Hydrophobically modified polymer for thermally stabilizing fracturing fluids
A method for treating a zone of subterranean formation is provided. The method includes the steps of: (a) forming a treatment fluid including: (i) water; (ii) a viscosity-increasing agent selected from the group consisting of water-soluble polysaccharides, water-soluble derivatives thereof, and any combination of the foregoing; (iii) a crosslinker for the viscosity-increasing agent; (iv) a hydrophobically modified water-soluble polymer; wherein the viscosity-increasing agent is not a hydrophobically modified polymer; and (b) introducing the treatment fluid into a zone of a subterranean formation, wherein the zone has a design temperature of equal to or greater than 350° F.
1. A method for treating a zone of subterranean formation, the method comprising the steps of:
(a) forming a treatment fluid comprising:
(i) water;
(ii) a viscosity-increasing agent selected from the group consisting of a carboxyalkyl derivative of guar, a carboxyalkyl derivative of cellulose, and any combination of the foregoing;
(iii) a crosslinker for the viscosity-increasing agent;
(iv) a hydrophobically modified water-soluble polymer, wherein the hydrophobically modified water-soluble polymer is: (a) a reaction product of a hydrophilic polymer and a hydrophobic compound; or (b) prepared from a polymerization reaction of at least one hydrophilic monomer and at least one hydrophobically modified hydrophilic monomer; and
wherein the viscosity-increasing agent is not a hydrophobically modified polymer, and
(b) introducing the treatment fluid into a zone of a subterranean formation, wherein the zone has a design temperature of equal to or greater than 350° F.
2. The method according to claim 1 , wherein the crosslinker is selected from the group consisting of metal crosslinkers, borate crosslinkers, and any combination thereof.
3. The method according to claim 1 , wherein the viscosity-increasing agent and the crosslinker are each in at least a sufficient concentration such that a similar treatment fluid without the hydrophobically modified polymer would have a viscosity of at least 200 cP after 1 hour at 350° F.
4. The method according to claim 1 , wherein the hydrophobically modified water-soluble polymer comprises a polymer backbone comprising polar heteroatoms.
5. The method according to claim 1 , wherein the hydrophobically modified water-soluble polymer has a molecular weight in the range of about 100,000 to about 10,000,000.
6. The method according to claim 1 , wherein the hydrophobically modified water-soluble polymer is water soluble.
7. The method according to claim 1 , wherein the hydrophilic polymer comprises at least one polymer selected from the group consisting of: a cellulose, a chitosan, a polyamide, a polyetheramine, a polyethyleneimine, a polyhydroxyetheramine, a polylysine, a polysulfone, and a starch.
8. The method according to claim 1 , wherein the hydrophobic compound has an alkyl chain length of about 4 to about 22 carbons.
9. The method according to claim 1 , wherein the mole ratio of the hydrophilic monomer to the hydrophobically modified hydrophilic monomer in the hydrophobically modified water-soluble polymer is in the range of about 99.98:0.02 to about 90:10.
10. The method according to claim 1 , wherein the hydrophobically modified water-soluble polymer is a relative permeability modifier.
11. The method according to claim 1 , wherein the hydrophobically modified polymer increases the thermal stability of the treatment fluid at 350° F. compared to a similar fluid without the hydrophobically modified polymer.
12. The method according to claim 1 , wherein the hydrophobically modified polymer is in at least a sufficient concentration to increase the thermal stability of the treatment fluid by at least one hour at 350° F. compared to a similar fluid without the hydrophobic ally modified polymer.
13. The method according to claim 12 , wherein the hydrophobically modified polymer is in less than a sufficient concentration to increase the viscosity of the treatment fluid by more than two-fold measured after 1 hour at 350° F. compared to a similar fluid without the hydrophobically modified polymer.
14. The method according to claim 12 , wherein the hydrophobically modified polymer is in a concentration of less than 20% wt/vol of the water.
15. The method according to claim 1 , wherein the treatment fluid comprises: inorganic salt.
16. The method according to claim 1 , wherein the treatment fluid comprises: a breaker.
17. The method according to claim 1 , wherein the treatment fluid comprises: an oxygen scavenger.
18. The method according to claim 17 , wherein the oxygen scavenger comprises sodium thiosulfate.
19. The method according to claim 1 , wherein step of introducing the treatment fluid into a zone of a subterranean formation is at a pressure above the fracture pressure of the zone.
20. The method according to claim 1 , wherein the carboxyalkyl derivative of guar is selected from the group consisting of: carboxymethylguar, carboxymethylhydroxyethylguar, carboxymethylhydroxypropylguar, and ethylcarboxymethylguar, and any combination thereof.
21. The method according to claim 1 , wherein the carboxyalkyl derivative of cellulose is selected from the group consisting of: carboxymethylcellulose, carboxymethylhydroxyethylcellulose, ethylcarboxymethylcellulose, and any combination thereof.
22. The method according to claim 1 , wherein the hydrophilic polymer comprises at least one polymer selected from the group consisting of: a chitosan, a polyetheramine, a polyethyleneimine, a polyhydroxyetheramine, a polylysine, a polysulfone, and a starch.