Capsules
The present invention related to (micro-or nano-) capsules that have two different functional groups on the outer shell of the particles that allow deposition onto the textile surfaces (i.e. exhibit substantivity) and subsequent covalent bonding of the particles onto the textile (i.e. are reactive towards the fiber).
1. A capsule, characterized in that the capsule is a microcapsule or nanocapsule having a core and a polymeric shell, which shell is characterized in that the shell has cationic and fiber-reactive groups on the outside of the shell surface, characterized in that the ratio of cationic groups to the reactive fiber groups on the shell surface is 50:1 up to 1:1,
the reactive groups are methylol groups of melamine formaldehyde resin; methylol groups of methylol acrylamide; 2,4 -dichloro-1,3,5-triazine (DCT); mono-chlorotriazine (MCT), wherein the triazine can be additionally substituted by one substituent chosen form the group consisting of —F, —OH, —OC 1 -C 4 alkyl, —NH 2 , —NH(C 1 -C 4 alkyl) and -N(C 1 -C 4 alkyl) 2 ; mono-fluorotriazine, wherein the triazine can be additionally substituted by one subsitutent chosen form the group consisting of —F, —OH, —OC 1 -C 4 alkyl, —NH 2 , —NH(C 1 -C 4 alkyl) and —N(C 1 -C 4 alkyl) 2 , 2-sulfooxyethylsulfonyl group; 2-chloroethylsulfonyl; vinylsulfonyl group; alkoxychlorotriazine; 2-(sulfothio)ethylsulfonyl groups; trichloropyrimidine; difluorochloropyrimidine (DFCP); dichloroquinoxaline; 2,3-dichloro-chinoxaline (DCC) and 3-chloropropionamine (CPA) and the fiber reactive groups are groups which form covalent bonds with the functional groups of the fiber.
2. The capsule according to claim 1 , characterized in that the core comprises an active ingredient within the polymeric shell.
3. The capsule according to claim 2 wherein the capsule further comprises a matrix polymer with the active ingredient distributed evenly throughout the matrix.
4. The capsule according to claim 1 characterized in that the size of the capsule is from 10 nm to 500 μm.
5. The capsule according to claim 1 , wherein the cationic groups are quaternary ammonium groups.
6. The capsule according to claim 2 , wherein the core is a solid or liquid compound.
7. The capsule according to claim 3 , wherein the matrix contains secondary polymer particles that are capable of absorbing and retaining active materials.
8. The capsule according to claim 2 , wherein the core contains active materials selected from UV absorbers, UV reflectors, active dye tracer materials, enzymes, detergent builders, bioactive or anti-microbial/fungal agents, antistats, drugs or pharmaceuticals, sunblock agents, dyes, pigments, colorants, scents or fragrances, fire retardant or suppressant chemicals, metallic reflector colloids, reflective particles, magnetic particles, thermochromic materials, insect repellents, heat-absorbing or -releasing phase change agents, bleach catalysts, bleach activators, emollients, fabric softeners, zeolites and activated carbon.
9. A liquid formulation comprising capsules according to claim 1 .
10. A material treated with a capsule according to claim 1 , wherein the fiber reactive groups form covalent bonds with functional groups of the fiber.
11. The material according to claim 10 , wherein the material is selected from fibers, yarns, fabrics, textiles or webs, and paper.
12. The capsule according to claim 1 , wherein the fiber reactive groups are methylol groups of a melamine formaldehyde resin or methylol groups of methylol acrylamide.