splitter for generating a first beam portion and a second beam portion from the beam of light;
a probe light source responsive to the first beam portion for generating a pulsed probe beam of light to travel through a sample in a flash photolysis application;
a pump light source responsive to the second beam portion for generating a pulsed pump beam of light to travel through the sample and initiate a chemical reaction in the sample;
a delay generator to regulate a time delay between generation of the pulsed probe beam and generation of the pulsed pump beam throughout the flash photolysis application;
a detector to receive the pulsed probe beam exiting the sample to detect a change in absorption of the pulsed probe beam in the sample caused by the pulsed pump beam; and
a translation stage for controlling position of the sample relative to one of the pulsed probe beam of light and the pulsed pump beam of light.
14. The system for flash photolysis according to claim 13 , wherein the translation stage is operable to change the position of the sample in two dimensions.
15. The system for flash photolysis according to claim 13 , wherein the translation stage is operable to raster the sample in a series of spots where each spot is less than about 1 square micron.
16. A system for flash photolysis comprising:
a light source for generating a beam of light;
a beam splitter for generating a first beam portion and a second beam portion from the beam of light;
a probe light source responsive to the first beam portion for generating a pulsed probe beam of light to travel through a sample in a flash photolysis application;
a pump light source responsive to the second beam portion for generating a pulsed pump beam of light to travel through the sample and initiate a chemical reaction in the sample;
a delay generator to regulate a time delay between generation of the pulsed probe beam and generation of the pulsed pump beam throughout the flash photolysis application;
a detector to receive the pulsed probe beam exiting the sample to detect a change in absorption of the pulsed probe beam in the sample caused by the pulsed pump beam;
a lens for focusing one of the pulsed probe beam and the pulsed pump beam; and
a translation stage for controlling position of the sample relative to one of the pulsed probe beam of light and the pulsed pump beam of light.
17. The system for flash photolysis according to claim 16 , further comprising another lens for focusing the other of the pulsed probe beam and the pulsed pump beam,
18. The system for flash photolysis according to claim 16 , wherein the lens comprises a microscope objective.
19. The system for flash photolysis according to claim 16 , wherein the lens is configured to focus one of the pulsed probe beam and the pulsed pump beam to an area of less than about 1 square micron.
20. The system for flash photolysis according to claim 16 , wherein the translation stage is operable to raster the sample in a series of spots where each spot is less than about 1 square micron.