Graphene composite electrodes for energy storage devices
View Patent ↗Aspects of the invention are directed to a method for forming a graphene composite structure. Initially, an encapsulating film is formed on a substrate. The encapsulating film comprises graphene. Subsequently, a plurality of particles are deposited on the encapsulating film, and then a temporary layer is deposited on the plurality of active particles and the encapsulating film. The substrate is then removed. Lastly, the temporary layer is also removed so as to cause the plurality of particles to form a cluster that is at least partially encapsulated by the encapsulating film.
1. A method comprising the steps of:
forming an encapsulating film on a substrate, the encapsulating film comprising graphene;
depositing a plurality of particles on the encapsulating film;
depositing a temporary layer on the plurality of particles and the encapsulating film;
removing the substrate; and
removing the temporary layer so as to cause the plurality of particles to form a cluster that is at least partially encapsulated by the encapsulating film.
2. The method of claim 1 , wherein the step of forming the encapsulating film comprises chemical vapor deposition.
3. The method of claim 2 , wherein the chemical vapor deposition is accomplished at least in part with methane and hydrogen.
4. The method of claim 1 , wherein the method does not comprise reducing graphene oxide.
5. The method of claim 1 , wherein the substrate comprises at least one of copper and nickel.
6. The method of claim 1 , wherein the plurality of particles comprise at least one of silicon, germanium, and tin.
7. The method of claim 1 , wherein the plurality of particles comprise a transition metal oxide.
8. The method of claim 1 , wherein the plurality of particles comprise at least one of a lithium metal phosphate and a lithium metal oxide.
9. The method of claim 1 , wherein the plurality of particles comprise a conductive polymer.
10. The method of claim 1 , wherein the plurality of particles have an average diameter between about ten nanometers and about ten micrometers.
11. The method of claim 1 , wherein the step of depositing the plurality of particles comprises at least one of spray coating and dip coating.
12. The method of claim 1 , wherein the temporary layer comprises a polymeric material.
13. The method of claim 1 , wherein the temporary layer comprises a polymeric photoresist material.
14. The method of claim 1 , wherein the step of depositing the temporary layer comprises at least one of spray coating, dip coating, and spin coating.
15. The method of claim 1 , wherein the step of removing the substrate comprises wet chemical etching.
16. The method of claim 1 , wherein the step of removing the temporary layer comprises wet chemical etching.
17. The method of claim 1 , wherein the step of removing the temporary layer comprises at least one of centrifugation and supercritical drying.
18. The method of claim 1 , further comprising the step of installing the cluster that is at least partially encapsulated by the encapsulating film into an energy storage device.
19. The method of claim 18 , wherein the energy storage device comprises a battery.
20. The method of claim 19 , wherein the battery comprises a lithium-ion battery.
21. The method of claim 18 , wherein the energy storage device comprises a supercapacitor.