Method and system for the production of a combustible gas from a fuel
Method and system for the production of a combustible gas from a fuel, comprising the conversion of the fuel, at a temperature that is between 600 and 1000° C. and at a pressure that is lower than 10 bar, into at least a combustible gas that comprises CH 4 , CO, H 2 , CO 2 , H 2 O and higher hydrocarbons in a reactor installation ( 1 ). At least part of the higher hydrocarbons present in the combustible gas is catalytically converted into at least CH 4 , CO, H 2 , CO 2 and H 2 O in a reactor ( 45 ) at a pressure that is lower than 10 bar. After this catalytic conversion, an amount of H 2 O and an amount of CO 2 are removed from the combustible gas in a separator installation ( 50 ) at a pressure that is lower than 10 bar. After the removal of H 2 O and CO 2 , the pressure of the combustible gas is raised by a compressor ( 71 ).
1. A method for the production of a combustible gas from a fuel, comprising, sequentially:
(a) converting the fuel, at a temperature that is between 600 and 1000° C. and at a pressure that is lower than 10 bar, into at least a combustible gas that comprises CH 4 , CO, H 2 , CO 2 , H 2 O and higher hydrocarbons, the higher hydrocarbons comprising at least aromatic hydrocarbons,
(b) catalytically converting at least part of the higher hydrocarbons, including the aromatic hydrocarbons, at a pressure that is lower than 10 bar, into at least CH 4 , CO, H 2 , CO 2 and H 2 O,
(c) removing an amount of H 2 O and an amount of CO 2 from the combustible gas at a pressure that is lower than 10 bar,
(d) raising of the pressure of the combustible gas with a compressor, and
(e) methanizing the combustible gas of (d) without use of steam.
2. The method according to claim 1 , further comprising (e) burning the combustible gas of (d).
3. The method according to claim 2 , wherein the combustible gas of (d) is burned in a gas turbine.
4. The method according to claim 1 , wherein the higher hydrocarbons comprise unsaturated hydrocarbons, saturated hydrocarbons, or aromatic hydrocarbons.
5. The method according to claim 4 , wherein the unsaturated hydrocarbons comprise C 2 H 2 and C 2 H 4 , the saturated hydrocarbons comprise C 2 H 6 , and the aromatic hydrocarbons comprise C 6 H 6 and C 7 H 8 .
6. The method according to claim 1 , wherein any of steps (a)-(c) is carried out at a pressure that is lower than 5 bar.
7. The method according to claim 6 , wherein any of steps (a)-(c) is carried out at a pressure between 1-2 bar.
8. The method according to claim 1 , wherein the pressure of the combustible gas is raised to at least 5 bar.
9. The method according to claim 8 , wherein the pressure of the combustible gas is raised to at least 10 bar.
10. The method according to claim 1 , wherein at least 70% of the H 2 O and at least 70% of the CO 2 in the combustible gas are removed.
11. The method according to claim 1 , wherein the removal of H 2 O comprises cooling the combustible gas to a temperature at which the H 2 O present in the combustible gas condenses and forms a condensate.
12. The method according to claim 1 , wherein the removal of CO 2 comprises chemical absorption of CO 2 .
13. The method according to claim 12 , wherein the combustible gas is introduced into an absorber installation, in which the combustible gas is brought into contact with an absorbent for CO 2 .
14. The method according to claim 13 , in which the absorbent is an amine.
15. The method according to claim 14 , wherein the catalytic conversion is carried out with a catalyst comprising an active component comprising at least one of the noble metals Pt, Pd, Rh, Ru, (Os, Ir) or at least one of the transition metals Ni, Co, Mo and W, or compounds thereof.
16. The method according to claim 1 , wherein a quantity of tar, sulphur or chlorine are removed from the combustible gas prior to step (b).
17. The method according to claim 1 , wherein the fuel comprises biomass.