Foamable sunscreen formulation comprising pigments
The present application relates to sunscreen formulations, including foamable sunscreen formulations, that comprise zinc oxide and titanium dioxide particles, suitably at least 5 wt % of which have a primary particle size of greater than about 100 nm. The compositions also comprise pigments and suitably produce a minimal residual whitening effect when applied to a skin surface.
1. A foamable sunscreen formulation comprising:
active particles comprising zinc oxide particles having a primary particle size of less than about 50 nm and titanium dioxide particles having a primary particle size of greater than about 100 nm;
b) about 1 wt % microcrystalline cellulose and about 0.2 wt % cellulose gum;
c) about 16 wt % C 12-15 alkyl benzoate, about 1 wt % octyldodecyl neopentanoate, and about 1% wt % butyl octyl salicylate;
d) about 1.2 wt % glyceryl stearate, about 0.5 wt % ceteareth-20, and about 2 wt % polysorbate 80;
e) about 1.8 wt % polyhydroxystearic acid and about 2.7 wt % methyl methacrylate crosspolymer;
f) about 0.8 wt % polyurethane-2, about 0.3 wt % polymethyl methacrylate and about 0.6 wt % tricontanyl PVP film;
g) iron oxide particles comprising red iron oxide particles, yellow iron oxide particles, black iron oxide particles, or mixtures thereof; and
h) about 50 wt % to about $0 wt % water,
wherein at least about 5 wt % of the active particles have a primary particle size greater than about 100 am, and wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
2. The foamable sunscreen formulation of claim 1 , wherein at least about 20 wt % of the active particles have a primary particle size greater than about 100 nm.
3. The foamable sunscreen formulation of claim 2 , wherein at least about 50 wt % of the active particles have a primary particle size greater than about 100 nm.
4. The foamable sunscreen formulation of claim 3 , wherein at least about 75 wt % of the active particles have a primary particle size greater than about 100 nm.
5. The foamable sunscreen formulation of claim 1 , comprising about 0.05 wt % to about 1.0 wt % iron oxide particles having a primary particle size of less than about 50 nm.
6. A foamable sunscreen formulation comprising:
a) active particles comprising titanium dioxide particles having a primary particle size of less than about 50 nm and zinc oxide particles having a primary particle size of greater than about 100 nm;
b) about 1 wt % microcrystalline cellulose and about 0.2 wt % cellulose gum;
c) about 16 wt % C 12-15 alkyl benzoate, about 1 wt % octyldodecyl neopentanoate, and about 1 wt % butyl octyl salicylate;
d) about 1.2 wt % glyceryl stearate, about 0.5 wt % ceteareth-20, and about 2 wt % polysorbate 80;
e) about 1.8 wt % polyhydroxystearic acid and about 2.7 wt % methyl methacrylate crosspolymer;
f) about 0.8 wt % polyurethane-2, about 0.3 wt % polymethyl methacrylate and about 0.6 wt % tricontanyl PVP film;
g) iron oxide particles comprising red iron oxide particles, yellow iron oxide particles, black iron oxide particles, or mixtures thereof; and
h) about 50 wt % to about 60 wt % water,
wherein at least about 5 wt % of the active particles have a primary particle size greater than about 100 nm, and wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
7. The foamable sunscreen formulation of claim 6 , wherein at least about 20 wt % of the active particles have a primary particle size greater than about 100 nm.
8. The foamable sunscreen formulation of claim 7 , wherein at least about 50 wt % of the active particles have a primary particle size greater than about 100 nm.
9. The foamable sunscreen formulation of claim 8 , wherein at least about 75 wt % of the active particles have a primary particle size greater than about 100 nm.
10. The foamable sunscreen formulation of claim 6 , comprising about 0.05 wt % to about 1.0 wt % iron oxide particles having a primary particle size of less than about 50 nm.
11. A foamable sunscreen formulation comprising:
a) active particles comprising titanium dioxide particles having a primary particle size of greater than about 100 nm and zinc oxide particles having a primary particle size of greater than 100 nm;
b) about 1 wt % microcrystalline cellulose and about 0.2 wt % cellulose gum;
c) about 16 wt % C 12-15 alkyl benzoate, about 1 wt % octyldodecyl neopentanoate, and about 1 wt % butyl octyl salicylate;
d) about 1.2 wt % glyceryl stearate, about 0.5 wt % ceteareth-20, and about 2 wt % polysorbate 80;
e) about 1.8 wt % polyhydroxystearic acid and about 2.7 wt % methyl methacrylate crosspolymer;
f) about 0.8 wt % polyurethane-2, about 0.3 wt % polymethyl methacrylate and about 0.6 wt % tricontanyl PVP film;
g) iron oxide particles comprising red iron oxide particles, yellow iron oxide particles, black iron oxide particles, or mixtures thereof; and
h) about 50 wt % to about 60 wt % water,
wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
12. The foamable sunscreen formulation of claim 11 , comprising about 0.05 wt % to about 1.0 wt % iron oxide particles having a primary particle size of less than about 50 urn.
13. A method of preventing sun damage to a patient's skin surface, comprising applying the foamable sunscreen formulation of claim 1 to the skin surface.
14. The method of claim 13 , wherein the foamable sunscreen formulation is applied at least once a day.
15. The method of claim 13 , wherein the foamable sunscreen formulation is applied to the arms, face, legs, chest, trunk or hands.
16. A method of preventing sun damage to a patient's skin surface, comprising applying the foamable sunscreen formulation of claim 6 to the skin surface.
17. The method of claim 16 , wherein the foamable sunscreen formulation is applied at least once a day.
18. The method of claim 16 , wherein the foamable sunscreen formulation is applied to the arms, face, legs, chest, trunk or hands.
19. A method of preventing sun damage to a patient's skin surface, comprising applying the foamable sunscreen formulation of claim 11 to the skin surface.
20. The method of claim 19 , wherein the foamable sunscreen formulation is applied at least once a day.
21. The method of claim 19 , wherein the foamable sunscreen formulation is applied to the arms, face, legs, chest, trunk or hands.