Polarizing film, optical film laminate including polarizing film, and method for manufacturing the same
An optical film laminate includes a substrate including a crystallizable ester type thermoplastic resin in the form of a continuous web; and a polarizing film including a polyvinyl alcohol type resin layer formed on the substrate, said polarizing film including a dichroic material impregnated therein in a molecularly oriented state, wherein the polarizing film is formed by providing a laminate including the polyvinyl alcohol type resin layer formed on a substrate including a crystallizable ester type thermoplastic resin in an amorphous state and subjecting the laminate to a 2-stage stretching process including a preliminary in-air stretching and an in-boric-acid-solution stretching under a temperature maintaining the amorphous state of the substrate, such that the polyvinyl alcohol type resin layer is stretched to a thickness of 10 μm or less, the polarizing film having optical properties based on the formulae P>−(10 0.929T−42.4 −1) ×100 (where T<42.3) and P≧99.9 (where T≧42.3).
1. A method for manufacturing an optical film laminate in which a polarizing film made of a polyvinyl alcohol type resin having a dichroic material impregnated therein in a molecularly oriented state is formed on a substrate made of a crystallizable ester type thermoplastic resin in the form of a continuous web, comprising steps of:
forming a stretched laminate comprising a stretched intermediate made of a molecularly oriented polyvinyl alcohol type resin by subjecting a laminate comprising a substrate made of a crystallizable ester type thermoplastic resin in an amorphous state and a polyvinyl alcohol type resin layer formed on the substrate to a preliminary in-air stretching under a temperature in which the amorphous state of the substrate can be maintained;
forming a dyed laminate including a dyed intermediate comprising the polyvinyl alcohol type resin layer having a dichroic material impregnated therein in a molecularly oriented state by impregnating the dichroic material in the stretched laminate; and
forming the optical film laminate including a polarizing film which is made of the polyvinyl alcohol type resin having the dichroic material impregnated therein in a molecularly oriented state and has a thickness of 10 μm or less, by stretching the dyed laminate in a boric acid solution, wherein the polarizing film having optical properties which satisfy conditions represented by the formulae:
P>− (10 0.929T−42.4 −1)×100 (where T <42.3); and
P≧ 99.9 (where T≧ 42.3),
where T represents a single layer transmittance, and P represents a polarization rate.
2. The method as defined in claim 1 , wherein a stretching ratio of the preliminary in-air stretching is 3.5 or less.
3. The method as defined in claim 1 , wherein the preliminary in-air stretching is performed at a temperature greater than a glass transition temperature of the polyvinyl alcohol type resin.
4. The method as defined in claim 1 , wherein the stretching temperature of the preliminary in-air stretching is in a range of 80° C. to 120° C.
5. The method as defined in claim 1 , wherein the dyed laminate is formed by immersing the stretched laminate in a dyeing solution comprised of the dichroic material.
6. The method as defined in claim 5 , wherein the dyeing solution contains water as a solvent and iodine with a concentration in a range of 0.12 to 0.30 weight %.
7. The method as defined in claim 1 , which further comprises a first insolubilization step of applying insolubilization to the stretched intermediate included in the stretched laminate before immersing the stretched laminate in the dyeing solution comprised of the dichroic material.
8. The method as defined in claim 7 , wherein the first insolubilization step includes immersing the stretched laminate in a boric acid solution having a solution temperature of no more than 40° C.
9. The method as defined in claim 1 , wherein the dyed laminate is stretched in the boric acid solution to allow the polarizing film to have a thickness of 10 μm or less.
10. The method as defined in claim 1 , which further comprises an insolubilization step of applying insolubilization to the dyed laminate before stretching the dyed laminate in the boric acid solution.
11. The method as defined in claim 1 , wherein the dyed laminate is subjected to the preliminary in-air stretching and the in-boric-acid-solution stretching to attain a total stretching ratio of 5.0 or more.
12. The method as defined in claim 1 , wherein a solution temperature of the boric acid solution for the in-boric-acid-solution stretching is 60° C. or more.
13. The method as defined in claim 1 , wherein, when the preliminary in-air stretching is performed in an end-free uniaxial stretching, a total stretching ratio for the dyed laminate is in a range of 5.0 to 7.5.
