Stacked white OLED having separate red, green and blue sub-elements
The present invention relates to efficient organic light emitting devices (OLEDs). The devices employ three emissive sub-elements, typically emitting red, green and blue, to sufficiently cover the visible spectrum. Thus, the devices may be white-emitting OLEDs, or WOLEDs. Each sub-element comprises at least one organic layer which is an emissive layer—i.e., the layer is capable of emitting light when a voltage is applied across the stacked device. The sub-elements are vertically stacked and are separated by charge generating layers. The charge-generating layers are layers that inject charge carriers into the adjacent layer(s) but do not have a direct external connection.
1. An organic light emitting device comprising:
a cathode;
a blue-emitting sub-element comprising an emissive layer comprising a phosphorescent blue emissive material;
a charge-generating layer;
a green-emitting sub-element comprising an emissive layer comprising a phosphorescent green emissive material;
a charge-generating layer;
a red-emitting sub-element comprising an emissive layer comprising a phosphorescent red emissive material; and
an anode;
wherein each of the sub-elements has a charge balance factor of about 0.9 to 1,
wherein the emissive layers of each sub-element are within about 20% of the distance to an antinode for that emitter,
wherein each of the sub-elements is separated by a charge-generating layer, and
wherein a combined emission of the emissive materials gives a white emission from the device.
2. The organic light emitting device of claim 1 , wherein each of the sub-elements has a charge balance factor of about 0.95 to 1.
3. The organic light emitting device of claim 1 , wherein each sub-element comprises a hole transporting layer, an electron transporting layer and the emissive layer, wherein the emissive layer is the hole transporting layer, the electron transporting layer or a separate layer.
4. The organic light emitting device of claim 1 , wherein the device emits light having CIE coordinates of X=0.37±0.08, and Y=0.37±0.08.
5. The organic light emitting device of claim 1 , wherein the device is capable of a maximum external quantum efficiency of at least about 30%.
6. The organic light emitting device of claim 1 , wherein the charge-generating layers comprises an n-type layer adjacent to a p-type layer.
7. The organic light emitting device of claim 6 , wherein the p-type layers comprise a material selected from MoO 3 , V 2 O 5 , ITO, TiO 2 , WO 3 and SnO 2 .
8. The organic light emitting device of claim 7 , wherein the p-type layers comprise MoO 3 .
9. The organic light emitting device of claim 1 , wherein at least two of the emissive layers are close enough to an antinode so as to provide at least 90% of its maximum emission.
10. The organic light emitting device of claim 9 , wherein each of the emissive layers are close enough to an antinode so as to provide at least 90% of its maximum emission.