Lubricant compositions based on block copolymers and processes for making
Provided are lubricant compositions with improved oxidative stability and frictional and wear resistance properties for use in engine oil applications. The lubricant compositions include: i) a first base stock selected from a Group I base stock, a Group II base stock or a combination thereof at 50 to 80 wt %; ii) a block copolymer at 1 to 10 wt %; iii) a viscosity modifier at 3 to 15 wt % selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes; and iv) an additive package including a combination of antioxidants, dispersants, detergents, friction modifiers and antiwear agents at 2 to 30 wt %.
1. A lubricant composition for use in engine oil applications comprising:
i) a first base stock selected from a Group I base stock, a Group II base stock and a combination thereof at 50 to 80 wt % of the lubricant composition,
ii) a block copolymer, comprising:
an “A” block of a functionalized hydrocarbon moiety including one or more functional end groups selected from: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bonds, aromatic rings and thiols; and
a “B” block of a functionalized polyether moiety including one or more functional end groups selected from: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bonds, aromatic rings and thiols,
wherein the end group of the polyether moiety is different than the end group of the hydrocarbon moiety, wherein the hydrocarbon moiety and the polyether moiety are copolymerizable therewith, wherein the block copolymer ranges from 1 to 10 wt % of the lubricant composition,
iii) a viscosity modifier at 3 to 15 wt % of the lubricant composition selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes, and
iv) an additive package including a combination of antioxidants, dispersants, detergents, friction modifiers and antiwear agents, wherein the additive package ranges from 2 to 30 wt % of the lubricant composition.
2. The lubricant composition of claim 1 , wherein said hydrocarbon moiety is a poly-α-olefin and said polyether moiety is a polyalkylene glycol.
3. The lubricant composition of claim 2 , wherein the polyalkylene glycol is difunctional and the poly-α-olefin is difunctional.
4. The lubricant composition of claim 3 , wherein the polyalkylene glycol is a difunctional amine and the poly-α-olefin is a difunctional epoxide.
5. The lubricant composition of claim 4 , wherein the polyalkylene glycol is a polyether amine.
6. The lubricant composition of claim 5 , wherein the polyether amine is at least one amine selected from the group consisting of:
poly(propyleneglycol) bis(2-aminopropylether), and poly(propyleneglycol)-block-poly(ethyleneglycol)-block poly(propyleneglycol) bis(2-aminopropylether).
7. The lubricant composition of claim 2 , wherein the hydrocarbon moiety is an alkyl glycidyl ether, Armin amine or dioctylamine.
8. The lubricant composition of claim 1 , comprising a diblock copolymer.
9. The lubricant composition of claim 1 , comprising a repeating diblock copolymer.
10. The lubricant composition of claim 1 , wherein the block copolymer has an average molecular weight of 200 to 20000.
11. The lubricant composition of claim 10 , wherein the block copolymer has an average molecular weight of 250 to 5000.
12. The lubricant composition of claim 1 , further including a second base stock selected from: a metallocene poly-α-olefin, a poly-α-olefin, a GTL base stock, and a Group III base stock.
13. The lubricant composition of claim 1 , wherein the oxidative stability as measured by bench oxidation test at 167 hours yields a kinematic viscosity at 40° C. of less than or equal to 400 cSt.
14. The lubricant composition of claim 1 , wherein the wear resistance as measured by wear scar using a High Frequency Reciprocating Rig (HFRR) test is less than or equal to 170 microns.
15. The lubricant composition of claim 1 , wherein the average friction coefficient at 70° C. measured using a High Frequency Reciprocating Rig (HFRR) test is less than or equal to 0.165.
16. The lubricant composition of claim 1 , wherein the first base stock is a combination of a Group I base stock at 53 wt % of the lubricant composition and a Group II base stock at 20 wt % of the lubricant composition.
17. The lubricant composition of claim 16 , wherein the block copolymer is polyether amine at 3 wt % of the lubricant composition.
18. The lubricant composition of claim 17 , wherein the viscosity modifier is an olefin copolymer at 7 wt % of the lubricant composition.
19. The lubricant composition of claim 18 , wherein the additive package is at 17 wt % of the lubricant composition.
20. The lubricant composition of claim 19 , wherein the oxidative stability as measured by bench oxidation test at 167 hours yields a kinematic viscosity at 40° C. of 339 cSt, a wear resistance as measured by wear scar using a High Frequency Reciprocating Rig (HFRR) test of 144 microns, and an average friction coefficient at 70° C. as measured using a HFRR test of 0.151.
21. The lubricant composition of claim 1 , wherein the antioxidants include one or more aminic antioxidants, one or more phenolic antioxidants, one or more oil-soluble copper complexes and combinations thereof at a loading in the composition of from 0.2 wt % to 6 wt %.
22. The lubricant composition of claim 1 , wherein the friction modifiers include one or more metal-containing friction modifiers, one or more ashless friction modifiers and combinations thereof at loading in the composition of from 0.1 wt % to 5 wt %.
23. The lubricant composition of claim 1 , wherein the lubricant composition has a higher kinematic viscosity (Kv 100 and Kv 40 ) and a lower friction coefficient than a comparable composition not including the block copolymer.
24. A method of making a lubricant composition for use in engine oil applications comprising:
providing the following components:
i) a first base stock including a Group I base stock, a Group II base stock or a combination thereof,
ii) a block copolymer, comprising:
an “A” block of a functionalized hydrocarbon moiety including one or more functional end groups selected from the group consisting of: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bonds, aromatic rings and thiols; and
a “B” block of a functionalized polyether moiety including one or more functional end groups selected from the group consisting of: epoxides, amines, acids, acid chlorides, acid anhydrides, halogens, vinyl or vinylidene double bonds, aromatic rings and thiols,
wherein the end group of the polyether moiety is different than the end group of the hydrocarbon moiety, wherein the hydrocarbon moiety and the polyether moiety are copolymerizable therewith,
iii) a viscosity modifier selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes, and
iv) an additive package including a combination of antioxidants, dispersants, detergents friction modifiers and antiwear agents; and
blending the first base stock at 50 to 80 wt % of the lubricant composition, the block copolymer at from 1 to 10 wt % of the lubricant composition, the viscosity modifier at 3 to 15 wt % of the lubricant composition, and the additive package at from 2 to 30 wt % of the lubricant composition to form the lubricant composition.
25. The method of claim 24 , wherein the oxidative stability of the lubricant composition as measured by bench oxidation test at 167 hours yields a kinematic viscosity at 40° C. of less than or equal to 400 cSt.
26. The method of claim 24 , wherein the wear resistance of the lubricant composition as measured by wear scar using a High Frequency Reciprocating Rig (HFRR) test is less than or equal to 170 microns.
27. The method of claim 24 , wherein the average friction coefficient at 70° C. of the lubricant composition measured using a High Frequency Reciprocating Rig (HFRR) test is less than or equal to 0.165.
28. The method of claim 24 , wherein the antioxidants include one or more aminic antioxidants, one or more phenolic antioxidants, one or more oil-soluble copper complexes and combinations thereof at a loading in the composition of from 0.2 wt % to 6 wt %.
29. The method of claim 24 , wherein the friction modifiers include one or more metal-containing friction modifiers, one or more ashless friction modifiers and combinations thereof at loading in the composition of from 0.1 wt % to 5 wt %.
30. The method of claim 24 , wherein the lubricant composition has a higher kinematic viscosity (Kv 100 and Kv 40 ) and a lower friction coefficient than a comparable composition not including the block copolymer.