IP Library › Granted Patent US 8,747,659
Granted Patent B2
US 8,747,659 · App. 12/660,249 · Granted Jun 10, 2014

Hydrotreating process

Inventors: Gabor Kiss (Hampton, NJ); Lulian Nistor (Center Valley, PA); John Zengel (Clinton, NJ)
Assignee: ExxonMobil Research and Engineering Company
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Quick Facts
Patent No.
US 8,747,659
App. No.
12/660,249
Granted
Jun 10, 2014
Kind
B2
Abstract

A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.

Claims (8)

1. A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed boiling in the diesel fuel range using a fresh supported CoMo catalyst, the process comprising:

treating a fresh, sulfided CoMo hydrotreating catalyst having a support of amorphous alumina, silica or alumina-silica, under first hydrotreating conditions including a temperature of about 300° C. to about 350° C., a pressure of about 1.5 MPaq to about 3.5 MPaq, and an LHSV of about 0.3 hr −1 to about 1.0 hr −1 with a second hydrocarbon feed having a lower aromatics content than said first feed, the second hydrocarbon feed having an aromatics content of less than 20 wt % to reduce the activity of the catalyst by at least 5% and, following the treatment with the second hydrocarbon feed,

hydrotreating the first feed using the treated catalyst under hydrotreating conditions including a temperature of about 300° C. to about 380° C., a pressure of about 1.5 MPag to about 3.5 MPaq, and an LHSV of about 0.2 hr −1 to about 0.8 hr − to reduce the sulfur content of said first feed to 15 wppm or less.

2. The process of claim 1 , wherein said treating with the second hydrocarbon feed is conducted from 3 days to 10 days.

3. The process of claim 1 , wherein said first and second hydrotreating conditions are substantially the same.

4. The process of claim 1 , wherein the first feed has an aromatics content of at least 20 wt %.

5. The process of claim 1 , wherein the second feed is produced by adding aliphatic hydrocarbons to the first feed.

6. The process of claim 5 , further comprising adding said aliphatic Hydrocarbons to the first feed so as to reduce an aromatics content thereof by at least 50%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2011
From: KISS, GABOR; NISTOR, IULIAN; ZENGEL, JOHN
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 026870/0965 →
Continuity (1)
Related Publication 20110203971A1 · Aug 25, 2011