Iron-based sintered alloy for valve seat, and valve seat for internal combustion engine
It is an object of the present invention to provide a valve seat product in which the amount of hard particles added to improve the wear resistance of a valve seat of an internal combustion engine is increased, and is excellent in the mechanical strength and machinability. In order to achieve the object, an iron-based sintered alloy material for a valve seat is employed which is made to contain a first hard particle having an average primary particle diameter of 5 to 20 μm and a second hard particle having an average primary particle diameter of 20 to 150 μm in a texture, wherein a particle size distribution curve measured by laser diffraction scattering analysis has N peaks (N is an integer equal to or larger than 2) and when particle diameters corresponding to the peak top positions are denoted as D T1 to D TN , a peak top particle diameter difference between neighboring D Tn-1 and D Tn (|D Tn-1 −D Tn |: n is an integer equal to or larger than 2 and equal to or smaller than N) is in the range of 15 to 100 μm in at least one neighboring D Tn-1 and D Tn ; and the total area ratio occupied by both of the first hard particle and the second hard particle constituting the mixed hard particle in the texture of the iron-based sintered alloy is 10 to 60% by area.
1. An iron-based sintered alloy material for a valve seat comprising a first hard particle and a second hard particle dispersed in an iron-based sintered alloy matrix, wherein the first hard particle and the second hard particle have a same hardness with a Vickers Hardness in a range of 650HV0.1 to 1100HV0.1, wherein the first hard particle is different in an average particle diameter from the second hard particle, and wherein the iron-based sintered alloy material for a valve seat satisfies all of Conditions 1 to 4 below:
Condition 1: the first hard particle has an average primary particle diameter of 5 to 20 μm;
Condition 2: the second hard particle has an average primary particle diameter of 20 to 150 μm;
Condition 3: in a mix of a plurality of first hard particles and a plurality of second hard particles, a particle size distribution curve has N peaks (N is an integer equal to or larger than 2) and when particle diameters corresponding to peak top positions are denoted as D T1 to D TN , a peak top particle diameter difference between at least one neighboring D Tn-1 and D Tn (|D Tn-1 −D Tn |: n is an integer equal to or larger than 2 and equal to or smaller than N) is in a range of 15 to 100 μm; and
Condition 4: a total area ratio occupied by the mix in a texture of the iron-based sintered alloy material is 10 to 60% by area.
2. The iron-based sintered alloy material for a valve seat according to claim 1 , wherein the first hard particle and the second hard particle comprise any composition selected from cobalt-based intermetallic compound composition 1, cobalt-based intermetallic compound composition 2 and an iron-based intermetallic compound composition below:
Cobalt-based intermetallic compound composition 1:
silicon: 0.5 to 4.0% by weight,
chromium: 5.0 to 20.0% by weight,
molybdenum: 20.0 to 40.0% by weight, and
a balance: cobalt and inevitable impurities;
Cobalt-based intermetallic compound composition 2:
silicon: 0 to 4.0% by weight,
nickel: 5.0 to 20.0% by weight,
chromium: 15.0 to 35.0% by weight,
molybdenum: 15.0 to 35.0% by weight, and
a balance: cobalt and inevitable impurities; and
Iron-based intermetallic compound composition:
cobalt: 10.0 to 20.0% by weight,
nickel: 2.0 to 20.0% by weight,
chromium: 12.0 to 35.0% by weight,
molybdenum: 12.0 to 35.0% by weight, and
a balance: iron and inevitable impurities.
3. The iron-based sintered alloy material for a valve seat according to claim 1 , wherein the iron-based sintered alloy material contains two or more alloying constituents selected from carbon, silicon, chromium, molybdenum, cobalt, nickel, copper, tungsten and vanadium, in a range of 13.0 to 90.0% by weight in the texture.
4. The iron-based sintered alloy material for a valve seat according to claim 1 , wherein the texture of the iron-based sintered alloy material comprises a solid lubricant powder of a sulfide or a fluoride in a range of 0.2 to 5.0% by area against to 100% by area of an area ratio occupied by the mix and the matrix.
5. A valve seat of an internal combustion engine, manufactured by using an iron-based sintered alloy material for a valve seat according to claim 1 .
6. An iron-based sintered alloy material for a valve seat, comprising:
first hard particles; and
second hard particles;
wherein the first hard particles and the second hard particles have a same hardness with a Vickers Hardness in a range of 650HV0.1 to 1100HV0.1;
wherein the first hard particles are different in an average particle diameter from the second hard particles;
wherein the first hard particles and the second hard particles are dispersed in a matrix;
wherein the first hard particles have a diameter of 5 to 20 μm;
wherein the second hard particles have a diameter of 20 to 150 μm;
wherein a particle size distribution curve for the first hard particles and the second hard particles dispersed in the matrix has N peaks (where N is an integer equal to or larger than 2), wherein particle diameters corresponding to peak top positions on the curve are denoted as D T1 to D TN , and wherein a peak top particle diameter difference between at least one neighboring D Tn-1 and D Tn (|D Tn-1 −D Tn |: n is an integer equal to or larger than 2 and equal to or smaller than N) is in a range of 15 to 100 μm;
and wherein an area occupied by the first hard particles and the second hard particles is 10 to 60% of an area of the material.