Heat stabilized moulding composition
The invention relates to a thermostabilized thermoplastic molding composition comprising (a) a thermoplastic polyamide composition, consisting of a blend of at least two polyamides comprising (a.1) at least 50% mass, relative to the total mass of the thermoplastic polyamide composition, of a first polyamide (PA-1), being a semi-crystalline polyamide having a melting point Tm-1, or being an amorphous polyamide having a glass transition point Tg-1, wherein Tm-1 and Tg-1 together are denoted as T-1 and T-1 is at least 200° C. and (a.2) a second polyamide (PA-2), with a C/N ratio of at most 7, being a semi-crystalline polyamide having a melting point Tm-2 or an amorphous polyamide having a glass transition point Tg-2, wherein Tm-2 and Tg-2 together are denoted as T-2 and T-2 is at least 20° C. lower than T-1, (b) a stabilizing system comprising a thermostabilizer selected from the group consisting of phenolic thermostabilizers, organic phosphites, aromatic amines, metal salts of elements from Group IB, MB, III and IV of the Periodic Table and metal halides of alkali and alkali earth metals, and combinations thereof, and (c) a metal oxide, or salt thereof, of a transition metal element from Group VB, VIIB, VIIB and VIIIB of the Periodic Table, or a mixture thereof.
1. A thermostabilized thermoplastic moulding composition comprising:
a) a thermoplastic polyamide composition which consists of a blend of at least two polyamides comprising:
a1) at least 50 mass %, relative to the total mass of the thermoplastic polyamide composition, of a first polyamide (PA-1), being a semi-crystalline polyamide having a melting point Tm-1, or being an amorphous polyamide having a glass transition point Tg-1, wherein each of the melting point Tm-1 and the glass transition point Tg-1 is denoted as a temperature T-1 which is at least 200° C., and
a2) an amount of 1-50 mass %, relative to the total mass of the thermoplastic polyamide composition, of a second polyamide (PA-2), with a C/N ratio of at most 7, being a semi-crystalline polyamide having a melting point Tm-2 or an amorphous polyamide having a glass transition point Tg-2, wherein each of the melting point Tm-2 and the glass transition point Tg-2 is denoted as a temperature T-2 which T-2 is at least 20° C. lower than the temperature T-1,
b) a stabilizing system comprising a thermostabilizer which is at least one selected from the group consisting of phenolic thermostabilizers, organic phosphites, aromatic amines, metal salts of elements from Group IB, IIB, III or IV of the Periodic Table, metal halides of alkali or alkali earth metals, and combinations thereof, and
c) 0.01-10 mass %, relative to the total mass of the thermoplastic polyamide composition, of iron oxide, wherein
the moulding composition exhibits reduced deterioration when exposed to an elevated temperature of 230° C. for a prolonged time period of 1000 hours as compared to an identical moulding composition including a CuI/KI stabilization system but not including the iron oxide.
2. The composition according to claim 1 , wherein the iron oxide comprises particles with a particle size of less than 1 mm.
3. The composition according to claim 2 , wherein the particle size of the particles of the iron oxide is less than 0.1 mm.
4. The composition according to claim 3 , wherein the particle size of the particles of the iron oxide is less than 0.01 mm.
5. The composition according to claim 1 , wherein the iron oxide is present in an amount of 0.1-4 mass %, relative to the total mass of the thermoplastic polyamide composition.
6. The composition according to claim 1 , wherein the stabilizing system (b) comprises a copper salt.
7. The composition according to claim 1 , wherein the first polyamide is PA-6,6, PA-4,6 or a semi-aromatic polyamide.
8. The composition according to claim 1 , wherein the second polyamide is PA-6 or a copolyamide thereof.
9. The composition according to claim 1 , wherein T-1 is at least 220° C. and T-2 is at least 30° C. lower than T-1.
10. The composition according to claim 1 , wherein the second polyamide is present in an amount of 2.5-40 mass %.
11. A moulded part for high-temperature applications involving a use temperature of at least 150° C., which comprises a composition according to claim 1 .
12. A moulded part consisting of a composition according to claim 1 .
13. An automotive engine, a machine, or an electrical or electronic installation which comprises a moulded part according to claim 12 .
14. A process for preparing a moulded part comprising feeding a composition according to claim 1 , and optionally further ingredients, to a moulding machine.