Cyclic adsorption process using centrifugal machines

1. An adsorption system for the separation of a more absorbable gas from a less absorbable gas in a gas mixture comprising:

at least one adsorber vessel containing at least one adsorber bed for receiving the more absorbable gas and capable of undergoing the steps of pressurization and depressurization;

at least one centrifugal machine in fluid flow communication with the adsorber vessel and designed to provide gas flow for the pressurization and the depressurization steps and which accelerates and decelerates in response to instructions;

a controller for receiving data signals for the decreasing pressure ratio conditions across the centrifugal machine during deceleration and capable of sending instructions to the centrifugal machine and the flow control valves in response to the conditions;

one or more flow control valves located at the suction inlet of the centrifugal machine and capable of adjustment upon receiving instructions to adjust;

wherein the centrifugal machine is designed to pressurize the adsorber bed in which the more absorbable gas is adsorbed while removing the less absorbable gas from the adsorber vessel bed and/or depressurized the adsorber bed to remove the more absorbable gas from the adsorber bed;

and further wherein the controller sends instructions to the one or more flow control valves which adjust in response to the instructions and adjusts the mass flow of the more absorbable gas during deceleration such that the deceleration rate of the centrifugal machine obtains its lowest operating speed near the point required to begin acceleration.

2. The adsorption system of claim 1 wherein the one or more flow control valves are placed in the suction piping at a distance equivalent to the diameter of two or more times the suction pipe diameter upstream of the machine.

3. The adsorption system of claim 1 wherein the more absorbable gas is nitrogen and the less absorbable gas is oxygen.

4. A pressure swing adsorption system for the separation of a at least one more absorbable gases from one or more less absorbable gases in a gas mixture comprising the following components in fluid flow communication:

at least one adsorber vessel containing at least one adsorber bed for adsorbing and desorbing the at least one more absorbable gases during cyclic operation;

at least one centrifugal machine having a compressor and drive train and designed to accomplish the steps of at least depressurization and pressurization and capable of accepting instructions for accelerating and decelerating during the pressurization and depressurization steps;

a controller for receiving data signals about the operating conditions in the system including the pressure ratio conditions during deceleration and for sending instructions to the centrifugal machine in response to the operating conditions; and

a control system in communication with the drive train and capable of accepting the instructions from the controller to control the speed of the drive train during deceleration; and

wherein the controller is configured to send instructions to the control system to reduce the deceleration rate of the centrifugal machine in response to the decreasing pressure ratio conditions to arrive at the minimum operating speed of the centrifugal machine near the xpoint required to begin acceleration.

5. A pressure swing adsorption system of claim 4 wherein the control system is a dynamic braking system.

6. A pressure swing adsorption system of claim 4 wherein the control system is a regenerative braking system.

7. A pressure swing adsorption system of claim 4 wherein the control system is an aerodynamic braking system.

8. A pressure swing adsorption system of claim 7 wherein the aerodynamic braking system is comprised of one or more flow control valves at the suction inlet of the centrifugal machine and capable of receiving the instructions from the controller for movement of the values.

9. A pressure swing adsorption system of claim 8 wherein the flow control valves are capable of being opened to increase mass flow or closed to reduce mass flow.

10. A pressure swing adsorption system of claim 9 wherein the flow control valve(s) are placed in the suction piping at a distance equivalent to the diameter of two or more times the suction pipe diameter upstream of the centrifugal machine.

11. A pressure swing adsorption system of claim 4 wherein the centrifugal machine is used in the absence of a positive displacement machine.

12. A pressure swing adsorption system of claim 4 wherein the system is designed for a PSA or VPSA process and the more absorbable gas is nitrogen and the less absorbable gas is oxygen.

13. A pressure swing adsorption system of claim 4 wherein the controller is designed to limit the idle time to less than 8 percent of the total cycle time.

14. A pressure swing adsorption system of claim 4 wherein the controller is designed to limit the idle time to less than 3 seconds.

15. A pressure swing adsorption system of claim 4 wherein the system is a two-bed system.

16. A pressure swing adsorption system of claim 4 wherein the system is for the production or oxygen from air.

17. A pressure swing adsorption system of claim 4 wherein the pressure ratio conditions during deceleration are measured using a pressure measuring device.