Process for isomerizing A (hydro)fluoroalkene
A process for isomerizing a (hydrohalo)fluoroalkene, the process comprising contacting the (hydrohalo)fluoroalkene with a catalyst a catalyst which is a chromia-containing catalyst supported on AlF 3 or fluorinated alumina.
1. A process for isomerising a (hydro)fluorobutene or (hydro)fluoropropene, the process comprising contacting the (hydro)fluorobutene or (hydro)fluoropropene with a catalyst which is a chromia-containing catalyst supported on AlF 3 or fluorinated alumina, wherein the chromia-containing catalyst contains an additional metal selected from zinc, magnesium, nickel, cobalt, silver, copper, aluminium, tin, zirconium, and mixtures thereof.
2. A process for isomerising a (hydro)fluorobutene or (hydro)fluoropropene, the process comprising contacting a E-(hydro)fluorobutene or E-(hydro)fluoropropene with a catalyst which is a chromia-containing catalyst supported on AlF 3 or fluorinated alumina to convert the E-(hydro)fluorobutene or E-(hydro)fluoropropene to a Z-(hydro)fluorobutene or Z-(hydro)fluoropropene, wherein the chromia-containing catalyst contains an additional metal selected from zinc, magnesium, nickel, cobalt, silver, copper, aluminium, tin, zirconium, and mixtures thereof.
3. A process according to claim 1 , wherein the isomerisation results in the changing of the ratio of the E and Z isomers.
4. A process according to claim 3 , wherein the ratio of the Z isomer to the E isomer increases.
5. A process according to claim 1 , wherein the isomerisation is carried out as an in situ step in the synthesis of the (hydro)fluorobutene or (hydro)fluoropropene.
6. A process according to claim 5 , wherein the isomerisation results in a changing of the ratio of the E to Z isomer compared to what it would have been if the catalyst had not been utilized.
7. A process according to claim 1 , wherein the ratio of E to Z isomers changes from that which is the kinetic equilibrium from the reaction preparing the (hydro)fluorobutene or (hydro)fluoropropene.
8. A process according to claim 1 , wherein the additional metal in the chromia-containing catalyst is present at a level of at least 0.01% by weight of the catalyst, or wherein the additional metal in the chromia-containing catalyst is present at a level of at least 0.1% by weight of the catalyst, or wherein the additional metal in the chromia-containing catalyst is present at a level of at least 1% by weight of the catalyst, or wherein the additional metal in the chromia-containing catalyst is present at a level of no more than 20% by weight of the catalyst, or wherein the additional metal in the chromia-containing catalyst is present at a level of no more than 10% by weight of the catalyst.
9. A process according to claim 1 , wherein the (hydro)fluoropropene has the formula CX 3 CX═CX 2 wherein each X is, independently, H or F provided that at least one X is F and at least one X is H, Cl, Br or I.
10. A process according to claim 9 , wherein the (hydro)fluoropropene is selected from the monofluoropropene 1-fluoropropene (CH 3 CH═CHF), the difluoropropenes 1,2-difluoropropene (HFC═CFCH 3 ) and 1,3-difluoropropene (HFC═CHCH 2 F), the trifluoropropenes 1,2,3-trifluoropropene (HFC═CFCH 2 F) and 1,3,3-trifluoropropene (HFC═CHCF 2 H), the tetrafluoropropenes 1,3,3,3-tetrafluoropropene (HFC═CHCF 3 ) and 1,2,3,3-tetrafluoropropene (HFC═CFCF 2 H), and the pentafluoropropene 1,2,3,3,3-pentafluoropropene (HFC═CFCF 3 ).
11. A process according to claim 1 conducted at a temperature of from −50 to 400° C., and/or a pressure of from 0 to 30 bara, and/or conducted in the presence of HF.