14. The method as defined in claim 1 , wherein, when the preliminary in-air stretching is performed in an end-fixed uniaxial stretching, a total stretching ratio for the dyed laminate is in a range of 5.0 to 8.5.
15. The method as defined in claim 1 , which further comprises a step of cleaning the optical film laminate including the polarizing film which is made of the polyvinyl alcohol type resin having the dichroic material impregnated therein in the molecularly oriented state and has a thickness of 10 μm or less, by a solution containing iodide salt having a solution temperature of no more than 40° C.
16. The method as defined in claim 1 , which further comprises a step of attaching a separator film through an adhesive agent to a surface of the polarizing film opposite to the surface which is attached to the substrate included in the optical film laminate.
17. The method as defined in claim 1 , which further comprises a step of attaching an optically functional film through a bonding agent to a surface of the polarizing film opposite to the surface which is attached to the substrate included in the optical film laminate.
18. The method as defined in claim 17 , which further comprises a step of attaching a separator film through an adhesive agent to a surface of the optically functional film opposite to the surface which is attached to the polarizing film.
19. A method for manufacturing an optical film laminate in which a polarizing film made of a polyvinyl alcohol type resin having a dichroic material impregnated therein in a molecularly oriented state is formed on a substrate made of a crystallizable ester type thermoplastic resin in the form of a continuous web, comprising steps of:
forming a stretched laminate comprising a stretched intermediate made of a molecularly oriented polyvinyl alcohol type resin by subjecting a laminate comprising a substrate made of a crystallizable ester type thermoplastic resin in an amorphous state and a polyvinyl alcohol type resin layer formed on the substrate to a preliminary in-air stretching under a temperature in which the amorphous state of the substrate can be maintained;
forming a dyed laminate including a dyed intermediate comprising the polyvinyl alcohol type resin layer having a dichroic material impregnated therein in a molecularly oriented state by impregnating the dichroic material in the stretched laminate;
forming the optical film laminate including a polarizing film which is made of the polyvinyl alcohol type resin having the dichroic material impregnated therein in a molecularly oriented state and has a thickness of 10 μm or less, by stretching the dyed laminate in a boric acid solution; and
a first insolubilization step of applying insolubilization to the stretched intermediate included in the stretched laminate before immersing the stretched laminate in the dyeing solution comprised of the dichroic material.
20. The method as defined in claim 19 , wherein the polarizing film having optical properties which satisfy conditions represented by the formulae:
P>− (10 0.929T−42.4 −1)×100 (where T< 42.3); and
P≧ 99.9 (where T≧ 42.3),
where T represents a single layer transmittance, and P represents a polarization rate.
21. The method as defined in claim 19 , wherein a stretching ratio of the preliminary in-air stretching is 3.5 or less.
22. The method as defined in claim 19 , wherein the dyed laminate is formed by immersing the stretched laminate in a dyeing solution comprised of the dichroic material, the dyeing solution contains water as a solvent and iodine with a concentration in a range of 0.12 to 0.30 weight %.
23. The method as defined in claim 19 , wherein the first insolubilization step includes immersing the stretched laminate in a boric acid solution having a solution temperature of no more than 40° C.
24. The method as defined in claim 19 , wherein the dyed laminate is stretched in the boric acid solution to allow the polarizing film to have a thickness of 10 μm or less.
25. The method as defined in claim 19 , which further comprises a second insolubilization step of applying insolubilization to the dyed laminate before stretching the dyed laminate in the boric acid solution.
26. The method as defined in claim 19 , wherein the dyed laminate is subjected to the preliminary in-air stretching and the in-boric-acid-solution stretching to attain a total stretching ratio of 5.0 or more.
27. The method as defined in claim 19 , wherein, when the preliminary in-air stretching is performed in an end-fixed uniaxial stretching, a total stretching ratio for the dyed laminate is in a range of 5.0 to 8.5.
28. The method as defined in claim 19 , which further comprises a step of cleaning the optical film laminate including the polarizing film which is made of the polyvinyl alcohol type resin having the dichroic material impregnated therein in the molecularly oriented state and has a thickness of 10 μm or less, by a solution containing iodide salt having a solution temperature of no more than 40° C.
29. The method as defined in claim 19 , which further comprises a step of attaching an optically functional film through a bonding agent to a surface of the polarizing film opposite to the surface which is attached to the substrate included in the optical film laminate.