Process for production of a metal hydride
A process for production of a metal hydride compound MH x , wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R 1 O) x M with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH x . R 1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R 1 O) x M is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.
1. A process for production of a metal hydride compound MH x , wherein x is one or two and M is an alkali metal, Be or Mg; said process comprising combining a compound of formula (R 1 O) x M with aluminum, hydrogen and titanium, wherein the titanium is present as an alloy in the aluminum or as free titanium metal, to produce a compound of formula MH x ; wherein R 1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group; a mole ratio of aluminum to (R 1 O) x M is from 0.1:1 to 1:1; and wherein the titanium is present at a level of at least 200 ppm based on weight of aluminum.
2. The process of claim 1 in which M is lithium, sodium or potassium, and x is one.
3. The process of claim 2 in which the mole ratio of aluminum to R 1 OM is from 0.1:1 to 0.7:1.
4. The process of claim 3 in which R 1 is phenyl substituted by an alkoxy group having from one to four carbon atoms.
5. The process of claim 4 in which M is sodium and R 1 is 4-methoxyphenyl.
6. The process of claim 5 in which the mole ratio of aluminum to R 1 ONa is from 0.2:1 to 0.5:1.