Ultrapure colloidal silica for use in chemical mechanical polishing applications

1. A method for preparing an ultrapure colloidal silica dispersion, comprising the steps of:

dissolving a fumed silica in an aqueous solvent comprising an alkali metal hydroxide to produce an alkaline silicate solution;

removing the alkali metal via ion exchange to generate a silicic acid solution; and

adjusting temperature, concentration and pH of said silicic acid solution to values sufficient to initiate nucleation and particle growth; and

cooling said silicic acid solution at a rate sufficient to produce said colloidal silica dispersion,

wherein said colloidal silica dispersion has less than 200 ppb of each trace metal impurity disposed therein, excluding potassium and sodium, wherein said trace metal is selected from the group consisting of Fe, Al, Li, Rb, Cs, Fr, or any combinations thereof, and

wherein said colloidal silica dispersion has less than 2 ppm residual alcohol.

2. The method of claim 1 , wherein said ultrapure colloidal silica dispersion comprises colloidal silica particles having a mean or aggregate particle size from about 10 to about 200 nm.

3. The method of claim 1 , wherein each said trace metal is present in said dispersion in a range from about 5 to about 200 ppb, excluding potassium and sodium.

4. The method of claim 1 , wherein the pH of said ultrapure colloidal dispersion is between 9 and 11.

5. The method of claim 1 , wherein the pH of said ultrapure colloidal dispersion is between 2 and 4.

6. The method of claim 2 , wherein said colloidal silica particles have a surface area from about 20 m 2 /g to about 300 m 2 /g.

7. The method of claim 2 , wherein said ultrapure colloidal dispersion further comprises a medium for suspending said colloidal silica particles, wherein said medium is selected from the group consisting of water, an organic solvent and a mixture thereof.