Method for producing polyacrylic acid (salt) type water absorbent resin powder
A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability. Disclosed is a method for producing a polyacrylic acid (salt)-type water absorbent resin powder, which includes, in sequence, a step of polymerizing an aqueous solution of acrylic acid (salt)-type monomer; a step of gel-crushing a gel of a water-containing gel-like crosslinked polymer during polymerization or after polymerization; a step of drying the water-containing gel-like crosslinked polymer; and a step of pulverizing and classifying the dried polymer, wherein water absorbent resin fine particles having a particle size of less than 150 μm or a hydrated-particles thereof is added to a step prior to the drying step, and in the drying step, hot air drying is carried out with a hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30° C. to 100° C., and a hot air temperature of 140° C. to 235° C.
1. A method for producing a water absorbent resin powder, comprising in sequence:
a polymerization step of an aqueous solution of a monomer, the solution including acrylic acid and/or a salt thereof as a main component;
a gel-crushing step of a water-containing gel-like crosslinked polymer during or after polymerization;
a drying step of the water-containing gel-like crosslinked polymer; and
a pulverization and classification step of the dried polymer,
wherein,
water absorbent resin fine particles having a particle size of less than 150 μm or hydrated-particles thereof are added to a step prior to the drying step, and
hot air drying is carried out in the drying step with hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30 to 100° C., and a temperature of 140 to 235° C.
2. The method for producing according to claim 1 , wherein in the drying step, the hot air drying is carried out for 10 to 120 minutes, and at a temperature of 160° C. to 220° C.
3. The method for producing according to claim 1 , wherein the neutralization rate of the acrylic acid and/or the salt thereof is 50 to 100% by mole.
4. The method for producing according to claim 1 , wherein the water absorbent resin fine particles are separated by the classification step.
5. The method for producing according to claim 1 , wherein 1 to 40% by weight of the dried polymer is separated as water absorbent resin fine particles in the classification step, and then is added to a step prior to the drying step.
6. The method for producing according to claim 1 , wherein the water absorbent resin fine particles or hydrated-particles thereof are added to at least one step of the polymerization step, the gel-crushing step and the drying step.
7. The method for producing according to claim 1 , wherein the water absorbent resin fine particles or hydrated-particles thereof are added to the water-containing gel-like crosslinked polymer during or after polymerization.
8. The method for producing according to claim 1 , wherein the water absorbent resin fine particles or hydrated-particles thereof are added to the water-containing gel-like crosslinked polymer during kneader polymerization.
9. The method for producing according to claim 1 , wherein the polymerization step is carried out by continuous kneader polymerization or continuous belt polymerization, and the water-containing gel-like crosslinked polymer is gel-crushed at the time of polymerization and/or after polymerization.
10. The method for producing according to claim 1 , wherein in the polymerization step of the aqueous solution, or in the drying step of the water-containing gel-like crosslinked polymer, a water-containing gel-like crosslinked polymer containing gas bubbles is obtained.
11. The method for producing according to claim 1 , wherein the polymerization carried out in the polymerization step is foaming polymerization or boiling polymerization.
12. The method for producing according to claim 1 , wherein the aqueous solution contains gas bubbles.
13. The method for producing according to claim 1 , wherein the aqueous solution contains a methoxyphenol compound in an amount of 5 to 160 ppm relative to acrylic acid.
14. The method for producing according to claim 1 , wherein a resin solid content of the water-containing gel-like crosslinked polymer is 40% by weight or greater.
15. The method for producing according to claim 1 , wherein a weight average particle size (D50) of the water-containing gel-like crosslinked polymer is 0.5 to 4 mm.
16. The method for producing according to claim 1 , wherein a dryer used in the drying step is a through-circulation band type hot air dryer, and a flow direction of the hot air is upward and/or downward in a direction perpendicular to the ventilated band surface.
17. The method for producing according to claim 1 , wherein in the drying step, an atmosphere dew point at the beginning of drying is 50 to 90° C., and an atmosphere dew point at the end of drying is higher than or equal to 30° C. and lower than 50° C.
18. The method for producing according to claim 1 , wherein in the drying step, a temperature of the mixture of the water-containing gel-like crosslinked polymer and the water absorbent resin fine particles or hydrated-particles thereof is 40° C. to 100° C. when the mixture is fed into the dryer.
19. The method for producing according to claim 1 , further comprising:
a surface crosslinking step after the classification step.
20. The method for producing according to claim 19 , wherein a dehydration reactive surface crosslinking agent is used in the surface crosslinking step.