Water-based ink, water-based ink set, and process for producing dispersion
An aqueous ink ensuring less blurring and high color formation on plain paper, satisfactory color formation and fixing property on special paper and excellent ejection stability is realized by using a microcapsule of a colorant encapsulated with a polymer and rendered dispersible in water and specifying the amount of the aromatic ring in the polymer to be from 20 to 70 wt % of the polymer.
1. An aqueous ink comprising a dispersing element of a pigment encapsulated with a polymer and rendered dispersible in water, and two or more members selected from an acetylene glycol-base surfactant, an acetylene alcohol-base surfactant, a silicon-base surfactant, a glycol ether and an 1,2-alkylene glycol having a carbon number of 4 to 10, wherein the amount of an aromatic ring in said polymer is from 25 to 50 wt % of said polymer, and wherein the aqueous ink comprises a liquid component in which the dispersing element is dispersed, wherein the liquid component contains a total amount of polyvalent metal ions of 200 ppm or less, and does not contain any one of Si, Ca, Mg, Fe, Cr, Ni or Zr ions in an amount of more than 50 ppm.
2. The aqueous ink as claimed in claim 1 , wherein the weight ratio of said pigment to said polymer is from 10:90 to 90:10.
3. The aqueous ink as claimed in claim 1 , wherein the weight ratio of said pigment to said polymer is from 40:60 to 90:10 for a black pigment, from 50:50 to 90:10 for a yellow pigment, from 50:50 to 90:10 for a red pigment and from 20:80 to 70:30 for a blue pigment.
4. The aqueous ink as claimed in claim 1 , wherein the liquid component contains polyvalent anions in an amount of 1,000 ppm or less.
5. The aqueous ink as claimed in claim 4 , wherein said polyvalent anions contained in the liquid component are selected from the group consisting of sulfate ions, and phosphate ions.
6. The aqueous ink as claimed in claim 1 , wherein the liquid component contains monovalent cations in an amount of 5,000 ppm or less.
7. The aqueous ink as claimed in claim 6 , wherein said monovalent cations are alkali metal ions.
8. The aqueous ink as claimed in claim 7 , wherein said alkali metal ions are selected from the group consisting of lithium ions, sodium ions and potassium ions.
9. The aqueous ink as claimed in claim 6 , wherein said monovalent cations are ammonium ions.
10. The aqueous ink as claimed in claim 1 , wherein the liquid component contains monovalent anions in an amount of 3,000 ppm or less.
11. The aqueous ink as claimed in claim 10 , wherein said monovalent anions are halogen ions.
12. The aqueous ink as claimed in claim 11 , wherein said halogen ions are selected from the group consisting of chlorine ions, bromine ions and iodine ions.
13. The aqueous ink as claimed in claim 1 , wherein the liquid component contains polyvalent metal ions in an amount of 200 ppm or less, polyvalent anions in an amount of 1,000 ppm or less, monovalent cations in an amount of 5,000 ppm or less, monovalent anions in an amount of 3,000 ppm or less and free polymer in an amount of 2 wt % or less.
14. The aqueous ink as claimed in claim 1 , wherein the polymer encapsulating the colorant in said dispersing element is one or more member selected from the group consisting of a polyacrylic acid ester, a styrene-acrylic acid copolymer, a polystyrene, a polyester, a polyamide, a polyimide, a silicon-containing polymer and a sulfur-containing polymer.
15. The aqueous ink as claimed in claim 1 , wherein the polymer that encapsulates the pigment is produced by an emulsification polymerization method or a phase inversion emulsification reaction method.
16. The aqueous ink as claimed in claim 1 , wherein the members comprise the acetylene glycol-base surfactant, and the glycol ether or the 1,2-alkylene glycol having a carbon number of 4 to 10.
17. The aqueous ink as claimed in claim 16 , wherein the acetylene glycol-base surfactant is present in an amount of 0.01 to 10 wt % and the 1,2-alkylene glycol having a carbon number of 4 to 10 is present in an amount of 1 wt % or more, the aqueous ink further comprising at least one of (di)ethylene glycol monobutyl ether and (di)propylene glycol monobutyl ether.
18. The aqueous ink as claimed in claim 16 , further comprising (di)propylene glycol monobutyl ether in an amount of 10 wt % or less.
19. The aqueous ink as claimed in claim 16 , further comprising (di)ethylene glycol monobutyl ether in an amount of 20 wt % or less.
20. The aqueous ink as claimed in claim 16 , wherein the 1,2-alkylene glycol having a carbon number of 4 to 10 is 1,2-hexanediol, and the 1,2-hexanediol is present in an amount of 0.5 to 10 wt %.