Metal nanoparticle dispersion
View Patent ↗According to one embodiment, metal nanoparticle dispersion includes organic solvent, and metal-containing particles dispersed in the organic solvent. The metal-containing particles include first metal nanoparticles and second metal nanoparticles. Each of the first metal nanoparticles has a high-molecular compound on at least part of a surface thereof. Each of the second metal nanoparticles has a low-molecular compound on at least part of a surface thereof. A total amount of the low-molecular compound on all of the second nanoparticles includes an amount of a primary amine as the low-molecular compound.
1. A metal nanoparticle dispersion comprising:
organic solvent; and
metal-containing particles dispersed in the organic solvent, the metal-containing particles comprising first metal nanoparticles and second metal nanoparticles, the second metal nanoparticles comprising a noble metal as a major component, each of the first metal nanoparticles having a high-molecular compound on at least part of a surface thereof, each of the second metal nanoparticles having a low-molecular compound on at least part of a surface thereof, a total amount of the low-molecular compound on all of the second nanoparticles containing an amount of a primary amine as the low-molecular compound, the high molecular compound having a weight average molecular weight range of 3,000 to 100,000, the low-molecular compound having a molecular weight of 100 to 300.
2. The dispersion according to claim 1 , wherein the first metal nanoparticles are nanoparticles comprising at least one selected from the group consisting of copper, silver, gold, iron, platinum, palladium, tin, nickel, cobalt, ruthenium and rhodium.
3. The dispersion according to claim 2 , wherein the first metal nanoparticles comprise copper as a major component.
4. The dispersion according to claim 1 , wherein the high-molecular compound comprises a functional group or an atom which participates in the adsorption to the first metal nanoparticles.
5. The dispersion according to claim 1 , wherein the noble metal comprises silver.
6. The dispersion according to claim 1 , wherein the low-molecular compound comprises a functional group or an atom which interacts with the second metal nanoparticles.
7. The dispersion according to claim 1 , wherein the primary amine has a boiling point of 250° C. or less.
8. The dispersion according to claim 1 , wherein the first metal nanoparticles and the second metal nanoparticles respectively have an average primary particle diameter of 10 to 100 nm.
9. The dispersion according to claim 1 , wherein the first metal nanoparticles and the second metal nanoparticles respectively have a maximum particle diameter of 500 nm or less.
10. The dispersion according to claim 1 , wherein the organic solvent has 8 to 18 carbons.
11. The dispersion according to claim 1 , wherein the metal-containing particles account for 4 to 70 mass % of the metal nanoparticle dispersion composition.
12. The dispersion according to claim 1 , wherein the amount of the second metal nanoparticles is 0.1 to 30% of the amount of the first metal nanoparticles.
13. The dispersion according to claim 1 , wherein the dispersion is an ink.
14. The dispersion according to claim 13 , wherein the ink is an ink for ink jet printing.
15. The dispersion according to claim 1 , wherein the high-molecular compound comprises polyvinyl type compound.
16. The dispersion according to claim 15 , wherein the high-molecular compound comprises polyvinyl type compound which is selected from the group consisting of polyvinyl alcohol and polyvinyl pyrrolidone.