Acrylic copolymer with high heat resistance and high strength, and optical film comprising the same
The present invention relates to an acrylic copolymer having high heat resistance and high strength, and an optical film comprising the same, and more particularly, to an acrylic copolymer for optical films in which alkyl (meth)acrylate monomers; (meth)acrylate monomers comprising aromatic rings and/or aliphatic rings; and (meth)acrylamide monomers are included and polymerized. An acrylic copolymer according to the present invention is excellent in heat resistance while maintaining transparency. Further, an optical film comprising a compound resin including the acrylic copolymer has superior transparency and heat resistance and is excellent in formability, adhesion, retardation properties, and durability.
1. An acrylic copolymer for optical films, polymerized by comprising:
1) 50 to 98.9% by weight of alkyl (meth)acrylate monomers;
2) 1 to 49.9% by weight of cycloalkyl (meth)acrylate monomers or aryl (meth)acrylate monomers; and
3) 0.1 to 10% by weight of (meth)acrylamide monomers.
2. The acrylic copolymer for optical films of claim 1 , wherein the alkyl (meth)acrylate monomers have alkyl groups with 1 to 10 carbon atoms.
3. The acrylic copolymer for optical films of claim 1 , wherein the alkyl (meth)acrylate monomers are methyl (meth)acrylate monomers.
4. The acrylic copolymer for optical films of claim 1 , wherein the cycloalkyl (meth)acrylate monomers have a cycloalkyl group with 4 to 12 carbon atoms, and the aryl (meth)acrylate monomers have an aryl group with 6 to 12 carbon atoms.
5. The acrylic copolymer for optical films of claim 1 , wherein the cycloalkyl (meth)acrylate monomers or aryl (meth)acrylate monomers are one or more selected from the group consisting of cyclopentyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, cyclohexyl acrylate, 3,3,5-trimethylcyclohexyl methacrylate, 4-t-butylcyclohexyl methacrylate, phenyl methacrylate, 4-t-butylphenyl methacrylate, 4-methoxyphenyl methacrylate, and 2-naphthyl methacrylate.
6. The acrylic copolymer for optical films of claim 1 , wherein the (meth)acrylamide monomers are N-substituted methacrylamide, or methacrylamide including aromatic rings and/or aliphatic rings, and substituents of the N-substituted methacrylamide are one selected from the group consisting of ethyl, isopropyl, tert-butyl, cyclohexyl, benzyl, and phenyl groups.
7. The acrylic copolymer for optical films of claim 1 , wherein the acrylic copolymer has a glass transition temperature (Tg) of not less than 120° C.
8. The acrylic copolymer for optical films of claim 1 , wherein the acrylic copolymer has a weight average molecular weight of 50,000 to 500,000.
9. A compound resin in which an acrylic copolymer for optical films of claim 1 is mixed with resins having aromatic rings and/or aliphatic rings included in main chains thereof.
10. The compound resin of claim 9 , wherein the resins having aromatic rings and/or aliphatic rings included in main chains thereof are polycarbonate resins.
11. The compound resin of claim 10 , comprising 60 to 99.9% by weight of the acrylic copolymer for optical films and 0.1 to 40% by weight of polycarbonate resin.
12. An optical film comprising the compound resin of claim 9 .
13. The optical film of claim 12 , wherein the optical film is a retardation compensation film or a protection film.
14. The optical film of claim 13 , wherein the retardation compensation film is a retardation compensation film for a VA (Vertical Alignment) mode liquid crystal display device or a retardation compensation film for a TN (Twisted Nematic) mode liquid crystal display device.
15. The optical film of claim 12 , wherein the optical film has a surface directional retardation value R in of −5 nm to 200 nm represented by the following Mathematical Formula 1:
R in =( n x −n y )× d [Mathematical Formula 1]
where n x is a refractive index of a direction in which the refractive index is the greatest in the surface direction of the film, n y is a refractive index of a direction perpendicular to the n x direction in the surface direction of the film, and d is thickness of the film.
16. The optical film of claim 12 , wherein the optical film has a thickness directional retardation value R th of 5 nm to −300 nm represented by the following Mathematical Formula 2:
R th =( n z −n y )× d [Mathematical Formula 2]
where n x is a refractive index of a direction at which the refractive index is the greatest in the surface direction of the film, n y is a refractive index of a direction perpendicular to the n x direction in the surface direction of the film, n z is a thickness directional refractive index, and d is thickness of the film.
17. The optical film of claim 12 , wherein the optical film has a surface directional retardation value R in of 20 nm to 80 nm represented by the following Mathematical Formula 1 and a thickness directional retardation value R th of −50 nm to −300 nm represented by the following Mathematical Formula 2:
R in =( n x −n y )× d [Mathematical Formula 1]
R th =( n z −n y )× d [Mathematical Formula 2]
where n x is a refractive index of a direction at which the refractive index is the greatest in the surface direction of the film, n y is a refractive index of a direction perpendicular to the n x direction in the surface direction of the film, n z is a thickness directional refractive index, and d is thickness of the film.
18. The optical film of claim 12 , wherein the optical film has a surface directional retardation value R in of 0 nm to 10 nm represented by the following Mathematical Formula 1 and a thickness directional retardation value R th of −10 nm to 10 nm represented by the following Mathematical Formula 2.
R in =( n x −n y )× d [Mathematical Formula 1]
R th =( n z −n y )× d [Mathematical Formula 2]
where n x is a refractive index of a direction at which the refractive index is the greatest in the surface direction of the film, n y is a refractive index of a direction perpendicular to the n x direction in the surface direction of the film, n z is a thickness directional refractive index, and d is thickness of the film.